• 한국주조공학회지
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• 제28권6호
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• pp.261-267
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• 2008

In-situ quasicrystalline icosahedral (I) phase reinforced Ti-based bulk metallic glass (BMG) matrix composites have been successfully fabricated by using two distinct thermal histories for BMG forming alloy. The BMG composite containing micron-scale Iphase has been introduced by controlling cooling rate during solidification, whereas nano-scale I-phase reinforced BMG composite has been produced by partial crystallization of BMG. For mechanical properties, micron-scale I-phase distributed BMG composite exhibited lower strength and plasticity compared to the monolithic BMG. On the other hand, nano-scale icosahedral phase embedded BMG composite showed enhanced strength and plasticity. These improved mechanical properties were attributed to the multiplication of shear bands and blocking of the shear band propagation in terms of isolation and homogeneous distribution of nanosize icosahdral phases in the glassy matrix, followed by stabilizing the mechanical and deformation instabilities.

• 대한기계학회논문집A
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• 제31권6호
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• pp.718-724
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• 2007

Some of gas turbine model of 7F-Class has constructed and is operating with units domestically. Non-destructive testing (NDT) is one of the methods being used to inspect damage $1^{st}$ stage bucket and review damage trends. We also analyze damage configuration and microstructure according to material and compare with pape of electric power research institute (EPRI). The damaged mode could be determined by leveraging failure analysis. Especially, configuration uprate of bucket is not only to prevent damage during operation but also avoid domestic manufacturing by the competitors. Modifications were mainly concentrated on surfaces such as cooling hole and bucket tips. Analyzing of bucket damage, the earlier model of 7F-Class used with one cycle with equivalent operation hour (EOH), has various cracking of the bucket surface. Bucket damage of new model is centered on tip area (54%) as analyzed by EPRI research. We conclude that improving bucket configuration would increase repair rate on the bucket tip.

• 한국전기전자재료학회논문지
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• 제31권4호
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• pp.249-254
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• 2018

We researched about a bulk metallic glass system as an additive to an Ag paste for high temperature thermoelectric modules. Bulk metallic glass (BMG) ribbons were produced by using a rapid solidification process (RSP) under a cooling rate condition higher than $10^{\circ}C/sec$. We investigated BMG characteristics of the ribbons by means of x-ray diffraction (XRD) and differential scanning calorimetry (DSC) in order to evaluate the glass transition temperature ($T_g$) and the recrystallization temperature ($T_x$) lower than $400^{\circ}C$. A milling process was also developed to apply the BMG ribbons to a commercial Al paste as an additive for lower sintering temperature.

• 소성∙가공
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• 제14권6호
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• pp.502-508
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• 2005

Hypereutectic Al-Si alloys have been regarded attractive for automotive and aerospace application, due to high specific strength, good wear resistance, high thermal stability, low thermal expansion coefficient and good creep resistance. Spray casting of hypereutectic Al-Si alloy has been reported to provide distinct advantages over ingot metallurgy (IM) or rapid solidification/powder metallurgy (RS/PM) process in terms of microstructure refinement. In this study, hypereutectic Al-25Si-2.0Cu-1.0Mg alloy was prepared by OSPREY spray casting process. The change of strain rate sensitivity and Creep transition were analyzed by using the load relaxation test and constant creep test. High temperature deformation behavior of the hypereutectic Al-Si alloy has been investigated by applying the internal variable theory proposed by Chang et al. Especially, the creep resistance of spray casted hypereutectic Al-Si alloy can be enhanced considerably by the accumulation of prestrain.

• 열처리공학회지
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• 제8권2호
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• pp.149-154
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• 1995

The alloying of 6.5wt % Silicon in iron decreases the magnetization and the anisotropy and minimizes the iron loss noticeably. But it is very difficult to make thin sheets because of its poor ductility which is due to an ordering reaction (body centered cubic to CsCI type crystal structure). However the ordering reaction can be suppressed by rapid solidification method. The cooling rate of rapidly solidified Fe-6.5wt % Si alloy is about $10^3K/s$ and rapidly solidified structure are fine structure, cellular structure, dendrite and equiaxed grain from surface. The precipitates of $DO_3$ Phase emerges on $B_2$ matrix and the coercive force was 0.51 Oe (50cycle, 15KGauss) in Fe-6.5wt% Si alloy which was processed by heat treatment of $1150^{\circ}C$ for 1hr in high vacuum.

• 대한금속재료학회지
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• 제49권8호
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• pp.619-627
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• 2011

The poisoning effect of Zr in aluminum alloys was investigated by analyzing the filtered cakes of aluminum alloy melt taken with the $Prefil^{(R)}$ footprinter through a variety of analytic instruments, SEM/EDX, Auger, and TEM. Experimental results indicated that the morphology and chemical composition of the aluminum alloys were not modified with the addition of Zr, which is to previous belief that Zr poisoning is caused by modification of $(Ti_{1-x}Zr_x)Al_3$. On the other hand, $TiAl_3$ surroundig $TiB_2$ particles was modified and its lattice parameter was more mismatched by increasing Zr content, leading to less nucleation rate. This is also supported by the observation that the poisoning effect is reduced when Ti is added, resulting in a lower content ratio of Zr to Ti. These results suggest that extra Ti should be added to eliminate the poisoning effect of Zr in aluminum alloys containing Zr.

• 한국주조공학회지
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• 제42권5호
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• pp.273-281
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• 2022

Al-Cu-Si 3원계 공정합금의 응고거동과 미세조직 변화를 이해하기 위해서, 금형 예열온도를 달리하여 Al-Cu-Si 3원계 공정합금의 미세조직 변화를 관찰하였다. 금형 예열온도가 500℃일 때, 초정 Si과 덴드라이트 형상의 Al2Cu상이 관찰되며, 이후 (α-Al+Al2Cu)의 2원계 공정상이 관찰된다. 금형 예열온도가 300℃일 때 미제조직은 금형 예열온도가 500℃일 때와 유사하나 (α-Al+Al2Cu+Si)의 3원계 공정상이 관찰되는 영역과 관찰되지 않는 영역이 나타난다. 금형 예열온도가 150℃인 경우에는 미세조직이 (α-Al+Al2Cu)의 2원계 공정상과 (α-Al+Al2Cu+Si)의 3원계 공정상이 관찰되는 Bimodal 구조를 나타낸다. 금형 예열온도를 달리 하였을 때 가장 큰 변화를 나타내는 상은 Si상이며, 임계냉각속도를 지나면 (α-Al+Al2Cu+Si)의 3원계 공정상이 형성되는 순간에 빠른 냉각에 의한 Si의 성장이 억제되면 Cooperative 성장을 하기 때문에 Al, Cu의 성장도 함께 억제된다. 서로 다른 합금설계 전산모사 프로그램을 통해 Al-27wt%Cu-5wt%Si의 3원계 공정 합금을 분석한 결과, 합금설계 전산모사 프로그램에 따라 결과의 차이가 발생하며, 전산모사의 신뢰성을 높이기 위해서는 실제 주조를 통한 미세조직 분석이 수반되어야 한다.

• 한국결정성장학회지
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• 제10권5호
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• pp.345-349
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• 2000

Micro-pulling down법을 이용하여 $Al_2O_3/ZrO_2$eutectic fiber를 제조하여 그 미세구조 및 기계적 특성과 성장속도의 관계를 조사하였다. 성장속도는 0.1~15 mm/min였으며, 직경 0.2~2 mm, 길이 500 mm의 eutectic fiber를 제조하였다. $Al_2O_3/ZrO_2$eutectic fiber의 미세구조는 성장속도에 따라 rod-shape structure에서 lameller structure를 거쳐 lamellar pattern을 갖는 cellular structure로 변화하였다. lamellar thickness는 성장속도가 1 mm/min에서 15 mm/min로 증가함에 따라 380 nm에서 110 nm로 감소하였다. 이와 같은 성장속도에 따른 lamellar thickness의 감소경향은 inverse-square-root로 나타내면, = 1 -l/2와 같이 표현할 수 있다. 여기서 는 m, 는 m/s의 단위를 갖는다. 13.1 Gpa의 hardness, 900 Mpa의 상온인장강도를 나타냈으며, 성장속도의 증가 즉, interlamellar spacing이 감소함에 따라 증가하는 경향을 나타냈다.

• 소성∙가공
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• 제16권2호
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• pp.126-131
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• 2007

Voids in a large rotor are formed in solidification process of a cast ingot. The voids have to be eliminated from the rotor by a forming process, because they would became stress-intensity factors which suddenly fracture the rotor in the operation. Previous studies on void-elimination of a large rotor have mainly focused on finding the process variables affecting the void-closure. But the study on the amount of void closure in a large rotor has been very rare. This study was performed to obtain an equation which predicts the amount of void-closure in a forging process of a large rotor and to evaluate the availability of the void-closure equation through finite element analyses. Firstly, 2D FE analysis was carried out to find effects of time integral of hydrostatic stress and effective strain on void volume rate of a large rotor in the upsetting process for various diameters and shapes of void, and material temperature. From the 2D FE analysis, we found that effective strain was suitable for predicting the void-closure of a large rotor, because there was a constant relationship between void volume rate and effective strain. And a void-closure equation was proposed fur predicting void-closure of a large rotor in the upsetting process. Finally, ken the 3D FE analysis, the proposed void-closure equation was verified to be useful for upsetting and cogging processes.

• 한국주조공학회지
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• 제29권5호
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• pp.225-232
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• 2009

For comprehensive understanding of the formation behavior of $\beta-Al_5FeSi$ phase in Al-Si-Cu alloys with the existence of Fe element, microstructure characterizations were performed using combined analysis of OM, SEM-EDS, XRD. Especially, experimental and predictive works on solidification events of $\beta-Al_5FeSi$ phase as well as other phases formed together with $\beta-Al_5FeSi$ have been carried out by using DSC analysis and Java-based Materials Properties software (J. Mat. Pro.). Primary and eutectic $\beta-Al_5FeSi$ phases were able to distinguish from each other on microstructures by their morphological features. Primary $\beta-Al_5FeSi$ phase was seen to have rough surface perpendicular to growth direction, indicating free attachment of solute atoms in liquid state. On the other hand, the eutectic $\beta-Al_5FeSi$ phase was formed with plain and straight surface during eutectic reaction together with $\alpha$-Al phase. The eutectic reaction of $\beta-Al_5FeSi$ and $\alpha$-Al phases was seen to be able to separate into each formation depending on cooling rate.