Characteristics of Level of Perchlorate Pollution near Military Facility Areas

군사시설물 인근지역에서의 퍼클로레이트 오염수준 및 특성

  • Choi, Jinsu (School of Civil & Environmental Engineering, Yonsei University) ;
  • Um, Chul Yong (School of Civil & Environmental Engineering, Yonsei University) ;
  • Chu, Kyoung Hoon (School of Civil & Environmental Engineering, Yonsei University) ;
  • Ham, Seok Heon (School of Civil & Environmental Engineering, Yonsei University) ;
  • Lee, Jong Hyeok (School of Civil & Environmental Engineering, Yonsei University) ;
  • Yoo, Sung Soo (School of Civil & Environmental Engineering, Yonsei University) ;
  • Ko, Kwang Baik (School of Civil & Environmental Engineering, Yonsei University)
  • 최진수 (연세대학교 토목.환경공학과) ;
  • 엄철용 (연세대학교 토목.환경공학과) ;
  • 주경훈 (연세대학교 토목.환경공학과) ;
  • 함석헌 (연세대학교 토목.환경공학과) ;
  • 이종혁 (연세대학교 토목.환경공학과) ;
  • 유성수 (연세대학교 토목.환경공학과) ;
  • 고광백 (연세대학교 토목.환경공학과)
  • Published : 2012.05.30

Abstract

Perchlorate is used in a number of applications as an oxidizer in solid propellants, munitions and fireworks and is one of the endocrine disrupting chemicals, which interferes with iodide uptake into the thyroid gland. The purpose of this study was to investigate perchlorate occurrence and distribution with a results of analysis of 94 samples collected from military facilities in Korea from October 11 to October 23, 2011. Overall, among all of the 94 samples analyzed, perchlorate was detected in 6.4% of the total number of samples above $4{\mu}g/L$ (minimum reported limit) and the average concentration was $26.1{\mu}g/L$ and the maximum concentration was $107.7{\mu}g/L$ which was observed in surface water near manufacturing site of ammunition. By site classification, perchlorate was detected at one site in 4 manufacturing sites of ammunition and the maximum concentration was $107.7{\mu}g/L$ which was six times higher than that in guideline for perchlorate in Nakdong River and resulted from point source discharge. Perchlorate was detected at 3 sites in 78 measurements for shooting area and the maximum concentration was $12.4{\mu}g/L$ which was collected in dringking water and perchlorate in another sample was detected above MRL in shooting area was collected right away after shooting. These results showed that long term monitoring was needed considering weather conditions and shooting schedules.

Keywords

References

  1. 기상청(2011). 기상월보, 11-1360000-000002-06, pp. 2-7.
  2. 김신조, 이기용, 이기철, 박상민, 권오상, 정동일(2010). 아연 제련소 무기성폐수 중 간섭이온이 생물학적 퍼클로레이트 처리에 미치는 영향, 수질보전 한국물환경학회지, 26(5), pp. 768-774.
  3. 김현구, 김정화, 이연희(2007). 국내 주요 정수장 수돗물의 퍼클로레이트 검출현황, 수질보전 한국물환경학회지, 23(6), pp. 822-828.
  4. 김현구, 김정화, 이연희, 이재호, 김산(2008). 고도정수처리 과정에서 퍼클로레이트 이온의 농도 변화, 수질보전 한국물환경학회지, 24(2), pp. 164-168.
  5. 손희종, 정철우(2007). 낙동강 수계에서의 Perchlorate 검출 및 활성탄 공정에 의한 제거특성, 대한환경공학회지, 29(4), pp. 438-443.
  6. 정혜진(2007). Perchlorate 주요 오염원 인근 지역에서의 실태조사, 석사학위논문, 서울대학교, pp. 35-44.
  7. 환경부(2006). http://www.me.go.kr/.
  8. EPA (1999). Method 314.0 Determination of Perchlorate in Drinking Water Using Ion Chromatography, Revision, pp. 9-33.
  9. EPA (2009). Interim Drinking Water Health Adivisory for Perchlorate, EPA 822-R-08-025, Washington, DC:US Environmental Protection Agency, pp. 12-34.
  10. EPA (2011). Final Regulatory Determination for Perchlorate. EPA Fact Sheet, EPA 815-F-11-003, pp. 1-2.
  11. EPA Federal Facilities Restoration and Reuse Office (FFRRO) (2005). Perchlorate Treatment Technology Update - Federal Facilities Forum Issue Paper, EPA 542-R-05-015, pp. 4-7.
  12. EPA Federal Facilities Restoration and Reuse Office (FFRRO) (2007). http://www.epa.gov/fedfac/.
  13. GAO (2005). Perchlorate : A System to Track Sampling and Cleanup Results is Needed, GAO-05-462, pp. 2-9
  14. Interstate Technology & Regulatory Council (ITRC) Perchlorate Team (2005). Perchlorate: Overview of Issues, Status, and Remedial Options, pp. 5-24.
  15. Mendiratta, S. K., Dotson, R. L., and Brooker, R. T. (1996). Kirk-Othmer Encyclopedia of Chemical Technology, 18, pp. 157-170.
  16. Murray, C. W., Egan, S. K., Kim, H., Beru, N., and Bolger, P. M. (2008). U.S. Food and Drug Administration's Total Diet Study : Dietary Intake of Perchlorate and Iodine, Journal of Exposure Science and Environmental Epidemiology, 18, pp. 571-580. https://doi.org/10.1038/sj.jes.7500648
  17. NAS (2005). Health Implications of Perchlorate Ingestion, pp. 35-74.
  18. Rajaqopalan, S., Anderson, T. A., Fahlquist, L., Rainwater, K. A., Ridley, M., and Jackson, W. A. (2006). Widespread Presence of Naturally occurring Perchlorate in High Plains of Texas and New Mexico, Environmental Science and Technology, 40, pp. 3156-3162. https://doi.org/10.1021/es052155i
  19. Susarla, S., Bacchus, S., Wolfe, N. L., and McCutcheon, S. C. (1999). Potential Species for Phytoremediation of Perchlorate, EPA-600-R-99-069, pp. 21-35.
  20. U.S. Department of Defense Material of Evolving Regulatory Interest Team (DoD MERIT) (2011). Emerging Contaminants Program Basics, http://www.denix.osd.mil/perchloratesummaries/.