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Adsorption Behavior of PAHs in Cigarette Smoke on Glass Beads - Effect of Plasma Polymerization Coating  

Basarir, Fevzihan (Department of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST))
Rhee, Moon-Soo (KT&G Central Research Institute)
Lee, Young-Taek (KT&G Central Research Institute)
Yoon, Tae-Ho (Department of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST))
Publication Information
Journal of Adhesion and Interface / v.11, no.4, 2010 , pp. 137-143 More about this Journal
Abstract
Glass beads (GBs) were modified via plasma polymerization coatings in order to enhance the adsorption of polycyclic aromatic hydrocarbons (PAHs) in cigarette smoke and activated carbons (ACs) were also utilized for comparative purposes. First, GBs and ACs were subjected to surface modification via plasma polymerization coating of acrylic acid, acrylonitrile, 1,3-diaminopropane, thiophene or dimethylphosphite with a RF plasma (13.56 MHz) generator. Next, their adsorption behavior was evaluated with a home-made 4-port smoking machine by collecting the total particulate matters (TPMs) on a Cambridge filter pad, followed by the separation of PAHs via solid phase extraction and analysis with GC/MS. Finally, the plasma polymerization coatings were analyzed by FT-IR/ATR to elucidate the adsorption mechanism, while the topology of the modified GBs and ACs were studied by FE-SEM.
Keywords
polycyclic aromatic hydrocarbon; cigarette smoke; plasma polymerization; activated carbon; glass beads;
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