• 한국세라믹학회지
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• 제39권3호
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• pp.299-307
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• 2002

본 연구에서는 복잡 형상의 세라믹체를 효율적으로 성형할 수 있어 새로운 성형기법으로 부각되고 있는 직응집성형(Direct Coagulation Casing, DCC)공정기술에 관하여 콜로이드 계면화학을 이용하여 연구하였다. 높은 고형분량을 가지는 안정된 질화규소 슬립을 제조하기 위하여 분산제, 소결조제 그리고 응집제 각각이 다양한 공정변수에 미치는 영향에 대하여 평가하였다. 1.0 wt% Tetraethylammonium Hydroxide(TEAH)를 첨가하여 염기영역에서 소결조제를 포함한 안정된 51vol%의 질화규소 슬립을 제조할 수 있었다. 질화규소 슬립은 첨가된 $Al(CH_3COO)_2OH$의 온도증가에 따른 열분해를 이용하여 직응집성 유도하였다. 염기영역에서 $Al^{3+}$ 이온들이 aluminum hydroxide$(Al(OH)_3)$ 석출되면서 슬립내 $OH^-$ 농도를 감소시켜 질화규소 슬립을 직응집시켰다.

• 한국결정성장학회지
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• 제7권1호
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• pp.167-173
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• 1997

$ZnFeO_4$ 분말은 금속 질산염을 수산화 칼슘으로 침전시켜 이를 1,4-부탄에디을 속에서 비교적 고온고압을 가하여 얻어졌다. 미분말이 얻어진 온도는 225-$300^{\circ}C$, 압력은 1-3.5 MPa이였다. 분말의 미세구조는 주사전자현미경으로 결정상은 X-선 회절 분석으로 행하였다. 분말의 물성과 반응온도, 반응시간 및 농도의 관계를 조사하였다. $ZnFe_2O_4$ 분말의 평균입자 크기는 반응온도와 시간이 증가함에 따라 증가하였다. $270^{\circ}C$에서 8시간 반응을 행한 경우의 평균입자 크기는 약 50 nm였다.

• 한국결정성장학회지
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• 제7권4호
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• pp.567-572
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• 1997

고순도 ZnO 미분말은 금속 질산염을 수산화 칼슘으로 침전시켜 이를 1,4-부탄에디올속에서 고온고압 반응으로 얻어졌다. 이때 미분말이 얻어진 반응온도는 $225-275^{\circ}C$, 압력은 1-3.0 MPa 이였다. 분말의 미세구조는 주사전자현미경으로 결정상은 X-선회절 분석으로 행하였다. 분말의 물성과 반응온도, 반응시간 및 농도의 관계를 조사하였다. ZnO 분말의 평균입자크기는 반응온도와 시간이 증가함에 따라 증가하고, 입자의 모양은 반응온도가 증가함에 따라 다각형의 모양이 얻어졌다. $225^{\circ}C$에서 8 시간 반응을 행한 경우의 평균입자 크기는 약 150 nm 이고, 입도분포는 균일하였다.

• KSBB Journal
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• 제25권4호
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• pp.357-362
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• 2010

Green alga, Ulva pertusa kjelmann has been known to be one of the largest pollutants in Korea. Therefore, the efficient pretreatment processes have been required to improve the yields of fermentable sugar. The optimal pretreatment conditions were determined to be $195^{\circ}C$ for 15 min. The sugar yield of glucose and xylose were estimated as 20.5%, and 5.0% respectively, based on theoretical yields. However solid residues were estimated enzymatic digestibility of 90-95% with cellulase loading of 15 FPU/g glucan. This process was proved to generate the low concentration of Hydroxy-Methyl-Furfural (51 ppm), which resulted in ethanol production with 95% of the maximum conversion yield from glucose in the culture of Saccharomyces cerevisiae (ATCC, 24858). This study showed that Ulva pertusa kjellmann can be used as a bioetahnol resource using the high temperature liquefaction process.

• 상하수도학회지
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• 제32권3호
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• pp.221-233
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• 2018

Two climate change scenarios, the RCP (Representative Concentration Pathways) 4.5 and the RCP 8.5 in the fifth Assessment Report (AR5) by Intergovernmental Panel on Climate Change (IPCC), were applied in the Yocheon basin area using the SWAT (Soil and Water Assessment Tool) model to estimate changes in flow rates and pollutant loadings in the future. Field stream flow rate data in Songdong station and water quality data in Yocheon-1 station between 2013~2015 were used for model calibration. While $R^2$ value of flow rate calibration was 0.85 and $R^2$ value of water qualities were in the 0.12~0.43 range. The total study period was divided into 4 sub periods as 2030s (2016~2040), 2050s (2041~2070) and 2080s (2071~2100). The predicted results of flow rates and water quality concentrations were compared with results in calibrated periods, 2015s (2013~2015). In both RCP scenarios, flow rate and TSS (Total Suspended Solid) loadings were estimated to be in increasing trend while TN (Total Nitrogen) and TP (Total Phosphorus) loadings showed decreasing patterns. Also, flow rates and pollutant loadings showed larger differences between the maximum and the minimum values in RCP 4.5 than RCP 8.5 scenarios indicating more severe effect of drought and flood, respectively. Dependent on simulation period and rainfall periods in a year, flow rate, TSS, TN and TP showed different trends in each scenario. This emphasizes importance of considerations on time and space when analyzing climate change impacts of each variable under various scenarios.

• 대한기계학회논문집A
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• 제38권3호
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• pp.309-314
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• 2014

기계나 토목 구조물의 형상은 일반적으로 전통적인 방법들을 이용하여 얻었다. 예를 들면 전력송전탑이나 해상풍력 하부구조물 이외의 다른 구조물들도 조직적으로 만든다. 한편 컴퓨터 그래픽의 급속한 성장으로 인해, 진화된 구조해석 및 최적설계기법들을 이용하고 있다. 본 논문에서는 해상 풍력 터빈을 위한 자켓 구조물의 구조형상을 위상최적화 기법을 통하여 연구하였다. 이번 연구는 실제작동하중상태로 시뮬레이션을 위하여 다 하중으로 종속시켰으며, 최적화 목적 함수는 주어진 경계조건아래 컴플라이언스로 정의하였다. 최적화는 고유진동수와 체적을 구속함수로 사용하였으며, 1 단계 모델의 결과는 2 단계 구조를 위한 외형을 빠르게 볼 수 있도록 한다. 그 결과로 사각뿔대의 3D 모델은 위상최적화를 통하여 개발하였다.

• Coupled systems mechanics
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• 제1권4호
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• pp.381-395
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• 2012

Dynamic response of Pile Supported Structures is highly depended on Soil Pile Structure Interaction. In this paper, by comparison of experimental and numerical dynamic responses of a prototype jacket offshore platform for both hinge based and pile supported boundary conditions, effect of soil-pile-structure interaction on dynamic characteristics of this platform is studied. Jacket and deck of a prototype platform is installed on a hinge-based case first and then platform is installed on eight skirt piles embedded on continuum monolayer sand. Dynamic characteristics of platform in term of natural frequencies, mode shapes and modal damping are compared for both cases. Effects of adding and removing vertical bracing members in top bay of jacket on dynamic characteristics of platform for both boundary conditions are also studied. Numerical simulation of responses for the studied platform is also performed for both mentioned cases using capability of ABAQUS and SACS software. The 3D model using ABAQUS software is created using solid elements for soil and beam elements for jacket, deck and pile members. Mohr-Coulomb failure criterion and pile-soil interface element are used for considering nonlinear pile soil structure interaction. Simplified modeling of soil-pile-structure interaction effect is also studied using SACS software. It is observed that dynamic characteristics of the system changes significantly due to soil-pile-structure interaction. Meanwhile, both of complex and simplified (ABAQUS and SACS, respectively) models can predict this effect accurately for such platforms subjected to dynamic loading in small range of deformation.

• Journal of Pharmaceutical Investigation
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• 제33권2호
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• pp.121-127
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• 2003

The objective of this study was to solidify the simvastatin self-microemulsifying drug delivery system (SMEDDS) and to improve the encapsulation efficiency of solidified alginate beads using sodium alginate. Typical simvastatin SMEDDS was composed of various oils, surfactants and cosurfactants. Also solidified-alginate beads was prepared by crosslinking liquid emulsion mixtures containing sodium alginate and other excipients (cetylpyridinum chloride (CP-Cl), hydroxypropyl methylcellulose, starch and so on). in $CaCl_2$ solution, it has been investigated that the drug release pattern and encapsulation efficiency were varied with the ratio of cationic lipid (CP-Cl). Solidified sodium alginate beads containing simvastatin SMEDDS were redispersed into media without re-aggregation. Oil droplet size of redispersed solidified-beads in media produced smaller than the initial size. The density of beads and drug loading amount were increased with increasing cationic lipid content. These systems have advantages of storage stability and predictability of drug release rate.

• 한국물환경학회지
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• 제21권5호
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• pp.458-463
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• 2005

Considering the characteristics of a filtration bio-reactor equipped with a mesh filter module which can effectively maintain high concentration of biomass and enhanced solid-liquid separation performance, the hybrid process of filtration bio-reactor combined with coagulation was investigated to get improved filtration characteristics as well as water quality in this work. Two bio-reactors (Run-1 & Run-2) were operated under the following conditions: working volume of 25 L, continuous loading of a synthetic wastewater (BOD: 200 mg/L, T-N: 50 mg/L, T-P: 5 mg/L), where an appropriate amount of alum ($Al_2(SO_4)_3{\cdot}18H_2O$) was added once a day into the reactor (Run-2). In the system without using a alum (Run-1), the clogging of mesh filter module was observed two times through 85 days of whole operation. Meanwhile, the filter module did not clog even at higher MLSS concentration (6,000~12,000 mg/L) and the stable filtration (0.7 mid) was continued in the case of using a alum. Due to the stable formation of cake layers, BOD and SS were shown below 6 and 3 mg/L, respectively. T-P and pH of the effluent were changed because of the intermittent addition of the alum. In the case of Al/P=2.5, the average T-P removal efficiency per day was 85.2% and the average T-P concentration of the effluent was 0.3 mg/L. However, the removal efficiency of phosphate was influenced by pH in the reactor.

• Bulletin of the Korean Chemical Society
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• 제35권11호
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• pp.3188-3194
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• 2014

Compound K (CK) was formulated as polymeric micelles (PM) using Pluronic$^{(R)}$ F-127 to enhance the oral absorption of CK, an intestinal bacterial metabolite of ginseng protopanaxadiol saponin. The physicochemical properties of Ck-loaded PM were characterized and an in vitro transport study using the Caco-2 cell system as well as an in vivo pharmacokinetic study using SD rats was carried out. The hydrodynamic mean particle size of CK-loaded PM (CK-PM) was $254{\pm}23.45nm$ after rehydration and the drug loading efficiency was ca. 99.9%. The FT-IR spectroscopy, X-ray diffraction, differential scanning calorimetry and scanning electron microscopy data supported the presence of a new solid phase in the PM. The $P_{app}$ value of in vitro Caco-2 cell permeation of CK-PM and the oral absorption of CK was enhanced about 1.2-fold and 2.6-fold compared to CK suspension, respectively, showing that the present PM formulation enabled an enhancement of oral CK absorption.