• 제목/요약/키워드: Soluble ion

검색결과 339건 처리시간 0.027초

뿜칠형 수용성 고무화 아스팔트 차수재의 성능평가 및 폐기물 매립지 적용성 검토에 관한 연구 (A Study on Examination of Application in Waste Filled Land and Performance Evaluation as Waterproofing Material by the Spray Water-Soluble Rubber Asphalt)

  • 이성일;정문정;김형무;오상근
    • 한국건축시공학회:학술대회논문집
    • /
    • 한국건축시공학회 2001년도 학술논문발표회
    • /
    • pp.163-168
    • /
    • 2001
  • This study examinated the application in construction field and the development of waterproofing material system by the spray water-soluble rubber asphalt to solve the problems of synthetic polymer sheet and gio membrane(A mat sheet of Bentonite) that had been used domestic waterproofing material in advance. As the result of study, characters of study water-souble rubber asphalt are the follows; 1) The amount of water absorption was '0.06'g and the seepage quantity was '0'g in result. 2) The tensile strength was about 30.7kgf/$cm^2$ and the elongation was about 72.4% in result. 3) After reliance of temperature test had been ended, the tensile strength was about 72.4kg/$cm^2$ in low temperature and about 30.7kgf/$cm^2$ in normal temperature. 4) After acid and alkaline treatment had been ended, the tensile strength was about 19.7kgf/$cm^2$ and about 21.9kgf/$cm^2$ in result. 5) After chlorine ion treatment had been ended, the tensile strength was 28.5kgf/$cm^2$ and the elongation was 250% in result. So, this study can propose the spray water-soluble rubber asphalt to satisfy the security and durability of waste filled land.

  • PDF

수용성 절삭유의 부패 특성과 Copper Alloy Metal Fiber의 부패 방지 장치에 관한 연구 (A Study on the Antimicrobial Activity of Copper Alloy Metal Fiber on Water Soluble Metal Working Fluids)

  • 송주영;이상호;김종화
    • 한국응용과학기술학회지
    • /
    • 제26권1호
    • /
    • pp.69-73
    • /
    • 2009
  • Copper alloy metal fiber was incorporated into the conventional water-soluble metal working fluids to increase the antimicrobial activity. Fluid treated by copper alloy metal fiber is shown that bacteria is disappeared whereas that untreated metal fiber is increased bacteria as increasing the life time. When the electrochemical potential of Cu/Zn ion is -268mV, radicals with molecular oxygen are easily made. Especially, hydroperoxide radical shows strong toxicity to the strains, leading to the conformational change of plasma membrane. As a result antimicrobial activity of copper alloy metal fiber in metal working fluid is superior to that of copper fiber.

포천지역에서 측정한 $PM_{10}$중 2차 생성입자에 관한 연구 (The Study on Secondary Pollutants of $PM_{10}$ in Pocheon)

  • 박태술
    • 환경위생공학
    • /
    • 제20권4호통권58호
    • /
    • pp.9-20
    • /
    • 2005
  • The purpose of the study was characteristics of secondary pollutants of $PM_{10}$ collected in pocheon between August 2002 and June 2003. The ambient concentrations of $PM_{10}$ mass, 9 water-soluble anions and cations, and 13 bulk composition trace elements were determined from filter samples collected by $PM_{10}$ high volume air sampler(UV-15H, Graseby-Anderson Co., USA). During this period average $PM_{10}$ mass concentration was $83.8{\mu}g/m^3(49.8{\mu}g/m^3\~111.6{\mu}g/m^3)$ in Pocheon. Mechanism for transformation of secondary pollutants by soluble ion components is divided into two categories; $NaNO_3$ type by the reaction of sea salt and $HNO_3$ in the atmosphere, and nitrate salt or phosphate salt type such as $(NH_4)_2SO_4,\;NH_4NaSO_4,\;and\;(NH_4)_2SO_4(2NH_4O_3)$.

Characteristics of Water-soluble Polysaccharide, Showing Inhibiting Activity on ${\alpha}-Glucosidase$, in Cordyceps militaris

  • Chung, Ha-Yull;Yoo, Mi-Kyong;Kawagishi, Hirokazu
    • Food Science and Biotechnology
    • /
    • 제18권3호
    • /
    • pp.667-671
    • /
    • 2009
  • Extract of water-soluble polysaccharide (CFWx), showing inhibiting activity on ${\alpha}-glucosidase$, was prepared from the fruiting bodies of Cordyceps militaris by hot-water extraction, and ethanol precipitation. Chemical characteristics of CFWx were as follows: carbohydrate content 30% including 16% of uronic acid; 51% protein content; monosaccharide composition, Man:Glu:Gal (30:43:27); molecular weight $3-5{\times}10^4$. CFWx was further purified by ion-exchange, gel-permeation, and affinity chromatography and $CFWx-AH-{\alpha}$ fraction was isolated. Fundamental structure of $CFWx-AH-{\alpha}$ was deduced as ${\alpha}-(1{\to}4$)-D-glucan with ${\alpha}-(1{\to}3$)- and/or ${\alpha}-(1{\to}6$)-D-glycosidic side chains based on methylation analysis.

고성능 표면침투제가 도포된 콘크리트의 복합열화저항성 평가 (The Evaluation of Resistance of Multi-degregation on Concrete Coated High Performance Penetration Agency)

  • 유성원;서정인;하헌재;이상민;박상순
    • 한국콘크리트학회:학술대회논문집
    • /
    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
    • /
    • pp.241-244
    • /
    • 2004
  • The evaluation of Single or multi-degregation of concrete coated by high performance surface penetration agency was examined through various tests, i.e., carbonation, absorption, carbonation + chloride ion and carbonation + chemical solution according to various high performance surface penetration agencies and various compressive strengths of base concrete. The 2 types of high performance surface penetration agencies were used i.e., inorganic and alcohol soluble. And 2 types of compressive strength of base concrete were used such as 21 30. MPa. The characteristics of concrete coated high performance surface penetration agency was more improved than that of non-coated concrete, and especially, water soluble inorganic agency was most effective. And if compressive strength of base concrete was low, the improved effects would be larger.

  • PDF

Partial Purification and Characterization of a Soluble $\beta$-Fructoguracosidase from Onion (Allium cepa)

  • Lee, Yong-Eok;Yoo, Jin-Young
    • Preventive Nutrition and Food Science
    • /
    • 제3권2호
    • /
    • pp.152-156
    • /
    • 1998
  • A Fructan-degrading enzyme was partially purified from onion (Allium cepa)bulbs by a combination of ammonium sufate precipitation, concanavalin-A-Affinity chromatography, and ion-exchange and gel-filtration chromatography. The enzyme hydrolyzed sucrose more effectively than inulin and was identified as a $\beta$- fructofuranosidase (invertase). The optimum pH and temperature were pH 5.5 and 35$^{\circ}C$, respectively. The enzymehydrolyzed sucrose with a Km of 1.2mM . The soluble $\beta$-fructofuranosidase is likely glycoprotein based on its ability to bind the lectin concanavalin-A. The enzyme was heatlabie, with mose activity being lost at 5$0^{\circ}C$ in 1 hr of incubation. The onion $\beta$-fructofuranosidase was partially inhibited by ZnCl2 HgCl2 and CuSo4.

  • PDF

약물 및 유전자 전달체로 응용하기 위한 Poly(L-Lysine)이 결합된 O-Carboxymethyl Chitosan PEG의 제조와 특성 (Preparation and Characterization of O-Carboxymethyl Chitosan Ion-complexed Poly(L-Lysine) for Drug and Gene Delivery System)

  • 남정표;김영민;박진수;이응재;최창용;장미경;나재운
    • 공업화학
    • /
    • 제21권6호
    • /
    • pp.643-647
    • /
    • 2010
  • 키토산의 응용성을 높이기 위해 제조된 O-carboxymethyl water soluble chitosan (OCMCh)의 구조에 인체 내 순환시간을 증가시키기 위하여 PEG를 도입하였으며, 약물 및 유전자 전달체로 응용하기 위하여 PEG가 결합된 OCMCh-PEG를 Poly(L-Lysine) (PLL)과 이온복합체를 형성함으로써 OCMCh-PEG-PLL를 제조하였다. 제조된 OCMCh-PEG-PLL의 물리화학적특성은 적외선 분광광도계와 핵자기공명장치를 이용하여 분석하였으며, 성공적으로 PLL이 결합되었음을 확인하였다. 또한 동적광산란장치와 투과전자현미경을 통하여 PLL의 양을 고정하였을 때, PEG의 양이 증가함에 따라 입자의 크기가 감소하는 것을 볼 수 있었으며, 구형의 입자형태를 가지는 것을 확인할 수 있었다. 이상의 결과는 OCMCh-PEG-PLL이 약물 및 유전자 전달체 등과 같은 생체재료로의 응용 가능성을 가지는 것을 볼 수 있다.

정수압이 해양콘크리트의 염화물이온 침투에 미치는 영향 (Influence of Hydrostatic Pressure on Chloride Ion Penetration of Marine Concrete)

  • 김경태;김규용;남정수;이보경;임창혁
    • 한국구조물진단유지관리공학회 논문집
    • /
    • 제23권1호
    • /
    • pp.78-84
    • /
    • 2019
  • 해양 콘크리트 구조물 중 침지대에 위치한 구조물은 수심이 10 m 깊어질수록 1 atm의 정수압을 받아 염화물이온 침투가 촉진될 가능성이 있다. 본 연구에서는 정수압이 해양콘크리트의 염화물이온침투에 미치는 영향과 원인을 평가하기 위하여 보통 포틀랜드 시멘트와 고로슬래그 시멘트를 활용한 콘크리트를 각각 1, 6 atm의 정수압과 인공해수에 노출시켜 깊이별 수용성 염화물량과 미세구조 분석을 실시하였다. 측정결과 6 atm의 정수압을 받는 콘크리트는 표면 염화물이온 농도가 급격하게 상승하며, 깊이별 수용성 염화물량이 증가하는 경향을 나타내었다. 또한, 정수압을 받은 콘크리트는 5~100 nm에 해당하는 모세관공극이 증가하는 경향을 나타내었다.

Solubilities of Salen Derivatives and Their Cobalt Complex in Liquid and Supercritical CO2

  • Koh, Seung-Hyun;Jeon, Byung-Wan;Kim, Ha-Kwon;Park, Kwang-Heon;Kim, Hong-Doo
    • Bulletin of the Korean Chemical Society
    • /
    • 제25권4호
    • /
    • pp.471-475
    • /
    • 2004
  • The solubility of N,N'-Bis(salicylidene) ethylenediamine (n-salen) and N,N'-bis(3,5-di-tert-butylsalicylidene) ethylenediamine (t-butyl-salen) was studied with in-situ UV-VIS spectrometer. n-Salen is 3-5 times more soluble than t-butyl-salen in liquid or supercritical $CO_2$. This behavior may be attributed to Lewis acid-base interaction between salen and $CO_2$. The chelation of salen with $Co^{++}$ ion in supercritical condition was confirmed to be fast enough above room temperature. However, the metal ion extraction capability of t-butyl salen is relatively poor because of its low solubility and ionic nature of complex.

Novel Synthesis of Hydrophilic Dipolar Chromophores using Dendronized Sulfonates

  • Kim, Mi-Rae;Maheswara, Muchchintala;Do, Jung-Yun
    • Bulletin of the Korean Chemical Society
    • /
    • 제32권2호
    • /
    • pp.664-672
    • /
    • 2011
  • A series of hydrophilic chromophores was synthesized through introduction of dendritic sulfonate anions using click chemistry. A dendron structure bearing several sulfonate groups enhances hydrophilicity of attached chromophores. A click triazole formation connects chromophores with hydrophilic groups. A neutral trichloroethyl sulfonate has versatile features such as easy introduction, chemical endurance for isolation or storage, and convenient transformation to a hydrophilic anion. Zinc and OH mediated cleavage of trichloroethyl group from the neutral sulfonate undergoes to generate a water-soluble sulfonate anion. The solubility was examined with different counter cations and in different pH media and thus increased with the number of attached sulfonate ion. Two hydrophilic chromophores of stilbene-derived and azobenzene-derived dipolar structures exhibit clear negative and positive solvatochromism in protic solvents, respectively.