• Title/Summary/Keyword: Solid surface

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Fundamental Process Development for Bio-degradable Polymer Deposition and Fabrication of Post Surgical Anti-adhesion Barrier Using the Process (생분해성 고분자 용착을 위한 기반 공정 개발과 이를 이용한 수술 후 유착 방지막의 제작)

  • Park, Suk-Hee;Kim, Hyo-Chan;Kim, Taek-Gyoung;Jung, Hyun-Jeong;Park, Tae-Gwan;Yang, Dong-Yol
    • Journal of the Korean Society for Precision Engineering
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    • v.24 no.4 s.193
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    • pp.138-146
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    • 2007
  • Some biodegradable polymers and other materials such as hydrogels have shown the promising potential for surgical applications. Post surgical adhesion caused by the natural consequence of surgical wound healing results in repeated surgery and harmful effects. Recently, scientists have developed absorbable anti-adhesion barriers that can protect a tissue from adhesion in case they are in use; however, they are dissolved when no longer needed. Although these approaches have been attempted to fulfill the criteria for adhesion prevention, none can perfectly prevent adhesions in all situations. Overall, we developed a new method to fabricate an anti-adhesion membrane using biodegradable polymer and hydrogel. It employed a highly accurate three-dimensional positioning system with pressure-controlled syringe to deposit biopolymer solution. The pressure-activated microsyringe was equipped with fine-bore nozzles of various inner-diameters. This process allowed that inner and outer shapes could be controlled arbitrarily when it was applied to a surgical region with arbitrary shapes. In order to fulfill the properties of the ideal barriers f3r preventing postoperative adhesion, we adopted the pre-mentioned method combined with surface modification with the hydrogel coating by which anti-adhesion property was improved.

Basic Study on the Image Instrument of the Facial-form by the 3D-facial Scanner (얼굴스캐너를 활용한 안면형상 영상진단기의 기초 연구)

  • Kim, Gyeong-Cheol;Lee, Jeong-Won;Kim, Hoon;Shin, Soon-Shik;Lee, Hai-Woong;Lee, Yong-Tae;Chi, Gyoo-Yong;Kim, Jong-Won
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.22 no.2
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    • pp.497-501
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    • 2008
  • 3D facial scanner for an accurate analysis is measured precisely a distance in straight, a distance in curved line, an angle in 3D data, the area of surface. We can easy acquire 3D data by the method of 0.8sec in each scan with easy handling, simple merge to whole face, harmless and fast process. In the HyungSang medicine, the inspection of the facial shape includes the Dam(gall bladder) - Bang Kwang(urinary bladder) body, the Jung${\cdot}$Gi${\cdot}$Shin${\cdot}$Hyul, the six merdian types etc. And we will collect the evidence based date verifing in the HyungSang clinical medicine. As we will analyze the facial whole form and the size${\cdot}$length${\cdot}$angle of the facial part, put the facial form's standardization on a solid foundation.

Characteristics of Level of Perchlorate Pollution near Military Facility Areas (군사시설물 인근지역에서의 퍼클로레이트 오염수준 및 특성)

  • Choi, Jinsu;Um, Chul Yong;Chu, Kyoung Hoon;Ham, Seok Heon;Lee, Jong Hyeok;Yoo, Sung Soo;Ko, Kwang Baik
    • Journal of Korean Society on Water Environment
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    • v.28 no.3
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    • pp.460-466
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    • 2012
  • Perchlorate is used in a number of applications as an oxidizer in solid propellants, munitions and fireworks and is one of the endocrine disrupting chemicals, which interferes with iodide uptake into the thyroid gland. The purpose of this study was to investigate perchlorate occurrence and distribution with a results of analysis of 94 samples collected from military facilities in Korea from October 11 to October 23, 2011. Overall, among all of the 94 samples analyzed, perchlorate was detected in 6.4% of the total number of samples above $4{\mu}g/L$ (minimum reported limit) and the average concentration was $26.1{\mu}g/L$ and the maximum concentration was $107.7{\mu}g/L$ which was observed in surface water near manufacturing site of ammunition. By site classification, perchlorate was detected at one site in 4 manufacturing sites of ammunition and the maximum concentration was $107.7{\mu}g/L$ which was six times higher than that in guideline for perchlorate in Nakdong River and resulted from point source discharge. Perchlorate was detected at 3 sites in 78 measurements for shooting area and the maximum concentration was $12.4{\mu}g/L$ which was collected in dringking water and perchlorate in another sample was detected above MRL in shooting area was collected right away after shooting. These results showed that long term monitoring was needed considering weather conditions and shooting schedules.

Investigation of Bending Stiffness of Porous Shell Structures Fabricated by 3D Printing (3차원 프린팅으로 제작된 다공성 박판 구조물의 굽힘강성 고찰)

  • Lim, Yeong-Eun;Park, Keun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.41 no.6
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    • pp.491-497
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    • 2017
  • In recent years, 3D printing has received increasing attention due to its potential for direct fabrication beyond the traditional rapid prototyping. 3D printing has the advantage of being able to manufacture complicated shapes that were thought impossible to produce by traditional manufacturing processes. This advantage has driven applications of 3D printing to direct manufacturing of functional parts, such as lightweight structures and component integration. In this study, a porous shell structure is designed for the purpose of weight reduction and ventilation. Finite element (FE) analyses are performed to compare the effective stiffness of the porous structure with the conventional solid structure. Structural reinforcements are also considered in order to make up the stiffness reduction due to the porosity, and the relevant FE analyses are performed to investigate the effect of the reinforcement design on the bending stiffness. The optimized reinforced structure is then proposed through response surface analysis.

Dielectric and Pyroelectric Properties for 0.65PbMg1/3Ta2/3)O3-0.35PbTiO3 Solid Solution Modified with Ag2O (Ag2O가 첨가된 0.65PbMg1/3Ta2/3)O3-0.35PbTiO3 고용체의 유전, 초전 특성)

  • Kim, G.B.
    • Journal of the Korean Vacuum Society
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    • v.17 no.5
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    • pp.442-447
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    • 2008
  • Ferroelectric samples of the 0.65Pb$(Mg_{1/3}Ta_{2/3})O_3-0.35PbTiO_3$ modified with $Ag_2O$ were prepared by sintering at $1200^{\circ}C$ for 4 h. The fractured surface of sintered pellets were examined by scanning electron microscopy(SEM). The dielectric constant, loss, and pyroelectric coefficient of the ceramics samples were determined. The dielectric and pyroelectric properties could be improved with the addition of small amount of $Ag_2O$ up to 0.2 mol%. The dielectric and pyroelectirc peak temperatures are continuously shifted to lower temperature with addition of small amounts of $Ag_2O$.

Thermodynamic Control in Competitive Anchoring of N719 Sensitizer on Nanocrystalline $TiO_2$ for Improving Photoinduced Electrons

  • Lim, Jong-Chul;Kwon, Young-Soo;Song, In-Young;Park, Sung-Hae;Park, Tai-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.68-69
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    • 2011
  • The process of charge transfer at the interface between two semiconductors or between a metal and a semiconductor plays an important role in many areas of technology. The optimization of such devices requires a good theoretical description of the interfaces involved. This, in turn, has motivated detailed mechanistic studies of interfacial charge-transfer reactions at metal/organic, organic/organic, and organic/inorganic semiconductor heterojunctions. Charge recombination of photo-induced electron with redox species such as oxidized dyes or triiodide or cationic HTM (hole transporting materials) at the heterogeneous interface of $TiO_2$ is one of main loss factors in liquid junction DSSCs or solid-state DSSCs, respectively. Among the attempts to prevent recombination reactions such as insulating thin layer and lithium ions-doped hole transport materials and introduction of co-adsorbents, although co-adsorbents retard the recombination reactions as hydrophobic energy barriers, little attention has been focused on the anchoring processes. Molecular engineering of heterogeneous interfaces by employing several co-adsorbents with different properties altered the surface properties of $TiO_2$ electrodes, resulting to the improved power conversion efficiency and long-term stability of the DSSCs. In this talk, advantages of the coadsorbent-assisted sensitization of N719 in preparation of DSSCs will be discussed.

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바이오 센서 응용을 위한 Tree-like 실리콘 나노와이어의 표면성장 및 특성파악

  • An, Chi-Seong;Kulkarni, Atul;Kim, Ho-Jung;Kim, Tae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.346-346
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    • 2011
  • 실리콘 나노와이어는 높은 표면적으로 인해 뛰어난 감지 능력을 가지는 재료 중 하나로 다양한 센서 응용 분야에 사용되고 있다. 이를 제작하는 방법에는 Micro Electro Mechanical Systems (MEMS) 공정을 이용한 Top-down 방식과 Vapor-Liquid-Solid (VLS) 공정을 이용한 Bottom-up 방식이 널리 사용되고 있다. 특히 Plasma-Enhanced Chemical Vapor Deposition(PECVD)와 Au 촉매를 이용한 Bottom-up 방식은 수십 나노미터 이하의 실리콘 나노와이어를 간단한 변수 조절을 통해 성장시킬 수 있다. 또한 Au/Si의 공융점인 363$^{\circ}C$보다 낮은 온도에서 $SiH_4$를 분해시킬 수 있어 열적 효과로 인한 손실을 줄일 수 있는 장점을 지니고 있다. 하지만 PECVD를 이용한 실리콘 나노와이어 성장은 VLS 공정을 통해 표면으로부터 수직으로 성장하게 되는데 이는 센서 응용을 위한 전극 사이의 수평 연결 어려움을 지니고 있다. 따라서 이를 피하기 위한 표면 성장된 실리콘 나노와이어가 요구된다. 본 연구에서는 PECVD VLS 공정을 이용하여 $HAuCl_4$를 촉매로 이용한 표면 성장된 Tree-like 실리콘 나노와이어를 성장시켰다. 공정가스로는 $SiH_4$와 이를 분해시키기 위해 Ar 플라즈마를 사용 하였고 웨이퍼 표면에 HAuCl4를 분사하고 고진공 상태에서 챔버 기판을 370$^{\circ}C$까지 가열한 후 플라즈마 파워(W) 및 공정 압력(mTorr)을 변수로 두어 실험을 진행하였다. 기존의 보고된 연구와 달리 환원된 금 입자 대신 $HAuCl_4$용액을 그대로 사용하였는데 이는 표면 조도(Surface roughness)를 가지는 Au 박막 상태로 존재하게 된다. 이 중 마루(Asperite) 부분에 PECVD로부터 발생된 실리콘 나노 입자가 상대적으로 높은 확률로 흡착하게 되어 실리콘 나노와이어의 표면성장을 유도하게 된다. 성장된 실리콘 나노와이어는 SEM과 EDS를 이용하여 직경, 길이 및 화학적 성분을 측정하였다. 직경은 약 100 nm, 길이는 약 10 ${\mu}m$ 정도로 나타났으며 Tree-like 실리콘 나노와이어가 성장되었다. 향후 전극이 형성된 기판위에 이를 직접 성장시킴으로써 이 물질의 I-V 특성을 파악 할 것이며 이는 센서 응용 분야에 도움이 될 것으로 기대된다.

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Identification and Characterization of Myxobacteria from Korean Soil (국내토양에서 분리한 점액세균의 동정및 특성)

  • 김재헌;손승렬
    • Korean Journal of Microbiology
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    • v.37 no.4
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    • pp.239-244
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    • 2001
  • We isolated a Myxobacteria strain from a soil sample obtained from Mt. Daedoon located in Choongnam, Korea. This strain, ARJ, secreted slime while swarmed on the surface of CT medium. It produced greenish yellow pigment in liquid or solid media, and the swarming edge showed green florescence under U. V. at 366 nm. It formed fruiting bodies when nutrient was exhausted, which is one of the most imkportant characteristics of Myxobacteria. The fruiting bodies did not have a stalk and consisted of naked myxospores when examined under the scanning electron microscope. These traits lead us to believe that this strain is very close to Myxococcus virescens. It showed antimicrobial activity, especially against Gram positive bacteria. Culture filtrate showed the activity but this was not due to protein. The culture filtrate also had proteolytic activity in which at least two enzymes are involved.

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A Synthesis of $(Ba_{1-x}Sr_x)TiO_3$ Powders by Sol-Gel Route (졸-겔법을 이용한$(Ba_{1-x}Sr_x)TiO_3$분말합성)

  • Kim, Young-Seok;Kim, Duk-Jun;Kim, Hwan
    • Korean Journal of Materials Research
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    • v.2 no.2
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    • pp.151-156
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    • 1992
  • Using $Ba(OH)_2{\cdot}8H_2O, \;Sr(OH)_2{\cdot}8H_2O$ and $Ti(i-OC_3H_7)_4$, fine $(Ba_{1-x}, \;Sr_{x})TiO_3$ powders were synthesized through sol-gel process. The particle size of the powders calcined at $700^{\cric}C$ proved to be 20-40nm by the observation of TEM micrographs and measurement of BET specific surface area. The analysis of XRD patterns showed that the phase of the powders was cubic, and it was identified with the lattice parameters determined through XRD patterns and the shift of (112) peaks that the solid solution powders were synthesized. It was expected through the analysis of relative ratio of cations and the uniformity of compositions in the powders examined by EDAX analysis and relative dielectric constant measurements for sintered body that the distribution of cations was uniform in particle unit.

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Size Tailored Nanoparticles of ZrN Prepared by Single-Step Exothermic Chemical Route

  • Lee, Sang-Ki;Park, Kyung-Tae;Ryu, Hong-Youl;Nersisyan, Hayk H.;Lee, Kap-Ho;Lee, Jong-Hyeon
    • Korean Journal of Materials Research
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    • v.22 no.5
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    • pp.243-248
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    • 2012
  • ZrN nanoparticles were prepared by an exothermic reduction of $ZrCl_4$ with $NaN_3$ in the presence of NaCl flux in a nitrogen atmosphere. Using a solid-state combustion approach, we have demonstrated that the zirconium nitride nanoparticles synthesis process can be completed in only several minutes compared with a few hours for previous synthesis approaches. The chemistry of the combustion process is not complex and is based on a metathesis reaction between $ZrCl_4$ and $NaN_3$. Because of the low melting and boiling points of the raw materials it was possible to synthesize the ZrN phase at low combustion temperatures. It was shown that the combustion temperature and the size of the particles can be readily controlled by tuning the concentration of the NaCl flux. The results show that an increase in the NaCl concentration (from 2 to 13 M) results in a temperature decrease from 1280 to $750^{\circ}C$. ZrN nanoparticles have a high surface area (50-70 $m^2/g$), narrow pore size distribution, and nano-particle size between 10 and 30 nm. The activation energy, which can be extracted from the experimental combustion temperature data, is: E = 20 kcal/mol. The method reported here is self-sustaining, rapid, and can be scaled up for a large scale production of a transition metal nitride nanoparticle system (TiN, TaN, HfN, etc.) with suitable halide salts and alkali metal azide.