• 제목/요약/키워드: Solid support

검색결과 356건 처리시간 0.028초

화학축냉용 무기염들의 수화반응 및 열 및 물질전달 향상방안 (Study of Hydration Reaction Characteristics of Inorganic Salts for Chemical Cold Storage and Method of Enhancement of Heat and Mass Transfer)

  • 김상욱;한종훈;황용준;이건홍
    • 한국에너지공학회:학술대회논문집
    • /
    • 한국에너지공학회 1999년도 춘계 학술발표회 논문집
    • /
    • pp.185-191
    • /
    • 1999
  • An air-conditioning system based on the chemical heat storage principle was considered. $H_2O$ was chosen as the reaction gas and the working fluid as well. Na$_2$S, CaCl$_2$, MnCl$_2$, BaCl$_2$, MgCl$_2$, Fe$_2$(SO$_4$)$_3$ and MnSO$_4$ were tested as the solid reactants by using Cahn pressure balance. Na$_2$S was superior to other salts in respect of high capability of absorption of water gas, 5 moles of $H_2O$ per unit mole of Na$_2$S, and adequate temperature of adsorption, $65^{\circ}C$ at 7torr, and of desorption, 13$0^{\circ}C$ at 76torr. Clausius-Clapeyron diagram of Na$_2$S was obtained via adsorption experiments at several vapor pressures of water gas. To enhance heat and mass transfer characteristics, usually below 1W/m K, of the reactor bed of general adsorption systems, expanded graphite block was adapted as the support of Na$_2$S salt. Expanded graphite blocks had thermal conductivity values of 20~80W/mK with respect to 100~400kg/㎥ of block bulk density. Permeability values of expanded graphite blocks were 10$^{-13}$ ~ 10$^{-14}$ $m^2$ with respect to 100~300kg/㎥ of block bulk density showing highly decreasing values of permeability, below 10$^{-l4}$$m^2$, in the range of above 150kg/㎥ of block bulk density.y.

  • PDF

공적 가족사업역사 아카이브 구축을 위한 기초 연구 (A Study on the Implementation of Official Family-related Service History Archives in Korea)

  • 김경아;박미석;강복정;이영호;최새은;전지원;김미영
    • 가족자원경영과 정책
    • /
    • 제24권3호
    • /
    • pp.79-102
    • /
    • 2020
  • This study aims to provide basic resources for the construction of the archives on the official family service history in Korea. The study collected records of family policies and official family service from 1948 to 2019 and thereafter attempted to classify the official family service. In addition, experts were consulted to diagnose compliance with research contents and directions, investigate priorities of the family policies, and provide opinions on the elements of each process of archiving. The results of this study were as follows. First, there were five areas of concern to be considered in the process of establishing an archive of official family services: concept, scope, collection, arrangement, preservation, and utilization. Second, the findings suggest which processes are critical to developing a sustainable and systematic archive system for the official family service history. The construction of the archives will provide a platform for understanding the contents of integrated family policies and inform the direction of future family policies in Korea. In addition, these archives will be an important factor in building a solid Korean national identity.

Experimental and numerical investigation of reinforced concrete beams containing vertical openings

  • Parol, Jafarali;Ben-Nakhi, Ammar;Al-Sanad, Shaikha;Al-Qazweeni, Jamal;Al-Duaij, Hamad J.;Kamal, Hasan
    • Structural Engineering and Mechanics
    • /
    • 제72권3호
    • /
    • pp.383-393
    • /
    • 2019
  • Horizontal openings in reinforced concrete (RC) beams are quite often used to accommodate service pipelines. Several research papers are available in the literature describing their effect. RC beams with vertical openings are commonly used to accommodate service lines in residential buildings in Kuwait. However, there are lack of design guidelines and best practices reported in the literature for RC beams with vertical openings, whereas the detailed guidelines are available for beams with horizontal openings. In the present paper, laboratory experiments are conducted on nine RC beams with and without vertical openings. Parametric study has been carried out using nonlinear finite element analysis (FEA) with changes in the diameter of the opening, various positions of the opening along the length and width of the beam, edge distance, etc. 50 finite element simulations were conducted. The FEA results are verified using the results from the laboratory experiments. The study showed that the load carrying capacity of the beam is reduced by 20% for the RC beam with vertical openings placed near the center of the beam compared to a solid beam without an opening. Significant reduction in load carrying capacity is observed for beams with an opening near the support (${\approx}15%$). The overall stiffness of the beam, crack pattern and failure modes were not affected due to the presence of the vertical opening. Furthermore, an artificial neural network (ANN) analysis is carried out using the FEA generated data. The results and observations from the ANN and FEA are in good agreement with experimental results.

Characterization of Rhizophora SPP. particleboards with SOY protein isolate modified with NaOH/IA-PAE adhesive for use as phantom material at photon energies of 16.59-25.26 keV

  • Samson, Damilola Oluwafemi;Shukri, Ahmad;Mat Jafri, Mohd Zubir;Hashim, Rokiah;Sulaiman, Othman;Aziz, Mohd Zahri Abdul;Yusof, Mohd Fahmi Mohd
    • Nuclear Engineering and Technology
    • /
    • 제53권1호
    • /
    • pp.216-233
    • /
    • 2021
  • In this work, Rhizophora spp. particleboard phantoms were made using SPI-based adhesives, modified with sodium hydroxide and itaconic acid polyamidoamine-epichlorohydrin (0, 5, 10, and 15 wt%). An X-ray computed tomography (CT) imaging system was used to ascertain the CT numbers and density distribution profiles of the particleboards. The SPI-based/NaOH/IA-PAE/Rhizophora spp. particleboard phantoms with 15 wt% IA-PAE addition level had the highest solid content, flexural strength, flexural modulus, and internal bonding strength of 36.06 ± 1.08%, 18.61 ± 0.38 Nmm-2, 7605.76 ± 0.89 Nmm-2, and 0.463 ± 0.053 Nmm-2, respectively. The moisture content, mass density, water absorption, and dimensional stability were 6.93 ± 0.27%, 0.962 ± 0.037 gcm-3, 22.36 ± 2.47%, and 10.90 ± 0.86%, respectively. The results revealed that the mass attenuation coefficients and effective atomic number values within the 16.59-25.26 keV photon energy region, were close to the calculated XCOM values in water, with a p-value of 0.077. Moreover, the CT images showed that the dissimilarities in the discrepancy of the profile density decreased as the IA-PAE concentrations increased. Therefore, these results support the appropriateness of the SPI-based/NaOH/IA-PAE/Rhizophora spp. particleboard with 15 wt% IA-PAE adhesive as a suitable tissue-equivalent phantom material for medical health applications.

뇌 기억-학습 원리를 적용한 중등영어교사 임용시험 준비용 어플 (An Exam Prep App for the Secondary English Teacher Recruitment Exam with Brain-based Memory and Learning Principles)

  • 이혜진
    • 한국콘텐츠학회논문지
    • /
    • 제21권1호
    • /
    • pp.311-320
    • /
    • 2021
  • 현재 국내 국·공립 중등교사가 되기 위한 유일한 등용문은 중등교원 임용시험이며 2014학년도 개정 이후 임용시험의 모든 문항이 서답형으로 전환되었기 때문에 더 완성도 높고 정확하고 견고한 답안 작성이 요구된다. 재인기억을 측정하는 선택형 문항과 비교하면 회상기억을 측정하는 서답형 문항의 경우 정보 인출을 위해 더 많은 인지적 노력이 요구된다. 이 때문에 지속적인 암기 및 인출 연습이 필요하지만 이를 수행할 수 있는 학습 도구가 충분하지 않다. 이러한 맥락에서 본고는 중등영어교사 임용시험 준비용 모바일 어플인 ONE PASS를 구현하였다. 본 어플에서는 특히 인지작용의 근간이 되는 뇌의 작용기제를 반영하여 학습용 콘텐츠를 구현하였으며 학습계획 설정 및 동기측정, 마인드맵, 브레인스토밍, 기출문제 등 다양한 기능을 구안하였다. 본 연구는 학습용 어플 콘텐츠 개발 관련 연구에 이바지함과 동시에 임용시험 수험자들에게 조금이나마 도움이 될 수 있기를 기대한다.

Structural and Electrical Properties of (La,Nd,Sr)MnO3 Ceramics for NTC Thermistor Devices

  • Shin, Kyeong-Ha;Park, Byeong-Jun;Lim, Jeong-Eun;Lee, Sam-Haeng;Lee, Myung-Gyu;Park, Joo-Seok;Lee, Sung-Gap
    • 한국전기전자재료학회논문지
    • /
    • 제35권3호
    • /
    • pp.292-296
    • /
    • 2022
  • (La0.5Nd0.2Sr0.3)MnO3 specimens were prepared by a solid-state reaction. In all specimens, X-ray diffraction patterns of an orthorhombic structure were shown. The fracture surfaces of (La0.5Nd0.2Sr0.3)MnO3 specimens showed a transgranular fracture pattern be possibly due to La ions (0.122 nm) as a perovskite A-site dopant substituting for Nd ions (0.115 nm) having a small ionic radius. The full-width at half maximum (FWHM) of the Mn 2p XPS spectra showed a value greater than that [8] of the single valence state, which is believed to be due to the overlapping of Mn2+, Mn3+, and Mn4+ ions. The dependence of Mn 2p spectra on the Mn3+/Mn4+ ratio according to sintering time was not observed. Electrical resistivity resulted in the minimum value of 100.7 Ω-cm for the specimen sintered for 9 hours. All specimens show a typical negative temperature coefficient of resistance (NTCR) characteristics. In the 9-hour sintered specimen, TCR, activation energy, and B25/65-value were -1.24%/℃, 0.19 eV, and 2,445 K, respectively.

Study on the fire resistance of castellated composite beams with ortho-hexagonal holes and different beam-end constraints

  • Junli Lyu;Encong Zhu;Rukai Li;Bai Sun;Zili Wang
    • Steel and Composite Structures
    • /
    • 제46권4호
    • /
    • pp.539-551
    • /
    • 2023
  • In order to study the fire resistance of castellated composite beams with ortho-hexagonal holes and different beam-end restraints, temperature rise tests with constant load were conducted on full-scale castellated composite beams with ortho-hexagonal holes and hinge or rigid joint constraints to investigate the temperature distribution, displacement changes and failure patterns of castellated composite beams with two different beam-end constraints during the whole course of fire. The results show that (1) During the fire, the axial pressure and horizontal expansion deformation generated in the rigid joint constrained composite beam were larger than those in the hinge joint constrained castellated composite beam, and their maximum horizontal expansion displacements were 30.2 mm and 17.8 mm, respectively. (2) After the fire, the cracks on the slab surface of the castellated composite beam with rigid joint constraint were more complicated than hinge restraint, and the failure more serious; the lower flange and web at the ends of the castellated steal beams with hinge and rigid joint constraint produced serious local buckling, and the angles of the ortho-hexagonal holes at the support cracked; the welds at both ends of the castellated composite beam with rigid joint constraint cracked. (3) Based on the simplified calculation method of solid-web composite beam, considering the effect of holes on the web, this paper calculated the axial force and displacement of the beam-end constrained castellated composite beams under fire. The calculation results agreed well with the test results.

Develop a sustainable wet shotcrete for tunnel lining using industrial waste: a field experiment and simulation approach

  • Jinkun Sun;Rita Yi Man Li;Lindong Li;Chenxi Deng;Shuangshi Ma;Liyun Zeng
    • Advances in concrete construction
    • /
    • 제15권5호
    • /
    • pp.333-348
    • /
    • 2023
  • Fast infrastructure development boosts the demand for shotcrete. Despite sand and stone being the most common coarse and fine aggregates for shotcrete, excessive exploration of these materials challenges the ecological environment. This study utilized an industrial solid waste, high-titanium heavy slag, blended with steel fibers to form Wet Shotcrete of Steel Fiber-reinforced High-Titanium Heavy Slag (WSSFHTHS). It investigated its workability, shotcrete performance and mechanical properties under different water-to-cement ratios, fly ash content, superplasticizer dosage, and steel fiber content. The tunnel excavation and support were investigated by conducting finite element numerical simulation analysis and was used in 3 tunnel lining pipes in Zhonggouwan tailing pond. The major findings are as follows: (1) The water-to-cement ratio (w/c ratio) significantly impacted the compressive strength of WSSFHTHS. The highest 28-day compressive strength of 60 MPa was achieved when the w/c ratio was 0.38; (2) Adding fly ash improved the workability and shotcrete performance and strength development of WSSFHTHS. The best anti-permeability performance was achieved when the fly ash constituted 15%, with the lowest permeability coefficient of 4.596 × 10-11 cm/s; (3) The optimum superplasticizer dosage for WSSFHTHS is 0.8%. It provided the best workability and shotcrete performance. Excessive dosage resulted in water bleeding and poor aggregate encapsulation, while insufficient dosage decreased flowability and adversely affected shotcrete performance; (4) The dosage of steel fibers significantly impacted the flexural and tensile strength of WSSFHTHS. When the steel fiber dosage was 45 kg/m3, the 28-day flexural and tensile strengths were 8.95 MPa and 6.15 MPa, respectively; (5) By integrating existing shotcrete techniques, the optimal lining thickness was 80 mm for WSSFHTHS per simulation. The results revealed that after using WSSFHTHS, the displacement of the tunnel surrounding the rock significantly improved, with no cracks or hollows, similar to the simulation results.

Conceptual design study on Plutonium-238 production in a multi-purpose high flux reactor

  • Jian Li;Jing Zhao;Zhihong Liu;Ding She;Heng Xie;Lei Shi
    • Nuclear Engineering and Technology
    • /
    • 제56권1호
    • /
    • pp.147-159
    • /
    • 2024
  • Plutonium-238 has always been considered as the one of the promising radioisotopes for space nuclear power supply, which has long half-life, low radiation protection level, high power density, and stable fuel form at high temperatures. The industrial-scale production of 238Pu mainly depends on irradiating solid 237NpO2 target in high flux reactors, however the production process faces problems such as large fission loss and high requirements for product quality control. In this paper, a conceptual design study of producing 238Pu in a multi-purpose high flux reactor was evaluated and analyzed, which includes a sensitivity analysis on 238Pu production and a further study on the irradiation scheme. It demonstrated that the target structure and its location in the reactor, as well as the operation scheme has an impact on 238Pu amount and product quality. Furthermore, the production efficiency could be improved by optimizing target material concentration, target locations in the core and reflector. This work provides technical support for irradiation production of 238Pu in high flux reactors.

연료극 지지체식 평관형 고체산화물 연료전지 단위 번들의 제조 및 성능 (Fabrication and Performance of Anode-Supported Flat Tubular Solid Oxide Fuel Cell Unit Bundle)

  • 임탁형;김관영;박재량;이승복;신동열;송락현
    • 전기화학회지
    • /
    • 제10권4호
    • /
    • pp.283-287
    • /
    • 2007
  • 한국에너지기술연구원에서는 중온 ($700{\sim}800^{\circ}C$) 작동용 연료극 지지체 평관형 SOFC 스택을 구성하는 단위 번들을 개발했다. 연료극 지지체 평관형 셀은 Ni/YSZ 서밋 연료극 지지체 튜브, 8몰% $Y_2O_3$ stabilized $ZrO_2$ (YSZ) 전해질, $LaSrMnO_3$ (LSM)과 LSM-YSZ composite 및 $LaSrCoFeO_3(LSCF)$로 구성된 다중층 공기극으로 구성됐다. 제조된 연료극지지체 평관형 셀은 유도 브레이징 법에 의해 페리틱 (ferritic) 금속 캡에 접합됐고, 공기극의 전류집전을 위해 공기극 외부에 Ag 선 및 $La_{0.6}Sr_{0.4}CoO_3(LSCo)$ paste를 이용했으며, 연료극의 전류집전은 Ni felt, wire, 그리고 paste를 이용했다. 단위 번들을 만들기 위한 연료극 지지체 평관형 셀의 반응 면적은 셀 당 $90\;cm^2$ 이었으며, 2개의 셀이 병렬로 연결되어 1개의 단위 번들이 됐고, 총 12개의 단위 번들이 직렬로 연결되어 스택을 구성한다. 공기 및 3%의 가습된 수소를 산화제 및 연료로 사용한 단위 번들의 운전 결과 최대 성능은 $800^{\circ}C$에서 $0.39\;W/cm^2$의 출력이 나타났다. 본 연구를 통해 연료극 지지체 평관형 SOFC 셀의 기본 기술과 KIER 만의 독특한 연료극 지지체 평관형 SOFC 스택을 구성하는 단위 번들의 개념을 확립할 수 있었다.