• Title/Summary/Keyword: Solid Oxide Fuel Cell(SOFC)

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Development of Reduced Temperature Solid Oxide Fuel Cells and Test of a Short Stack (저온형 고체산화물 연료전지의 개발과 이를 이용한 소형 스택의 성능 시험)

  • 유영성;박진우;임희천;이규창;조남웅
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2003.05a
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    • pp.649-653
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    • 2003
  • 일반적으로 연료전지에는 알카리형(AFC)과 인산형(PAFC), 고분자형 연료전지(PEMFC) 등과 같이 비교적 저온에서 동작되는 연료전지와 고온형으로 $650^{\circ}C$에서 정온 동작되는 용융탄산염형 연료전지(MCFC)와 운전온도가 약 500~100$0^{\circ}C$로 폭넓게 적용될 수 있는 고체산화물 연료전지(혹은 고체전해질 연료전지, Solid Oxide Fuel Cell, SOFC)가 있다.(중략)

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Power Flow Control of Grid-Connected Fuel Cell Distributed Generation Systems

  • Hajizadeh, Amin;Golkar, Masoud Aliakbar
    • Journal of Electrical Engineering and Technology
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    • v.3 no.2
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    • pp.143-151
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    • 2008
  • This paper presents the operation of Fuel Cell Distributed Generation(FCDG) systems in distribution systems. Hence, modeling, controller design, and simulation study of a Solid Oxide Fuel Cell(SOFC) distributed generation(DG) system are investigated. The physical model of the fuel cell stack and dynamic models of power conditioning units are described. Then, suitable control architecture based on fuzzy logic and the neural network for the overall system is presented in order to activate power control and power quality improvement. A MATLAB/Simulink simulation model is developed for the SOFC DG system by combining the individual component models and the controllers designed for the power conditioning units. Simulation results are given to show the overall system performance including active power control and voltage regulation capability of the distribution system.

Development of 5kW PCS for SOFC System (5kW급 SOFC 시스템용 전력변환장치 개발)

  • Lee, J.M.;Choi, J.Y.;Kim, Y.W.;Yi, J.H.;Seo, Y.G.;Suh, I.Y.
    • Proceedings of the KIPE Conference
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    • 2010.07a
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    • pp.332-333
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    • 2010
  • The 5kW SOFC(Solid Oxide Fuel Cell) System is composed to 3kW parallel Fuel Cell. We propose to the parallel control of 5kW PCS in the unbalance condition of fuel cell. The developed 5kW PCS can be found control ability of DC/DC converters in the operating conditions of the unbalanced parallel operation. It is verify to the control characteristics by simulation and experiment.

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Part-load Performance Characteristics of a Solid Oxide Fuel Cell/Gas Turbine Hybrid Power System Operating with Various Load-following Operation Modes (부하추종 운전방법에 따른 고체산화물 연료전지/가스터빈 하이브리드 동력 시스템의 부분부하 성능특성)

  • Kim Jae-Hoon;Yang Jin-Sik;Ro Sung-Tack;Sohn Jeong-Lak
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.3 s.246
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    • pp.193-200
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    • 2006
  • The purpose of this study is to compare the part-load performance of a SOFC/GT hybrid power system with three different kinds of load-following operation modes. The primary mode for the part load operation of a hybrid power system is the reduction of supplied fuel (e.g., fuel control mode) to the hybrid system. The other two options, i.e., variable speed and VIGV controls, are related to the reduction of supplied air simultaneously with the reduction of supplied fuel to the system. With the performance analysis of a SOFC/GT hybrid power system, it is concluded that the variable speed con佐ol mode Provides the best performance for the part-load operations. It is also found that the VIGV control mode, with its better performance behavior than the fuel control mode, can be used as an important option for the part-load operation especially in case that the variable speed control mode can not be adopted.

Microstructural Characterization of Composite Electrode Materials in Solid Oxide Fuel Cells via Image Processing Analysis

  • Bae, Seung-Muk;Jung, Hwa-Young;Lee, Jong-Ho;Hwang, Jin-Ha
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.86-91
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    • 2010
  • Among various fuel cells, solid oxide fuel cells (SOFCs) offer the highest energy efficiency, when taking into account the thermal recycling of waste heat at high temperature. However, the highest efficiency and lowest pollution for a SOFC can be achieved through the sophisticated control of its constituent components such as electrodes, electrolytes, interconnects and sealing materials. The electrochemical conversion efficiency of a SOFC is particularly dependent upon the performance of its electrode materials. The electrode materials should meet highly stringent requirements to optimize cell performance. In particular, both mass and charge transport should easily occur simultaneously through the electrode structure. Matter transport or charge transport is critically related to the configuration and spatial disposition of the three constituent phases of a composite electrode, which are the ionic conducting phase, electronic conducting phase, and the pores. The current work places special emphasis on the quantification of this complex microstructure of composite electrodes. Digitized images are exploited in order to obtain the quantitative microstructural information, i.e., the size distributions and interconnectivities of each constituent component. This work reports regarding zirconia-based composite electrodes.

Fabrication of the Functional Coatings of a Tubular Solid Oxide Fuel by Plasma Spray Processes. (플라즈마 용사법을 이용한 원통형 고체산화물 연료전지의 요소피막 제조)

  • 주원태;홍상희
    • Journal of the Korean institute of surface engineering
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    • v.30 no.5
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    • pp.333-346
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    • 1997
  • Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

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Design Performance Analysis of Solid Oxide Fuel Cell/Gas Turbine Hybrid Systems for Various Gas Turbine Pressure Ratios (가스터빈 압력비 변화에 따른 고체 산화물 연료전지/가스터빈 하이브리드 시스템의 설계 성능 해석)

  • Park, Sung-Ku;Kim, Tong-Seop
    • Proceedings of the SAREK Conference
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    • 2006.06a
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    • pp.885-890
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    • 2006
  • This study presents analysis results for the hybrid system combining solid oxide fuel cell and gas turbine. Two different system layouts(an ambient pressure system and pressurized system) are considered and their design performance are comparatively investigated taking into account critical design factor, the most critical parameter such as turbine inlet temperature, gas turbine pressure ratio, temperature difference at the fuel cell and fuel cell operating temperature are considered as design constraints. Performance variations according to system layout and design parameters are examined in energetic view point.

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Optimal Design for Tubular SOFC Testing Jig (관형 고체산화물연료전지 테스트 지그 최적화)

  • Choi, Hoon;An, Gwon-Seong;Shin, Chang-Woo;Cha, Suk-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.303-306
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    • 2009
  • High temperature solid oxide fuel cells (SOFCs) offer a clean, pollution-free technology to electrochemically generate electricity at high efficiencies. Solid oxide fuel cells in several different designs have been investigated; these include planar and tubular geometries. The tubular type cell is widely researched due to it have advantages about thermal expansion and sealing issues. Unfortunately, lab scale tubular cell for testing has thermal expansion and sealing problems. The previous Jig for lab scale tubular cell testing has many sealing problems. When we feed fuel gas to jig inlet, ceramic glue sealant has amount of gas expansion pressure, because temperature of feeding gas changes ambient temperature to high temperature ($700{\sim}900^{\circ}C$). Furthermore, when we carry out long time test, something like degradation test, crack of ceramic glue sealant due to weakness of mechanical properties can make stop working the test. Additionally, we reduce setting process for assembling, because micanite is not required drying or debinding process.

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Fuel Cell Performance by the Impedance Method (임피던스법을 적용한 연료전지 성능규명)

  • 김귀열;서장수;박용필;이준응
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.157-159
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    • 2001
  • The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the MCFC which use strongly corrosive molten carbonate at 650$^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of Fe/20Cr/Ti alloys has been done in (62+38)mol% (Li+K)CO$_3$ melt at 923K by using steady state polarization and electrochemical impedance spectroscopy method. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for SOFC, by the way, Ni-YSZ materials are used as anode of SOFC widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(47vo1%) was bettor excellent than the others.

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Development of HIL simulator for performance validation of stack inlet gases temperature controller of marine solid oxide fuel cell system (선박용 고체산화물형 연료전지 시스템의 스택 공급 가스 온도 제어기 성능 검증을 위한 HIL 시뮬레이터 개발)

  • Ahn, Jong-Woo;Park, Sang-Kyun
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.6
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    • pp.582-588
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    • 2013
  • Solid Oxide Fuel Cell (SOFC) has been focused as a promising power source, which can replace a diesel engine regarding as major source of air pollution by the ship, due to high efficiency and eco-friendly. High operating temperature of SOFC is enable to secure of high efficiency, use various fuels and no need of high priced catalyst, but it may damage to components of SOFC. Therefore temperature control system has to be designed and validated before employing the fuel cell system for securing high efficiency and reliability. In this paper, instead of using typical method to validate performance of the controller, which consumes high cost and time, performance validation system using Hardware-in-the-loop simulation was developed and validated performence of the designed temperature controller for SOFC system.