• Title/Summary/Keyword: Solid Wastes

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Development of Porous Support with Mine Waste Materials (광산 폐기물을 활용한 다공성 담체 개발)

  • 정문영;정명채;최연왕
    • Economic and Environmental Geology
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    • v.37 no.1
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    • pp.143-151
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    • 2004
  • This study focused on examining the possibility of recycling mine solid waste as environmental materials, especially for porous media. Basic properties including mineralogical compositions, chemical compositions, and particle size distribution of the tailings from the Sangdong W mine were checked. The mineralogical and chemical compositions of the tailings samples were not much different in depth. According to Korean Standard Leaching Test for Wastes(KSLT), concentrations of heavy metals leached from the tailings were below the standard values. As a result of particle size analysis, the median diameter (d$_{50}$) of the tailings was in the range of 10 to 30 ${\mu}{\textrm}{m}$. The stable tailings slurry made up of 3 ${\mu}{\textrm}{m}$ in d$_{50}$ was prepared using Attrition Mill. The milling condition was 40 vol% in slurry concentration, 700 rpm in stirring speed, and 1 hour in milling time. PEI was added as dispersing agent. Concentrated slurry was extended to 3 times by foaming method. In the case of 3 times foamed slurry, the total and open porosity of ceramic supports sintered at 1,075$^{\circ}C$ for 90 minutes was about 80% and 72%, respectively. Pore size was in the range of 30∼350${\mu}{\textrm}{m}$. Therefore, the tailings could be recycled starting material for environmental materials such as macroporous ceramic support.

A Comparative Measurement of Pb and Cd with Different Pretreatment (전처리방법에 따른 환경시료내 Pb과 Cd의 측정)

  • Yoon, Chun-Gyeong;Kwon, Tae-Young
    • Korean Journal of Environmental Agriculture
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    • v.18 no.2
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    • pp.109-115
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    • 1999
  • Lead and cadmium were analyzed with different pretreatemnt methods. Paddy soil and wastewater sludge samples were used and the result was compared each other. Pretreatment method affected the concentration obtained from samples significantly. Large difference was illustrated between the results. The concentration by 0.1N HCl extraction method, an official analytical method for soil and solid wastes, was far lower than those by the EPA3050B and mixed-acid digestion methods. The reason might be that metals associated with organics and silicates are not easily extracted by 0.1N HCl, while digestion methods using strong acids and high temperature dissolved all the elements in the samples. It implies that pretreatment method should be specified in addition to concentration on the report of metal analysis for environmental samples. Acid digestion methods are not necessarily good because the concentration obtained does not represent the natural condition which is our concern in many cases. The 0.1N HCl extraction method does not fully represent the natural condition either. The metals associated with organics will be extracted eventually as organics decompose with time. Therefore, proper pretreatment and analytical methods should be developed for specific purpose, and their standardization is recommended.

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Studies on the Microbial Utilization of Agricultural Wastes (Part 13) Optimization of Simultaneous Hydrolysis-Fermentation for Ethanol Production from Rice Straw (농생폐자원의 미생물학적 이용에 관한 연구 (제13보) Ethanol 생산을 위한 동시당화-발효조건의 검사)

  • Lee, Jung-Yoon;Kim, Byung-Hong;Bae, Moo;Kim, Sung-Ki
    • Microbiology and Biotechnology Letters
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    • v.9 no.2
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    • pp.71-75
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    • 1981
  • Studies were made to optimize the simultaneous hydrolysis-fermentation (SSF) process for the production of ethanol from rice straw. Trichoderma sp. KI 7-2 was selected to produced cellulase by solid culture for SSF. Ethanol production was highest when the SSF process utilized koji culture of the fungus grown on a medium of wheat bran-rice straw 3 : 2 mixture with moisture content of 50% adjusted to pH 4.5 for 7 days as the enzyme source. It was found that pretreatment of the substrate is not necessary. To ferment 1g of rice straw by SSF 2.47 units of cellulase were required, and the initial yeast concentration of 2.5$\times$10$^{7}$ cell/$m\ell$ was found to be sufficient. Optimum pH and temperature for the process were 4.5 and 4$0^{\circ}C$, respectively. It was also found that higher ethanol concentration in the broth can be obtained by the addition of substrate or substrate and enzyme to SSF broth.

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Generation of Food Waste from Different Sources and Its Composting Measures at the Apartment Complex (배출원별 음식물 쓰레기 발생 특성 및 아파트 단지에서의 퇴비화 방안 (대전 및 충청남도 지역을 중심으로))

  • Kang, H.;Lee, O.L.;Kim, J.W.;Hur, H.W.;Han, S.H.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.53-66
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    • 1998
  • This study was carried out to investigate the typical composition of food waste from municipal solid wastes (MSW) and unit food waste generation rates from different sources in the model cities and to study the food waste management system from unit household to composting facilities. The annual average food waste composition of MSW was determined as 49% in Taejon and 52% in Chungnam Province, respectively. No big difference in food waste composition was found among the different sources. Since the paper waste generally occupied the half of food waste, over 75% of MSW was found to be compostable or biodegradable. Per capita food waste generation rate, 200~250g/capita day was determined by the direct measurement from 32 households, while 380g/capita day for Chungnam Province and 400 g/capita day for Taejon were estimated by the load count analysis In the sanitary landfills. This difference means people contribute generating food waste at outside house approximately twice as much as that at inside house. Per capita food waste generation rates from several sources were determined as follows; 166~215g/capita day at municipalities, 400g/visitor day at a first class hotel, 170g/student day at a university restaurant. Food waste generation from restaurant was strongly dependant upon it's level or quality; 670g/capita day at the high level restaurant, 190g/capita day at the middle class and 60 g/capita day at the lower class restaurant. The food waste reduction rate in a In situ fermentor showed 30~40g/kg day.

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Radioactivity Analysis of $^{55}Fe\;and\;^{63}Ni$ in Dismantled Concrete (해체 콘크리트 폐기물에 포함된 $^{55}Fe$$^{63}Ni$ 방사능 분석)

  • Kang, Mun-Ja;Chung, Kun-Ho;Hong, Sang-Bum;Choi, Geun-Sik;Lee, Chang-Woo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.1
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    • pp.19-27
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    • 2007
  • Combined method of extraction chromatography and liquid scintillation analysis was established for determinating $^{55}Fe\;and\;^{63}Ni$ radioactivity in solid samples. Activated concrete wastes generated from dismantling KRR-2 were analysed. The sequential separation including precipitation and extraction chromatography resulted in the above 90% chemical recoveries of Fe. Above 62% recoveries of Ni were obtained by this procedure exception to 43.6 and 46.5% recoveries. The seperation and counting procedure was also confirmed with spiked samples of known quantity. The measured and spiked quantity were agreed with the 3.7% and 0.7% variations in the $^{55}Fe\;and\;^{63}Ni$ experiments, respectively. The radioactivities of $^{55}Fe$ in the dismantled concretes are shown from below MDA to maximum 362 Bq/g. The radioactivities of $^{63}Ni$ in all concrete samples are below MDA. The $^{63}Ni$ doesn't exist in dismantled concretes from KRR-2. The radioactivity of $^{55}Fe$ is decreased rapidly as the sampling depth is increased from the concrete surface.

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Efficiency Calibration of HPGe Detector in Normal ana Coincidence Mode for the Determination of Prompt Gamma-ray (즉발감마선 측정을 위한 HPGe 검출기의 전계수 또는 동시계수모드에서의 광대역 계측효율 보정)

  • 송병철;박용준;지광용
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.2
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    • pp.97-104
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    • 2004
  • Neutron induced prompt gamma-ray spectroscopy(NIPS) system measures the prompt gamma-ray emitting by the interaction of a neutron with various materials. This system will be of great benefit to scientists worldwide, since it provides the non-destructive measurement of many element in either solid or liquid wastes. In this study, the full-energy-peak (FEP) efficiency calibration for a HPGe detector was constructed in the ${\gamma}$-ray energy range from 80 keV to 8 MeV, using $^{l33}$Ba and >TEX>$^{152}Eu$ RI sources and $ ^{35}Cl(n, ${\gamma}$)^{36}Cl$ thermal neutron captured reaction. The FEP efficiency curve for the higher energies using the $^{35}Cl(n, ${\gamma}$)^{36}Cl$ reaction was normalized with the curve obtained from the RI sources, since the accurate activity of its prompt ${\gamma}$-ray is unknown. The average thermal neutron flux was theoretically calculated using the FEP efficiency curve for the KCl standard solutions. The NIPS system equipped with a ${\gamma}$-${\gamma}$ coincidence setup with two n-type coaxial HPGe detectors was considered in order to reduce the interfering ${\gamma}$-ray background. The FEP efficiency curve for the ${\gamma}$-${\gamma}$ coincidence system was also obtained for full energy range. The performance of the normal and coincidence NIPS system was tested by comparing signal-to-noise ratio in each mode using the reference sample.e.

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Cost-Benefit Analysis by Resource Recovery Facility for Municipal Waste -Focus on Gangwon Province- (생활폐기물 자원화시설의 편익분석 -강원도 중심으로-)

  • Han, Young-Han;Lee, Hae-Seung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.6
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    • pp.2833-2845
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    • 2012
  • In this study, the amount of waste resource that could be recovered was analyzed. The installation and operation costs of waste resource recovery for both single- and multi-regional facility were calculated, and compared with the costs of landfill to investigate the feasibility of them. RDF(Refuse Derived Fuel) process and resource recovery by incineration process were considered as waste resource recovery facility. And, the multi-regions for cost analysis were established on the basis of the proper generation rate of municipal waste with the consideration of combustible ratio. The study results showed that single region facility for both RDF and incineration process has no economic benefit, compared with the landfill method. For the multi-regional facility, RDF process could save a large cost than the landfill method, but the incineration facility couldn't. Separate from the economic benefits, the waste resource recovery should be importantly considered when considering the depletion of fossil fuel, global warming, environmental toxicity, and the enormous expenses due to social conflict and confuse. When the CDM(Clean Development Mechanism) is vitalized in the near future, the additional economic benefits by CERs(Certified Emission Reductions) could be expected. CERs for RDF facility is corresponding to about 256.5 billion won, and CERs for incineration facility is corresponding to about 54 and 77.4 billion won for single- and multi-regional facility, respectively.

Decontamination of simulated radioactive metal waste by modified electrolytic Process with neutral salt electrolytes (개선된 중성염 진해공정을 이용한 모의 방사성 금속폐기물의 제염)

  • Lee, Ji-Hoon;Yuk, Wan-Yi;Yang, Ho-Yeon;Ha, Jong-Hyun
    • Journal of Radiation Protection and Research
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    • v.27 no.2
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    • pp.95-100
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    • 2002
  • Conventional and modified electrolytic decontamination experiment were performed in the 1.7 M solution of sodium sulfate and sodium nitrate tot decontamination of carbon steel as the simulated metal wastes which have been produced in large amounts from nuclear power plants. Anode ant cathode were used as inconel and titanium respective. The reaction time and temperature were 1 hr and $25^{\circ}C$ The analyses were performed of the characteristics such as weight loss arid thickness change of metal waste. suspended solid in electrolyte and SEM observation. In modified electrolyte decontamination system with increased current density ranged from 0.1 to $0.6A/cm^2$, the metal waste showed thickness changes of $0.48{\pm}0.005$ to $67.7{\pm}0.02{\mu}m$ in 1.7 M sodium sulfate and those of $0.06{\pm}0.005$ to $17.7{\pm}0.05{\mu}m$ in sodium nitrate. Metal waste in modified electrolyte decontamination system showed the thickness change of $9.8{\pm}0.01{\mu}m$ while it reacted up to $3.7{\pm}0.03{\mu}m$ in conventional system with $0.3 A/cm^2$ of current density and 1.7 M sodium sulfate. Decontamination efficiencies of modified electrolytic process ate much hither than that of conventional electrolytic process when both are applied to metal waste.

Physicochemical Characteristics and Estimation of H2S Emission Rate from Municipal Solid Waste at the Environmental Facilities in Busan City (부산지역 환경기초시설에서 발생하는 폐기물의 물리, 화학적 특성 규명 및 황화수소 발생량 예측에 관한 연구)

  • Lee, Taeyoon;Kim, Doyong;Kim, Jaejin;Lee, Junki
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.2
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    • pp.13-20
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    • 2009
  • There have been increasing interests in the odor generation problems as concerns about the quality of life has been increased recently. Especially, approximately 67% of the odor complaints from environmental facilities are those from sewage treatment facilities and food waste treatment facilities. Moreover, sewage ocean dumping will be prohibited from 2012 by the international and domestic ocean laws, and thus, demand for alternative management plans is increasing. Therefore, it was first selected 5 sewage treatment facilities and 5 food waste treatment facilities where the amounts of waste are relatively immense in Busan, and collect their sludge samples. Then it was investigated the samples' physical and chemical characteristics through proximate analysis, elemental analysis, XRF analysis, and calorific value analysis. Finally, estimate the $H_2S$ emission rates were estimated in order to apply the results as the basic data for providing the fundamental solution for the oder complaints. As a result, the concentration of $H_2S$ in sewage sludge and in food waste treatment facility were 57.3 mg/kg and 19.7 mg/kg in average, respectively. Finally, the units of $H_2S$ in wastes stored in total 10 waste treatment facilities was estimated 16,017,910.0 mg/d.

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Restoration Strategies on Deteriorated Ecosystem due to Recreational Use in Nature Parks in Korea (자연공원내(自然公園內)의 휴양적(休養的) 이용(利用)에 따른 생태계훼손(生態系毁損)의 회복방안(恢復方案)에 대(對)한 고찰(考察))

  • Woo, Bo-Myeong
    • Journal of Korean Society of Forest Science
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    • v.80 no.4
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    • pp.369-378
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    • 1991
  • Major statutory nature protection areas include Nature Parks, Nature Reserves. Nature Ecological System Protected Areas. Biosphere Reserves, Nature Protected Forests, Wildlife Sanctuaries, and Protection Forests with total area of 1,124,000 ha. These protected areas cover almost 18% of the forested area. The number of visitors of NPs reached over 33 million per year with sharp increasing rate over the years. To protect the deteriorated hiking trails and camp grounds caused by overuse, two management policies have been implemented : cooking prohibition and natural rest rotation system. While prohibition of cooking is based on the fact that most of the solid wastes in nature parks are leftovers of cooking, natural rest rotation system is mainly for rehabilitation of deteriorated areas by natural processes. The system has closed 47 trails(in 27 mountains) throughout the country since January 1991, which is scheduled to continue 3 years. Due to the lack of accumulated scientific knowledge on how, when and where to close, application of the system leaves much to be desired. This paper discusses the current efforts to protect the natural resources for recreational use and suggests future directions for an effective policy implementation.

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