• Title/Summary/Keyword: Solid Mixture

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Prediction of Distribution of Solid Volume Fraction in Semi-Solid Materials Based on Mixture Theory (혼합이론에 근거한 반용융 재료의 고상률 분포 예측)

  • 윤종훈;김낙수;임용택
    • Transactions of Materials Processing
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    • v.8 no.4
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    • pp.399-406
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    • 1999
  • It is more appropriate to treat that the semi-solid mixture as a single phase material that obeys incompressibility in the global sense and to analyze the liquid flow only locally than the approach based on compressible yield criteria. In the present study, a numerical algorithm of updating the solid volume fraction based on mixture theory has been developed. Finite element analysis of simple upsetting was carried out using the proposed algorithm to investigate the degree of macro-segregation according to friction conditions and compressive strain rates under the isothermal condition. The simulation results were compared to experimental results available in reference to test the validity of the currently proposed algorithm. Since the comparison results show a good agreement it is construed that the proposed algorithm can contribute to the development of numerical analysis of determining the solid volume fraction semi-solid processing.

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Manrfacturing Process of Solid Fuel Using Food Wastes and Paper Sludges (음식물 쓰레기와 제지슬러지를 이용한 고체연료 제조)

  • Kim, Yong-Ryul;Son, Min-Il
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.437-444
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    • 2010
  • Dry Process(natural drying, hot-air drying, oil fry drying), optimized mixture ratio and the condition of carbonization was carried out in order to improve the product durability develop eco-friendly solid fuel mixing food waste and paper sludge. As a result of the experiment, oil fry drying process was the fastest method for drying food waste and paper sludge mixture that contains 80% water inside, and the optimized mixture ratio to minimize the generating concentration of chlorine gas against caloric value of mixture ratio was 7:3. Additionally proper temperature of product carbonization was about $200^{\circ}C$ and shown increasing product durability through the carbonization. Therefore, the pelletized solid fuel be shaped diameter around 0.5cm, length 2cm under which was pulverized and molded using 7:3 mixture of food waste, and paper sludge was the eco-friendly solid fuel possible to be industrialized which is consist of chlorine concentration of below 2.0wt% and the lowest caloric value of over 5,000kcal/kg. In conclusion, this developing manufacturing process of the solid fuel can be interpreted to contribute alternative energy development in accordance with low carbon and green growth era.

Effects of Cyclone and Freeboard Geometry on Solid Entrainment Loss in a Gas-Solid Fluidized Bed (기체-고체 유동층에서 사이클론과 프리보드의 형상이 고체 비산 손실에 미치는 영향)

  • RYU, HO-JUNG;JO, SUNG-HO;LEE, SEUNG-YONG;LEE, DOYEON;NAM, HYUNGSEOK;HWANG, BYUNG WOOK;KIM, HANA;WON, YOO SEOB;KIM, JUNGHWAN;BAEK, JEOM-IN
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.4
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    • pp.330-337
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    • 2019
  • Effects of cyclone and freeboard geometry on solid entrainment loss were investigated with two different types of cyclones and bubbling beds in a gas-solid fluidized bed system. The solid entrainment loss was measured by collected fines during continuous solid circulation condition. Bubbling bed which has an expanded freeboard showed less solid entrainment than the bubbling bed which has a straight freeboard. The cyclone which has a wide gas-solid mixture inlet showed less solid entrainment loss than the cyclone which has a narrow gas-solid mixture inlet. Moreover, the cyclone has a wide gas-solid mixture inlet can capture smaller particles.

Surface Discharge Characteristics of Solid Dielectrics in N2/O2 Mixture Gas for Eco-Friendly Insulation Design (친환경 절연설계를 위한 N2/O2 혼합가스 중 고체유전체 종류에 따른 연면방전특성)

  • Lim, Dong-Young;Park, He-Rie;Choi, Eun-Hyeok;Choi, Sang-Tae;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.26 no.3
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    • pp.9-15
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    • 2012
  • In this paper, we deal with a surface discharge that caused an aggravation of the dielectric strength in the $N_2/O_2$ mixture gas, When composit dielectrics were formed from the use of a solid dielectric. It was found from this study that the surface discharge voltage was deeply involved in the mixture ratio of $O_2$, the electrical property of the solid dielectric, kind of the solid dielectric, an electric field at the triple junction and a medium effect. These results expect basic data that will be used to transmission and distribution power system equipment using the $N_2/O_2$ mixture gas.

A Study on the Surface Discharge Characteristics by Dielectric Constant and Diameter of Solid Dielectrics to Improve Surface Dielectric Strength in Eco-Friendly Insulation Gas (친환경 절연가스 중 연면절연성 향상을 위한 고체유전체의 유전율과 지름에 따른 연면방전특성 연구)

  • Lim, Dong-Young;Min, Gyeong-Jun;Park, He-Rie;Choi, Eun-Hyeok;Choi, Sang-Tae;Park, Won-Zoo;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.1
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    • pp.85-91
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    • 2013
  • This paper studied surface discharge characteristics by a dielectric constant and diameter of solid dielectrics in $N_2/O_2$ mixture gas. Applied electric field strength at $N_2/O_2$ mixture gas was changed from the dielectric constant and diameter of the solid dielectrics, and insulation performance of the $N_2/O_2$ mixture gas determined surface discharge voltage. In each of the diameter at the solid dielectrics, the surface discharge voltage was increased by lengthening surface distance, whereas increasing rate of the surface discharge voltage was different from gas pressure. Thus, In this paper, main factors of surface discharge are as follows. 1) Insulation performance of $N_2/O_2$ mixture gas, 2) Dielectric constant of solid dielectrics, 3) Surface discharge path. It was clear that the surface discharge voltage depend on the main factors. These results will be applied to useful data for an eco-friendly composite insulation design.

Preparation and Characterization of a Surface Renewable Solid State Hg/HgO Reference Electrode Utilizing Gold Amalgam

  • Kim, Won;Park, Jong-Man
    • Bulletin of the Korean Chemical Society
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    • v.28 no.3
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    • pp.439-442
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    • 2007
  • A solid state Hg(Au)/HgO reference electrode was prepared utilizing gold amalgam solid particles. Solid fine powder of the gold amalgam was prepared by chemical reduction of Au(III) with NaBH4 followed by reduction of Hg(II) in the presence of gold fine particles. The solid content in the suspension of the gold amalgam particles and fine mercury oxide particles in DMF containing PVC was precipitated by the addition of a large amount of water to give solid Hg(Au)/HgO/PVC mixture. After drying, the mixture was pressure-molded to a physically stable Hg(Au)/HgO composite reference electrode material. The electrochemical characteristics of the electrode as a reference electrode were very similar to an ordinary Hg/HgO reference electrode. The electrode material can be molded and fabricated in any desired shape and size. The surface can be renewed by a simple polishing process whenever contaminated or deactivated. The applicability of the electrode in the electrochemical detection of carbohydrates after anion exchange separation was evaluated.

Analytical solution to the conduction-dominated solidification of a binary mixture (열전도에 의해 지배되는 이성분혼합물의 응고문제에 대한 해석해)

  • Jeong, Jae-Dong;Yu, Ho-Seon;No, Seung-Tak;Lee, Jun-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.11
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    • pp.3655-3665
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    • 1996
  • An analytical solution is presented for the conduction-dominated solidification of a binary mixture in a semi-infinite medium. The present approach differs from that of other solution by these four characteristics. (1) Solid fraction is determined from the phase diagram, (2) thermophysical properties in mushy zone are weighted according to the local solid fraction, (3) non-equilibrium solidification can be simulated and (4) the cooling condition of under-eutectic temperature can be simulated. Up to now, almost all analyses are based on the assumption of constant properties in mushy zone and solid fraction linearly with temperature or length. The validation for these assumptions, however, shows that serious error is found except some special cases. The influence of microscopic model on the macroscopic temperature profile is very small and can be ignored. But the solid fraction and average solid concentration which directly influence the quality of materials are drastically changed by the microscopic models. An approximate solution using the method of weighted residuals is also introduced and shows good agreement with the analytical solution. All calculations are performed for NH$_{4}$Cl-H$_{2}$O and Al-Cu system.

Solid Dispersion as a Strategy to Improve Drug Bioavailability (고체분산체를 이용한 약물의 생체이용율 향상을 위한 전략)

  • Park, Jun-Hyung;Chun, Myung-Kwan;Cho, Hoon;Choi, Hoo-Kyun
    • KSBB Journal
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    • v.26 no.4
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    • pp.283-292
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    • 2011
  • Solid dispersion is one of well-established pharmaceutical techniques to improve the dissolution and consequent bioavailability of poorly water soluble drugs. It is defined as a dispersion of drug in an inert carrier matrix. Solid dispersions can be classified into three generations according to the carrier used in the system. First and second generations consist of crystalline and amorphous substances, respectively. Third generation carriers are surfactant, mixture of polymer and surfactants, and mixture of polymers. Solid dispersions can be generallyprepared by melting method and solvent method. While melting method requires high temperature to melt carrier and dissolve drug, solvent method utilizes solvent to dissolve the components. The improvement in dissolution through solid dispersions is attributed to reduction in drug particle size, improvement in wettability, and/or formation of amorphous state. The primary characteristics of solid dispersions, the presenceof drug in amorphous state, could be determined by differential scanning calorimetry (DSC), powder X-ray diffraction (PXRD), and fourier-transformed infrared spectroscopy (FTIR). In spite of the significant improvement in dissolution by solid dispersion technique, some drawbacks have limited the commercial application of solid dispersions. Thus, further studies should be conducted in a direction to improve the congeniality to commercialization.

Effects of binary conductive additives on electrochemical performance of a sheet-type composite cathode with different weight ratios of LiNi0.6Co0.2Mn0.2O2 in all-solid-state lithium batteries

  • Ann, Jiu;Choi, Sunho;Do, Jiyae;Lim, Seungwoo;Shin, Dongwook
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.413-418
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    • 2018
  • All-solid-state lithium batteries (ASSBs) using inorganic sulfide-based solid electrolytes are considered prospective alternatives to existing liquid electrolyte-based batteries owing to benefits such as non-flammability. However, it is difficult to form a favorable solid-solid interface among electrode constituents because all the constituents are solid particles. It is important to form an effective electron conduction network in composite cathode while increasing utilization of active materials and not blocking the lithium ion path, resulting in excellent cell performance. In this study, a mixture of fibrous VGCF and spherical nano-sized Super P was used to improve rate performance by fabricating valid conduction paths in composite cathodes. Then, composite cathodes of ASSBs containing 70% and 80% active materials ($LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$) were prepared by a solution-based process to achieve uniform dispersion of the electrode components in the slurry. We investigated the influence of binary carbon additives in the cathode of all-solid-state batteries to improve rate performance by constructing an effective electron conduction network.

Dissolution Characteristics of Biphenyl Dimethyl Dicarboxylate from Solid Dispersions with Copolyvidone

  • Moon, Jee-Hyun;Chun, In-Koo
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1997.04a
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    • pp.118-118
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    • 1997
  • Solid dispersions were used to increase the dissolution rate of biphenyl dimethyl dicarboxylate (DDB) in water, with the ultimate goal of optimizing its bioavailability when incoporated into pharmaceuticals. Carriers used were Kollidon 30, Kollidon VA 64, 2-hydroxypropyl-${\beta}$-cyclodextrin (HPCD), sodium salicylate or sodium benzoate. DDB solid dispersions were prepared at drug to carrier proportions ranging from 1 : 5 to 1 : 20 (w/w) by solvent evaporation method. DDB tablets (7.5 mg) were prepared by compressing the powder mixture composed of solid dispersions, lactose, corn starch, crospovidone and magnesium stearate using a single-punch press. DDB capsules (7.5 mg) were prepared by filing the mixture into empty hard gelatin capsules (size #1). Dissolution studies of DDB from powdered solid dispersions, tablets and capsules were performed in 900 $m\ell$ of water at 100 rpm and 37$^{\circ}C$ by the paddle method. The dissolved amount was assayed by HPLC and expressed as the mean(%)of three determinations.

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