• Title/Summary/Keyword: Solid propellants

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Study on Coating Agent Composition for Adhesion of Solid Propellant(I) (고체 추진제 접착용 코팅제 조성 연구(I))

  • Jeong, Jae-Yun;Kim, Kyung Min;Park, Jung-Ho;Choi, Sung-Han
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.5
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    • pp.84-90
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    • 2020
  • The adhesion strength of two konds of solid propellants(primary propellant/secondary propellant) was studied by coating agent of adhesion composition composed of organic solvent, curing agent, and cure catalyst. The coating agent using FeAA, cure catalyst, resulted propellant breaking at more 0.14 wt% and interface breaking at less 0.10 wt%. The TPB cure catalyst of confirmed the result of the interface breaking immediately after curing of the secondary propellant. In addition, the coating agent using TPB was found to increase the adhesion strength between the primary propellant and the secondary propellant over time.

Combustion Efficiency Estimation Method of Solid Propellants and the Effects of Grain Shape using Closed Bomb Test (CBT를 이용한 고체 추진제의 연소효율 도출 방법과 그레인 형상의 영향 분석)

  • Jonggeun Park;Hong-Gye Sung;Wonmin Lee;Eunmi Kim
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.6
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    • pp.53-61
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    • 2022
  • The estimation method of combustion efficiency has been introduced by using closed bomb test(CBT). The Noble-Abel equation of state was applied to consider the real gas effects to take account of high operation pressure about a couple of 100 atm. of CBT. The heat loss through the CBT wall was considered. The volume change of grain was calculated by applying form functions, which estimated combustion efficiency of 8 different gain shapes. The combustion estimation method proposed in this study was fairly validated by the comparision with the pressure-time history data of the CBT experiments. The effects of both grain shape and propellant loading density were analyzed.

Effects of Aluminum Oxide Particles on the Erosion of Nozzle Liner for Solid Rocket Motors (고체 추진기관에서 산화알루미늄 입자가 노즐 내열재의 삭마에 미치는 영향)

  • 황기영;임유진;함희철
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.8
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    • pp.95-103
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    • 2006
  • The compositions, the gas properties in motor chamber and the aluminum oxide (Al2O3) particle size for two kinds of solid propellants with approximately 20% aluminum powder have been investigated. The SEM photographs of $Al_2O_3$ taken from nozzle entrance liner show that the aluminized PCP propellant with 47% volumetric fraction AP/HNIW and bimodal oxidizer 200-5 ${\mu}m$ can offer greater possibility for increasing aluminum agglomeration than the aluminized HTPB propellant with 64% volumetric fraction AP and trimodal oxidizer 400-200-6 ${\mu}m$. The nozzle entrance liner of solid rocket motor with the PCP propellant shows greater erosion at 4 circumferential sections in line with grain slots due to the impingement of large particles, but that with the HTPB propellant shows uniform erosion with circumferential angle.

A Study on the Property of NEPE System Propellant with Respect to the Size of RDX (RDX 입도에 따른 NEPE계 추진제 특성 연구)

  • Jang, Myungwook;Kim, Taekyu;Han, Haeji;Yun, Jaeho;Son, Hyunil
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.3
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    • pp.40-45
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    • 2018
  • The propellant tile and crack which account for the greatest proportion of solid rockets are profoundly affected by viscosity and mechanical properties of solid propellant. In this paper solid propellant with nitrate ester polyester(NEPE) system has been researched for the viscosity, mechanical properties and burning properties with size and mixing ratio of RDX. the viscosity of propellant was changed significantly depending on the size of RDX and mixing ratio, and mechanical properties of NEPE system propellant were also varied. Considering both lower viscosity and stable mechanical properties, the optimum size and mixing ratio of RDX can be identified as the main factors to the NEPE system propellant.

CFD Simulation of Combustion and Extinguishment of Solid Propellants by Fast Depressurization (고체 추진제의 연소 및 빠른 감압에 의한 소화 모델 CFD 모사)

  • Lee, Gunhee;Jeon, Rakyoung;Jung, Minyoung;Shim, Hongmin;Oh, Min
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.15-23
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    • 2019
  • In this study, an extinguishment model of a three-dimensional solid propellant rocket was developed by combustion and fast depressurization to control the thrust of a solid rocket. Computational fluid dynamics simulation was carried out to ascertain the change in flow patterns in the combustion chamber and the extinguishment process by using a pintle. An ammonium perchloride was used as the target propellant and the dynamic behavior of its major parameters such as temperature, pressure, and burning rate was predicted using the combustion model. The dynamic behavior of the combustion chamber was confirmed by fast depressurization from an initial pressure of 7 MPa to a final pressure of 2.5 MPa at a depressurization rate of approximately -912 MPa/s.

CBT Combustion Precise Modeling and Analysis Using VOF and FSI Methods (VOF와 FSI 방법을 적용한 CBT 연소 정밀 모델링 및 해석)

  • Jeongseok Kang;Jonggeun Park;Hong-Gye Sung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.26 no.5
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    • pp.35-43
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    • 2022
  • Precise modeling and analysis of closed bomb test(CBT) combustion using solid propellants was performed. The fluid structure interaction(FSI) method was implemented to analyze the gas and solid phases at the same time. The Eulerian analysis method was applied for the gas phase and grain combustion, and the Lagrangian analysis method was implemented for the grain movement. The interaction between the solid phase grains and the combustion gas was fully coupled through the source term. The volume of fluid(VOF) method was used to simulate the burning distance of the grain and the movement of the combustion surface. The force acting on the grain was comprised of the pressure and gravity acting on the grain burning surface, and the grain burning rate and grain movement speed were considered in the velocity term of the VOF. The combustion analysis was performed for both one and three grains, and fairly compared with the experiments. The acoustic field during grain combustion due to pressure fluctuations was also analyzed.

Synthesis and Crystallization of Hydrazinium Nitroformate(HNF) as Eco-friendly Oxidizer (친환경 산화제 HNF 합성 및 결정화 연구)

  • Kim, Jina;Kim, Min Jun;Min, Byoung Sun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.4
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    • pp.69-76
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    • 2015
  • Recently, environmental sustainability of the transitional explosives and propellants is an issue of growing importance in energetic materials. For examples, ammonium perchlorate(AP) as an solid propellants oxidizer could create a poisonous gas and atmospheric pollutions, such as HCl. Among the several oxidizers, hydrazinium nitroformate(HNF) is an effective candidate substance for eco-friendly oxidizer, which has high density, pressure index, and less smog generating property during combustion for the Divert and Attitude Control System(DACS). This study was confirmed a synthesis through various conditions, was performed for the essential data of solubility the crystallization process. Also, crystallization process such as cooling, drowning-out and sonication were performed.

Spray Characteristics of Water-Gel Propellant by Impinging Injector (Water-Gel 모사 추진제의 충돌 분무 특성 연구)

  • Hwang, Tae-Jin;Lee, In-Chul;Kim, Sang-Sun;Koo, Ja-Ye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.11-14
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    • 2009
  • The implementation of gelled propellants systems offers high performance, thrust-control, energy management of propulsion, storability, and high density impulse of solid propulsion. Present study focused on the spray behavior of liquid sheets formed by impinging jets of non-Newtonian liquids which are mixed by Carbopol 941 0.5%wt. The results are then compared with experiments conducted on spray images formed by impinging jets concerning with air-blast effect at center orifice. When gel propellants are injected by doublet impinging jets at low pressure, closed rim pattern shape appeared. As increasing air mass flow rate(decreasing GLR), spray breakup and atomization phenomenon better improved and spray structure instabilities for the effect of air-blast are also increased.

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Crystallization of Hydrazinium Nitroformate(HNF) as Eco-friendly Oxidizer (친환경 산화제 HNF 결정화 연구)

  • Kim, Jina;Kim, Min Jun;Min, Byoung Sun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.6
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    • pp.76-82
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    • 2016
  • Recently, environmental sustainability of the transitional explosives and propellants is an issue of growing importance in energetic materials. For examples, ammonium perchlorate(AP) as an solid propellants oxidizer could create a poisonous gas and atmospheric pollutions, such as HCl. Among the several oxidizers, hydrazinium nitroformate(HNF) is an effective candidate substance for eco-friendly oxidizer, which has high density, pressure index, and less smog generating property during combustion for the thrust control system. This study was controlled the size distribution and shapes through various conditions. Length and diameter ratio(L/D) of crystals has below 1 : 3, and the particle size was two types of $200{\mu}m$ and $50{\mu}m$.

Analysis of surface interaction between filler and binder of PBXs (복합화약 원료들간의 표면특성 해석)

  • 심정섭
    • Journal of the Korea Institute of Military Science and Technology
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    • v.4 no.1
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    • pp.207-215
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    • 2001
  • Plastic bonded explosive(PBX) is mainly composed of the nitramine-ploymer compositions. PBX is characterized by high velocity and pressure of detonation, low vulnerability and good thermal stability. Many important applications of PBX require the good adhesion between nitramine crystals and the binder. For PBXs as well as propellants, where good mechanical properties are of great importance, dewetting therefore must be prevented by strong adhesion between filler-binder. Adhesion depends on surface characteristics of filler and binder. In order to design for better adhesion, an understanding of the surface properties of explosive and binder is required. The surface free energies are calculated from contact angle values by the method of Kaelble. Critical surface tension of solids are calculated by Zisman plot. Critical surface tension is a useful parameter for characterizing the wettability of solid surface. In this study, HMX and 3 kinds of copolymers are selected, since they are widely used in many plastic bonded explosives. The technical objective of this investigation is to predict the interaction between filler and binder from their surface free energies.

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