• 제목/요약/키워드: Solid-liquid phase change

검색결과 130건 처리시간 0.026초

동시 축·방열 조건에서 PCM의 열전달 특성에 관한 연구 (A Study on the Characteristic of Heat Transfer of PCM(Phase Change Material) at the Simultaneous Charging and Discharging Condition)

  • 이동규;박세창;정동열;강채동
    • 설비공학논문집
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    • 제28권8호
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    • pp.305-310
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    • 2016
  • A thermal storage systems was designed to correspond to the temporal or quantitative variation in the thermal energy demand, and most of its heat is stored using the latent and sensible heat of the heat storage material. The heat storage method using latent heat has a very complex phenomenon for heat transfer and thermal behavior because it is accompanied by a phase change in the course of heating/cooling of the heat storage material. Therefore, many studies have been conducted to produce an experimentally accessible as well as numerical approach to confirm the heat transfer and thermal behavior of phase change materials. The purpose of this study was to investigate the problems encountered during the actual heat transfer from an internal storage tank through simulation of the process of storing and utilizing thermal energy from the thermal storage tank containing charged PCM. This study used analysis methods to investigate the heat transfer characteristics of the PCM with simultaneous heating/cooling conditions in the rectangular space simulating the thermal storage tank. A numerical analysis was carried out in a state considering natural convection using the ANSYS FLUENT(R) program. The result indicates that the slope of the liquid-solid interface in the analysis field changed according to the temperature difference between the heating surface and cooling surface.

상변화 물질을 조합한 히트파이프의 성능 특성에 관한 연구 (A Study on the Performance Characteristics of a Heat Pipe Combined with PCM)

  • 박영학;정의국;부준홍
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2119-2123
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    • 2007
  • This study deals with performance characteristics of heat pipe combined with a solid-liquid phase change material(PCM). The outer diameter of the heat pipe was 9.5 mm and the total length was 600 mm, where the evaporator, the adiabatic section and the condenser lengths were equally 200 mm. A paraffin wax having a melting point of 58.5$^{\circ}C$ was used as PCM. The paraffin container was attached to the adiabatic section of the heat pipe. The paraffin container had outer diameter of 18 mm, wall thickness of 1.2 mm and the total length of 100 mm. The heat pipe was tested with tilt angle of horizontal degree and favorite angle 10 degree, with evaporator lower position to provide stable operation of the heat pipe. Input thermal load was varied from 40 W, with increment of 40 W, to above 100 W until the maximum temperature of the heat pipe wall reached 200$^{\circ}C$. Test results of the PCM heat pipe were presented in comparison with conventional heat pipe of the same basic dimensions. The performance was analyzed in terms of temperature distribution, thermal resistance and heat transport capability.

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자동차 축열시스템의 저장매체에 관한 연구 (A Study on Storage Media of the Heat Storage System for a Vehicle)

  • 김홍철;송연호;이철태
    • 공업화학
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    • 제7권4호
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    • pp.726-734
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    • 1996
  • 본 연구는 $Ba(OH)_2{\cdot}8H_2O$, 나프탈렌, 아세트아미드를 대상으로 이들 물질이 자동차용 축열시스템의 축열매체로서의 사용 가능성여부를 조사하고자 하였다. 이들 물질을 대상으로 고-액상전이 순환과정 동안 상전이에 따른 여러 현상들을 조사하고 축열매체로서 사용되기 위해 위험성없이 재순환시켜 반복할 수 있는 가능성이 조사되었다. 그리고 이들 물질을 안전하게 저장할 수 있는 적절한 저장용기를 찾고자 하였다. 본 연구에서는 이들 물질 중 $Ba(OH)_2{\cdot}8H_2O$가 가장 상안정성이 좋아 자동차용 축열시스템의 축열매체로서의 사용가능성이 높았으며 저장용기는 구리캡슐이 적절하였다.

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PCM물질을 적용한 자연대류형 방열기의 방열특성에 관한 실험적 연구 (An Experimental Study on the Heat Dissipation Characteristics of the Natural Convection Type Radiator by using the PCMs)

  • 성대훈;김민준;김종하;윤재호;김우승;백종현
    • 대한설비공학회:학술대회논문집
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    • 대한설비공학회 2008년도 하계학술발표대회 논문집
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    • pp.1155-1160
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    • 2008
  • In the present study investigated the heat dissipation characteristics of the natural convection type radiator by using the latent heat from a solid-liquid PCM(Phase Change Material). Total radiator volume size is $423{\times}295{\times}83\;mm$ and PCM tank size is $398{\times}270{\times}26\;mm$. The objective was elapsed time lower than maximum operating temperature. Experimental condition, in order to study the effects of the phase-change phenomenon, carried out the various mass flow rate, input electric power, and heat of fusion temperature of two type PCMs. For the above experimental conditions, the cooling performance by using the latent heat showed that heat absorption rate performs for about 3 hours from using PCM $38^{\circ}C$. However, cooling performance by using PCM $50^{\circ}C$ showed higher than surface temperature of heater block because of heat of fusion.

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Effect of phenothiazine derivatives on the thermotropic phase transition of liposomal phospholipid membrane

  • Han, Suk-Kyu;Kim, Nam-Hong;Lee, Yong-Soo
    • Archives of Pharmacal Research
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    • 제9권2호
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    • pp.75-79
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    • 1986
  • The effect of phenothiazine derivatives on the thermotropic transition of liposomal lipid bilayer made of dipalmitoyl phosphatidylchline and dipalmitoyl phosphatidic acid was investigated with differential scanning calorimetry. The thermograms of the liposomal bilayer incorporated with levomepromazine, chlopromazine, prochloperazine, perphenazine and fluphenazine were obtained and the size of cooperative unit of the transition were calculated from the ratio of the van't Hoff enthalpy change to the calculated enthalpy change of the transition. The results showed that incorporation of phenothiazine derivatives into the liposomal bilayer reduced the transition temperature at which the transition from solid state to liquid-crystalline state occurs, and broadened the thermogram peaks. Phenothiazine derivatives also significantly reduced the size of cooperative unit of the transition. The effect of the drugs was proportional to the concentration of the drug in the bilayer. This means that phenothiazine derivatives might have significant fluidizing effects on the biomembrane. The sizes of cooperative unit were successfully corrlated with phar-macological activities of the drugs and the surface pressure increases of lipid monolayer by these drugs. These correlations might be ascribed to a possible hydrophobic nature of interaction between the biomembrane and the drugs involved in their pharmacology.

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비등온 평판의 이성분 합금 냉각코팅에 관한 수치해석 (A Numerical Analysis on the Freeze Coating of a Non-Isothermal Flat Plate with a Binary Alloy)

  • 남진현;김찬중
    • 대한기계학회논문집B
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    • 제24권11호
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    • pp.1437-1446
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    • 2000
  • A numerical analysis on the freeze coating process of a non-isothermal finite dimensional plate with a binary alloy is performed to investigate the growth and decay behavior of the solid and the mushy layer of the freeze coat and a complete procedure to calculate the process is obtained in this study. The continuously varying solid and mushy layers are immobilized by a coordinate transform and the resulting governing differential equations are solved by a finite difference technique. To account for the latent heat release and property change during solidification, proper phase change models are adopted. And the convection in the liquid melt is modeled as an appropriate heat transfer boundary condition at the liquid/mushy interface. The present results are compared with analytic solutions derived for the freeze coating of infinite dimensional plates and the discrepancy is found to be less than 0.5 percent in relative magnitude for all simulation cases. In addition the conservation of thermal energy is checked. The results show that the freeze coat grows proportional to the 1.2 square of axial position as predicted by analytic solutions ar first. But after the short period of initial growth, the growth rate of the freeze coat gradually decreases and finally the freeze coat starts to decay. The effects of various non-dimensional processing parameters on the behavior of freeze coat are also investigated.

Rheological Behavior of Lyotropilc Solutions of Cellulose in the $NH_3/NH_4SCN$ Solvent System

  • Jo, Jae-Jeong;Cuculo, J.A.;Theil, M.H.
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1990년도 제2차 학술발표초록집
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    • pp.36-37
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    • 1990
  • In the past, facile dissolution of cellulose has been hampered by the lack of suitable nondegrading solvents. Recently, this problem has been solved in our laboratory by the discovery of an inexpensive, convenient solvent system, that is the mixture of $NH_3\;and\;NH_4SCN$, for cellulose. Also, the $cellulose/NH_3/NH_4SCN$ solution system has been found to form the anisotropic, i.e., liquid crystalline phase. It is believed that both the cholesterio and the nematic phase occur. This finding has prompted extensive on-going researoh on the formation of the liquid crystalline phase from an inexpensive natural source such as cellulose since the nematic phase is envisioned as an excellent precursor sources for products with desirable properties, for example, high modulus and high strength. This interest naturally leads to a desire to understand the theological properties of the nematic phase so that the transformation of the nematic phase to the solid state with desirable properties can be efficiently accomplished, ;From this point of view, the theological behavior of the $cellulose/NH3_/NH_4SCN$ system has been studied as a function of shear rate and shear stress over a wide range of solvent compositions, cellulose concentration, centrifugation and urea contents, Results indicate that the viscosity decreases with increasing shear rate. A marked shear thinning behavior and a quasi-Newtonian behavior were observed in the low shear rate region and in the high shear rate region, respectively for all solvent compositions. The $cellulose/NH_3/NH_4SCN$ solution system only exhibited the viscosity increase with increasing cellulose concentration and failed to show the viscosity drop generally observed at the point of incipience of liquid crystal formation, This may be due to the gel-like nature of the solution by the association of the rodlike molecules into bundles which may serve as crosslinking points giving the cellulose solution a network structure. Also, simply hydrogen bonding may be so restrictive of molecular mobility that a viscosity drop is blocked. In addition to the above results, yield stress and thixotropy were also observed in the $cellulose/NH_3/NB_4SCN$ solution system which are characteristics of liquid crystal and gel, The results of the effect of centrifugation on viscosity show that viscosity decreases by the application of centrifugation. This may be explained by the change of the piled polydomain structure to the dispersed polydomain structure due to the pressure gradient generated during centrifugation.ation.

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과포정계 합금의 응고조직에 미치는 대류의 영향 (Effect of Convection on the Solidification Microstructure of Hyper-Peritectic Systems)

  • 박병규;김무근;박장식;김근오;최재광
    • 대한기계학회논문집B
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    • 제25권7호
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    • pp.958-966
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    • 2001
  • This study has examined the microstructural development in the Bridgman type directional solidification of hyper-peritectic Sn-Cd alloys, and the temperature and flow field have been numerically simulated to see if there is any change induced by convection. The directional solidification experiments carried out in quartz tubes with inside diameters of 0.4∼6mm showed that the resulting microstructures are clearly dependent on the size of tube diameters. The bigger ampoules where the effect of convection is highly expected produced saw-like structures resulting from the primary $\alpha$ and peritectic $\beta$ phase growing together at a planar solid-liquid front, with the former being surrounded by the latter. In the smaller ampoules, where the effect of convection is expected low however, the saw structure disappears, and as is understood from the theoretical prediction based on diffusion-controlled solidification the initial growth of the primary $\alpha$ phase is replaced by the nucleation of the peritectic $\beta$ phase whose growth continues to the end of the solidification.

고정격자계에서 유한체적법을 이용한 진공동결건조 과정의 열 및 물질전달에 대한 연구 (A Fixed Grid Finite Volume Analysis of Multi-Dimensional Freeze Drying Process under Vacuum Condition)

  • Chi-Sung, Song
    • Journal of Advanced Marine Engineering and Technology
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    • 제28권6호
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    • pp.981-992
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    • 2004
  • Freeze drying under vacuum condition is a complex process that involves simultaneous heat and mass transfer, sublimation of ice, and motion of sublimation front. Proper treatment of the motion of sublimation interface is crucial for an accurate prediction of the freeze drying process. Based on the enthalpy formulation that has been successfully used in liquid/solid phase change problems. a fixed grid method. streamlined for the freeze drying analysis. was developed in this study. The accuracy of the fixed grid method was checked by solving a one-dimensional tray freeze drying and a two-dimensional vial freeze drying problem and then comparing the results with those by the moving grid method. Finally. the freeze drying characteristics of two-dimensional slab and axis-symmetric cylinder was investigated using the fixed grid method.

미립피복 로릭산 슬러리의 관내 대류 열전달에 관한 연구 (A study on convective heat transfer with microcapsulated lauric acid slurry in circular pipe)

  • 정동주;최은수
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.1554-1559
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    • 2003
  • The objective of the present study is to reveal thermal characteristic of microcapsulated lauric acid slurry, which have high latent heat during phase change from solid to liquid, in circular pipe. Test were performed with microcapsulated lauric acid slurry in a heating test section with a constant heat flux boundary condition. Local Nusselt number and the effective thermal capacity were measured. As the size of microcapsulated lauric acid were increased, Local Nusselt number of microcapsulated lauric acid slurry were increased. The effective thermal capacity of microcapsulated lauric acid slurry was 0.5 times than it of water

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