• Carbon letters
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• v.9 no.2
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• pp.131-136
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• 2008

In order to investigate the effect of doping C, N, B and F elements on $TiO_2$ for reducing the band gap, the heat treatment of $TiO_2$ was carried out with tetraethylammonium tetrafluoroborate. Through XRD and XPS analysis, the C, N, B and F doped anatase $TiO_2$ was confirmed. According to the increase of temperature during treatment, the particle size was increased due to aggregation of $TiO_2$ with elements (B, C, N and F). To investigate the capacity of photocatalyst for degradation of dye under solar light, the degradation of acridine orange and methylene blue was conducted. The degradation of dyes was carried out successfully under solar light indicating the effect of doping elements (B, C, N and F) on $TiO_2$ for reducing the band gap effectively.

• The Journal of the Korea institute of electronic communication sciences
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• v.11 no.11
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• pp.1093-1100
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• 2016

This study is to demonstrate the superiority and stability of the solar - wind power hybrid power generation system for street lamps using super capacitor EDLC(:Electric Double Layer Capacitor). It is aiming to apply the lighting device using LED light source as the load of solar-wind power hybrid power generation system for independent power source and to develop the street light system device with high output power generation system. Unlike conventional controllers, EDLC, which is used as an auxiliary device for storing the developed power in the battery, can guarantee the high output and long life of the battery.

• Transactions on Electrical and Electronic Materials
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• v.16 no.4
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• pp.212-220
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• 2015

We investigated nanotextured Si solar cells using the silver-assisted chemical etching process. The nanotexturing process is very sensitive to the concentration of chemical etching solution. The high concentration process results in a nanowire formation for the nanosurfaces and causes severe surface damage to the top region of the micropyramids. These nanowires show excellent light absorption in photoreflectance spectra and radiative light emission in photoluminescence spectra. However, the low concentration process forms a nano-roughened surface and provides high minority carrier lifetimes. The nano-roughened surfaces of the samples show the improved electrical cell properties of quantum efficiency, conversion efficiency, and cell fill factor due to the reduction in the formation of the over-doped dead layer.

• Journal of the Korean Solar Energy Society
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• v.29 no.2
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• pp.70-75
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• 2009

In this experiment, we did sampling 6 kinds of photovoltaic modules and analyzed the discrepancy of measurement results between l laboratory and 4 PV makers to have performance repeatability at Standard Test Condition(STC) condition. From the KIER's results, Korea's standard test laboratory, other laboratory showed -10% measurement variation. The causes came from correction of reference cell, test condition and the state of skill. Form the comparison test, we analyzed the problems. But three PV maker reduced measurement variation, other one PV maker and one test laboratory didn't improve the problems of correction of reference cell, test condition and the state of skill. Also, High Efficiency Module had a big discrepancy of -10.0$\sim$-6.2% among 3 laboratories which have a less than 10msec light pulse duration time. This made low spectrum response speed so the Fill Factor decreased maximum output power under 10msec light pulse duration time

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.3-4
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• 2008

Photovoltaic module consists of serially connected solar cell which has low voltage characteristics. But, the other way, the whole current flow of PV module is restricted by lowest current of one solar cell. For the experiment, we make PV module composing the solar cells that have short circuit current difference of 0%, 1%, 3% and 5%. Using Light I-V and Dark I-V measurements, electrical characteristic parameters like Isc(short-circuit current), Voc(open-circuit voltage), Rs(series resistance), Rsh(shunt resistance) are analyzed. PV module of low current characteristics has electrical stress from other modules. And, such a module has a tendency of hot-spot suffering which leads degradation.

• Journal of the Korean institute of surface engineering
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• v.50 no.5
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• pp.315-321
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• 2017

Antireflective pyramid arrays can be readily obtained via anisotropic etching in alkaline solution (KOH, NaOH), which is widely used in crystalline-Si (c-Si) solar cells. The periodic inverted pyramid arrays show even lower light reflectivity because of their superior light-trapping characteristics. Since this inverted pyramidal structures are mostly achieved using very complex techniques such as photolithograpy and laser processes requiring extra costs, here, we demonstrate the Cu-nanoparticle assisted chemical etching processes to make the inverted pyramidal arrays without the need of photolithography. We have mainly controlled the concentration of $Cu(NO_3)_2$, HF, $H_2O_2$ and temperature as well as time factors that affecting the reaction. Optimal inverted pyramid structure was obtained through reaction parameters control. The reflectance of inverted pyramid arrays showed < 10% over 400 to 1100 nm wavelength range while showing 15~20% in random pyramid arrays.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.70-70
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• 2013

As the costs of carbon-footprinetd fuels grow continuously and simultaneously atmospheric carbon dioxide concentration increases, solar fuels are receiving growing attention as alternative clean energy carriers. These fuels include molecular hydrogen and hydrogen peroxide produced from water, and hydrocarbons converted from carbon dioxide. For high efficiency solar fuel production, not only light absorbers (oxide semiconductors, Si, inorganic complexes, etc) should absorb most sunlight, but also charge separation and interfacial charge transfers need to occur efficiently. With this in mind, this talk will introduce the fundamentals of solar fuel production and artificial photosynthesis, and then discuss in detail on photoelectrochemical (PEC) water splitting and CO2 conversion. This talk largely divides into two section: PEC water oxidation and PEC CO2 reduction. The former is very important for proton-coupled electron transfer to CO2. For this oxidation, a variety of oxide semiconductors have been tested including TiO2, ZnO, WO3, BiVO4, and Fe2O3. Although they are essentially capable of oxidizing water into molecular oxygen, the efficiency is very low primarily because of high overpotentials and slow kinetics. This challenge has been overcome by coupling with oxygen evolving catalysts (OECs) and/or doping donor elements. In the latter, surface-modified p-Si electrodes are fabricated to absorb visible light and catalyze the CO2 reduction. For modification, metal nanoparticles are electrodeposited on the p-Si and their PEC performance is compared.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.11
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• pp.5172-5177
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• 2011

This paper presents a reflection coating design scheme in the thin-film silicon solar cell. The antireflection(high reflection) coating skill is needed in the front(back) panel of the thin-film solar cell to improve an efficiency of light absorbing. In the single structure a reflectivity is changed according to the thickness of coating for antireflection scheme and its minimum value can be obtained by controlling thickness of coating. In the symmetric multi layer structure low reflectivity can be obtained in the wide wavelength range. And we also find that high reflectivity can be obtained through multi layer structure, which has alternate layers of high and low material, for high reflection scheme in the back panel.

• Journal of the Korean Solar Energy Society
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• v.28 no.4
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• pp.35-42
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• 2008

Besides genuine skin and clothes, it is called that building is third skin for us. That means the skin of buildings is the most important factor for our man-made environment. The issues in designing the building envelope include the insulation, infiltration, ventilation and bridging in windows. Getting light into the space safely and providing views to outdoor, additionally, are key things with the building envelope design. A deep-rooted preference for full view is still alive with large area of glass. Balcony expansion is legalized in apartment houses, which causes lots of environmental problems. Without balcony space, the adjacent space to unshaded window is exposed to the direct sun. A window can have many layers and the inner space can be utilized with an automatic blind system. Recently, the refurbished version of a double-glazed window system has been developed for the purpose of minimizing energy loss occurred around windows. For the better daylight control with equipped blind system, a set of adjustment technique of blind slats was tested in a mock-up building and recommended the detail operation. Not surprisingly, the optimized blind system can be oriented to enhance the uniformity in light distribution and direct glare from the sky as well..

• Journal of Electrochemical Science and Technology
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• v.9 no.4
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• pp.308-319
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• 2018

Single step electrodeposition of $Cu_2ZnSnS_4$ (CZTS) for solar cell applications was studied using an aqueous thiocyanate based electrolyte. The sodium thiocyanate complexing agent was found to decrease the difference in the deposition potential of the elements. X-ray diffraction analysis of the samples indicates the formation of kesterite phase CZTS. UV-vis studies reveal the band gap of the deposits to be in the range of 1.2 - 1.5 eV. The thickness of the deposit was found to decrease with increase in pH of the electrolyte. Nearly stoichiometric composition was obtained for CZTS films coated at pH 2 and 2.5. I-V characterization of the film with indium tin oxide (ITO) substrate in the presence and the absence of light source indicate that the resistance decrease significantly in the presence of light indicating suitability of the deposits for solar cell applications. Results of electrochemical impedance spectroscopic studies reveal that the cathodic process for sulfur reduction is the slowest among all the elements.