• Title/Summary/Keyword: Solid surface

Search Result 2,428, Processing Time 0.025 seconds

Adsorption Behavior of PAHs in Cigarette Smoke on Glass Beads - Effect of Plasma Polymerization Coating (담배 연기 내 PAH의 유리입자에 대한 흡착거동 - 플라즈마 고분자 중합 코팅 영향)

  • Basarir, Fevzihan;Rhee, Moon-Soo;Lee, Young-Taek;Yoon, Tae-Ho
    • Journal of Adhesion and Interface
    • /
    • v.11 no.4
    • /
    • pp.137-143
    • /
    • 2010
  • Glass beads (GBs) were modified via plasma polymerization coatings in order to enhance the adsorption of polycyclic aromatic hydrocarbons (PAHs) in cigarette smoke and activated carbons (ACs) were also utilized for comparative purposes. First, GBs and ACs were subjected to surface modification via plasma polymerization coating of acrylic acid, acrylonitrile, 1,3-diaminopropane, thiophene or dimethylphosphite with a RF plasma (13.56 MHz) generator. Next, their adsorption behavior was evaluated with a home-made 4-port smoking machine by collecting the total particulate matters (TPMs) on a Cambridge filter pad, followed by the separation of PAHs via solid phase extraction and analysis with GC/MS. Finally, the plasma polymerization coatings were analyzed by FT-IR/ATR to elucidate the adsorption mechanism, while the topology of the modified GBs and ACs were studied by FE-SEM.

A local-global scheme for tracking crack path in three-dimensional solids

  • Manzoli, O.L.;Claro, G.K.S.;Rodrigues, E.A.;Lopes, J.A. Jr.
    • Computers and Concrete
    • /
    • v.12 no.3
    • /
    • pp.261-283
    • /
    • 2013
  • This paper aims to contribute to the three-dimensional generalization of numerical prediction of crack propagation through the formulation of finite elements with embedded discontinuities. The analysis of crack propagation in two-dimensional problems yields lines of discontinuity that can be tracked in a relatively simple way through the sequential construction of straight line segments oriented according to the direction of failure within each finite element in the solid. In three-dimensional analysis, the construction of the discontinuity path is more complex because it requires the creation of plane surfaces within each element, which must be continuous between the elements. In the method proposed by Chaves (2003) the crack is determined by solving a problem analogous to the heat conduction problem, established from local failure orientations, based on the stress state of the mechanical problem. To minimize the computational effort, in this paper a new strategy is proposed whereby the analysis for tracking the discontinuity path is restricted to the domain formed by some elements near the crack surface that develops along the loading process. The proposed methodology is validated by performing three-dimensional analyses of basic problems of experimental fractures and comparing their results with those reported in the literature.

Analysis of PCM Wallboards Design Parameters using Dynamic Energy Simulation (동적 에너지 시뮬레이션을 이용한 PCM보드의 설계변수 분석에 관한 연구)

  • Lee, Jin-Uk;An, Sang-Min;Kim, Taeyeon;Lee, Seung-Bok
    • KIEAE Journal
    • /
    • v.12 no.4
    • /
    • pp.97-104
    • /
    • 2012
  • A phase-change material is a substance with a high heat of fusion which, melting and freezing at a certain temperature, is capable of storing and releasing large amounts of energy. Heat is absorbed or released when the material changes from solid to liquid. Therefore, PCMs are classified as latent heat storage (LHS) units. The purpose of this study is to analyze PCM wallboard design parameters using dynamic energy simulation. Among the factors of PCM, melting temperature, latent heat, phase change range, thermal conductivity are very important element to maximize thermal energy storage. In order to analyze these factors, EnergyPlus which is building energy simulation provided by department of energy from the U.S is used. heat balance algorithm of energy simulation is conduction finite difference and enthalpy-temperature function is used for analyzing latent heat of PCM. The results show that in the case of melting temperature, the thermal energy storage could be improved when the melting temperature is equal to indoor surface temperature. It seems that when the phase change range is wide, PCM can store heat at a wide temperature, but the performance of heat storage is languished.

A Defect Detection of Thin Welded Plate using an Ultrasonic Infrared Imaging (초음파 열화상 검사를 이용한 박판 용접시편의 결함 검출)

  • Cho, Jai-Wan;Chung, Chin-Man;Choi, Young-Soo;Jung, Seung-Ho;Jung, Hyun-Kyu
    • Journal of Institute of Control, Robotics and Systems
    • /
    • v.13 no.11
    • /
    • pp.1060-1066
    • /
    • 2007
  • When a high-energy ultrasound propagates through a solid body that contains a crack or a delamination, the two faces of the defect do not ordinarily vibrate in unison, and dissipative phenomena such as friction, rubbing and clapping between the faces will convert some of the vibrational energy to heat. By combining this heating effect with infrared imaging, one can detect a subsurface defect in material efficiently. In this paper a detection of the welding defect of thin SUS 304 plates using the UIR (ultrasonic infrared imaging) technology is described. A low frequency (20kHz) ultrasonic transducer was used to infuse the welded thin SUS 304 plates with a short pulse of sound for 280ms. The ultrasonic source has a maximum power of 2kW. The surface temperature of the area under inspection is imaged by a thermal infrared camera that is coupled to a fast frame grabber in a computer. The hot spots, which are a small area around the defect tip and heated up highly, are observed. From the sequence of the thermosonic images, the location of defective or inhomogeneous regions in the welded thin SUS 304 plates can be detected easily.

Poly(ethylenimine)-Stabilized Hollow Gold-Silver Bimetallic Nanoparticles: Fabrication and Catalytic Application

  • Shin, Kuan-Soo;Kim, Ji-Hoon;Kim, In-Hyun;Kim, Kwan
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.3
    • /
    • pp.906-910
    • /
    • 2012
  • Hollow gold-silver bimetallic nanoparticles (AuAg-HNPs) have been synthesized and their optical and structural properties were characterized. Initially Ag nanoparticles (Ag-NPs) were prepared using poly(ethylenimine) (PEI) as a reducing and a stabilizing agent simultaneously. AuAg-HNPs could then be synthesized via galvanic replacement reaction in a PEI aqueous solution by reacting sacrificial Ag template with a precursor compound of Au, i.e., $HAuCl_4$. Due to the presence of abundant amine functional groups in PEI, which could act as the dissolving ligand for AgCl, the precipitation problem of $Ag^+$ in the presence of Cl from $HAuCl_4$ salt was avoided. On this basis, the relatively high concentrations of $HAuCl_4$ and PEI-stabilized Ag nanoparticles could be used for the fabrication of AuAg-HNPs. Because of their increased surface areas and reduced densities, the AuAg-HNPs were expected and confirmed to outperform their solid counterparts in applications such as catalysis for the reduction of 4-nitrophenol in the presence of $NaBH_4$.

Comparative Study on Adsorptive Characteristics of Diazinon in Water by Various Adsorbents

  • Ryoo, Keon Sang;Jung, Sun Young;Sim, Hun;Choi, Jong-Ha
    • Bulletin of the Korean Chemical Society
    • /
    • v.34 no.9
    • /
    • pp.2753-2759
    • /
    • 2013
  • The aim of the present study is to explore the possibility of utilizing fly ash and loess, as alternative to activated carbon, for the adsorption of diazinon in water. Batch adsorption experiment was performed to evaluate the influences of various factors like initial concentration, contact time and temperature on the adsorption of diazinon. The adsorption data shows that fly ash is not effective for the adsorption of diazinon. The equilibrium data for both activated carbon and loess were fitted well to the Freundlich isotherm model. The pseudo-second-order kinetic model appeared to be the better-fitting model because it has higher $R^2$ compared to the pseudo-first-order kinetic model. The thermodynamic parameters such as free energy (${\Delta}G$), the enthalpy (${\Delta}H$) and the entropy (${\Delta}S$) were calculated. Contrary to loess, the ${\Delta}G$ values of activated carbon were negative at the studied temperatures. It indicates that the adsorption of diazinon by activated carbon is a favorable and spontaneous process. The positive ${\Delta}H$ values of activated carbon and loess suggest that the diazinon adsorption process is endothermic in nature. In addition, the positive ${\Delta}S$ values show that increased randomness occurs at the solid/solution surface during the adsorption of diazinon.

The Design and Fabrication of RESURF type SOI n-LDMOSFET (RESURF type의 SOI n-LDMOSFET 소자 설계 및 제작)

  • Kim, Jae-Seok;Kim, Beom-Ju;Koo, Jin-Gen;Koo, Yong-Seo;An, Chul
    • Proceedings of the IEEK Conference
    • /
    • 2004.06b
    • /
    • pp.355-358
    • /
    • 2004
  • In this work, N-LDMOSFET(Lateral Double diffused MOSFET) was designed and fabricated on SOI(Silicon-On-Insulator) substrate, for such applications as motor controllers and high voltage switches, fuel injection controller systems in automobile and SSR(Solid State Rexay)etc. The LDMOSFET was designed to overcome the floating body effects that appear in the conventional thick SOI MOS structure by adding p+ region in source region. Also, RESURF(Reduced SURface Field) structure was proposed in this work in order to reduce a large on-resistance of LDMOSFET when operated keeping high break down voltage. Breakdown voltage was 268v in off-state ($V_{GS}$=OV) at room temperature in $22{\mu}m$ drift length LDMOSFET. When 5V of $V_{GS}$ and 30V of $V_{DS}$ applied, the on resistance(Ron), the transcon ductance($G_m$) and the threshold voltage($V_T$) was 1.76k$\Omega$, 79.7uA/V and 1.85V respectively.

  • PDF

Sn계 무연 솔더에 관한 연구

  • 이창배;정승부;서창제
    • Proceedings of the International Microelectronics And Packaging Society Conference
    • /
    • 2001.11a
    • /
    • pp.75-87
    • /
    • 2001
  • Three different kinds of substrate used in this study : bare Cu substrate, Ni-P/Cu substrate with a Ni-P layer thickness of $5\mu\textrm{m},$ and Au/Ni-P/Cu substrate with the Ni-P and Au layers of $0.15\mu\textrm{m}$ and $5\mu\textrm{m}$ thickness respectively. The wettability of various Sn-base solders was affected by the substrate metal finish used, i.e., nickel, gold and copper. On the Au/Ni-F/Cu substrate, Sn-base solders wet better than any of the other substrate metal finishes tested. The interfacial reaction between various substrate and Sn-base solder was investigated at $70^{\circ}C,$ $100^{\circ}C,$ $120^{\circ}C,$ $150^{\circ}C,$ $170^{\circ}C$ and $200^{\circ}C$ for reaction times ranging from 0 day to 60 day. Intermetallic phases was formed along a Sn-base solder/ various substrate interface during solid-state aging. The apparent activation energy for growth of Sn-Ag/Cu, Sn-Ag-Bi/Cu, and Sn-Bi/Cu couples were 65.4, 88.6, and 127.9 Kj/mol, respectively. After isothermal aging, the fracture surface shoved various characteristics depending on aging temperature and time, and the types of BGA pad.

  • PDF

Survey on electrocoagulation to purify contaminated water (전기응고법을 이용한 오염 수 정화)

  • Kim, W.Y.;Park, K.S.;Oh, C.S.
    • Journal of Energy Engineering
    • /
    • v.23 no.3
    • /
    • pp.17-20
    • /
    • 2014
  • A magnetic fluid separation technology was confirmed to be very effective to remove the suspended solids from contaminated water. We have surveyed on the effects of operating variables on the characteristics of suspended solids(SS) removal investigated through the test runs using magnetic powder. Magnetic flocculation here formed by adsorbing fine magnetites on the surface of suspended solid was observed. The strength of magnet was of significance in determining the SS removal efficiency.

Influence of Metallic Sodium on Repair Weldability for Type 316FR Stainless Steel

  • Chun, Eun-Joon;Lee, Su-Jin;Suh, Jeong;Lee, Ju-Seung;Kang, Namhyun;Saida, Kazuyoshi
    • Journal of Welding and Joining
    • /
    • v.35 no.1
    • /
    • pp.79-88
    • /
    • 2017
  • The effect of residual metallic sodium on the solidification cracking susceptibility of type 316FR stainless steel was investigated via transverse-Varestraint tests. And a solidification brittle temperature range (BTR) of type 316FR stainless steel was 37 K. However, the BTR expanded from 37 to 67 K, as the amount of metallic sodium at the specimen surface increased from 0 to $7.99mg/cm^2$. Microstructural observation of the weld metal suggested that metallic sodium existed in the weld metal, including in the cell boundaries, during welding solidification. Thermodynamic calculations suggested that sodium expanded the temperature range of solidliquid coexistence during welding solidification of the steel weld metal. Therefore, the increased solidification cracking susceptibility (i.e., expansion of the BTR) in the residual sodium environment was attributed to enhanced segregation of sodium during the welding solidification; this segregation, in turn, resulted in an expanded temperature range of solid-liquid coexistence.