• 제목/요약/키워드: Solar Photovoltaics

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Mo : Na/Mo 이중층 구조 두께에 따른 태양전지 후면전극의 조직 및 전기적 특성 (Morphology and Electrical Properties of Back Electrode for Solar Cell Depending on the Mo : Na/Mo Bilayer Thickness)

  • 신윤학;김명한
    • 한국재료학회지
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    • 제23권9호
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    • pp.495-500
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    • 2013
  • Mo-based thin films are frequently used as back electrode materials because of their low resistivity and high crystallinity in CIGS chalcopyrite solar cells. Mo:Na/Mo bilayer thin films with $1{\mu}m$ thickness were deposited on soda lime glass by varying the thickness of each layer using dc-magnetron sputtering. The effects of the Mo:Na layer on morphology and electrical property in terms of resistivity were systematically investigated. The resistivity increased from $159{\mu}{\Omega}cm$ to $944{\mu}{\Omega}cm$; this seemed to be caused by increased surface defects and low crystallinity as the thickness of Mo:Na layer increased from 100 nm to 500 nm. The surface morphologies of the Mo thin films changed from a somewhat coarse fibrous structures to irregular and fine celled structures with increased surface cracks along the cell boundaries as the thickness of Mo:Na layer increased. Na contents varied drastically from 0.03 % to 0.52 % according to the variation of Mo:Na layer thickness. The change in Na content may be ascribed to changes in surface morphology and crystallinity of the thin films.

$TiO_2$ 나노 입자의 중간 전극을 이용한 직렬 적층형 유기 태양 전지 (Solution-processed Polymer Tandem Cells Using Nano Crystalline $TiO_2$ Interlayer)

  • 정원석;주병권;고민재;박남규;김경곤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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    • pp.444-444
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    • 2008
  • For the polymer tandem cell, simple and advantaged solution-based method to electron transport intermediate layer is presented which are composed $TiO_2$ nanoparticles. Device were based on a regioregular Poly(3-hexylthiophene)(P3HT) and [6,6]-phenyl $C_{61}$ butyric acid methyl ester($PC_{60}BM$) blend as a donor and acceptor bulk-heterojunction. For the middle electrode interlayer, the $TiO_2$ nanoparticles were well dispersed in ethanol solution and formed thin layer on the P3HT:PCBM charge separation layer by spin coating. The layer serves as the electron transport layer and divides the polymer tandem solar cell. The open-circuit voltage (Voc) for the polymer tandem solar cells was closed to the sum of those of individual cells.

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1,2-Dichlorobenzene Solvent를 이용한 고분자 유기태양전지에서 박막 두께에 따른 나노 구조와 열처리 효과 (Nanostructure and Thermal Effects Dependent on the Film Thickness in Poly(3-hexylthiophene):Phenyl-C61-butyric Acid Methyl Ester(P3HT:PCBM) Films Fabricated by 1,2-Dichlorobenzene Solvent for Organic Photovoltaics)

  • 이현휘;김효정
    • 한국염색가공학회지
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    • 제26권4호
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    • pp.347-352
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    • 2014
  • Film thickness dependent nanostructure evolution by a post annealing was investigated in poly (3-hexylthiophene):phenyl-C61-butyric acid methyl ester(P3HT:PCBM) films for organic solar cells which were fabricated by dichlorobenzene(DCB) solvent. In case of a 70nm thin film, the thermal annealing process affected to slight increment of the P3HT crystals in the surface region. On the other hand, large number of small sized P3HT crystals near the surface region was formed in the 200nm thick film. The solar cell devices showed the 3% power conversion efficiency(PCE) in 1:0.65 and 1:1 ratio(by weight) of P3HT and PCBM in 70nm and 200nm thickness conditions, respectively. Despite to the similar PCE, the short circuit current Jsc was different in 70nm and 200nm devices, which was related to the different nanostructure of P3HT:PCBM after thermal annealing.

ZnO 나노 분말 코팅 기반 건식전사 그래핀 전극 제작 및 유기태양전지 응용 (Partially Dry-Transferred Graphene Electrode with Zinc Oxide Nanopowder and Its Application on Organic Solar Cells)

  • 조영수;우채영;홍순규;이형우
    • 한국분말재료학회지
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    • 제27권4호
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    • pp.305-310
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    • 2020
  • In this study, partially dry transfer is investigated to solve the problem of fully dry transfer. Partially dry transfer is a method in which multiple layers of graphene are dry-transferred over a wet-transferred graphene layer. At a wavelength of 550 nm, the transmittance of the partially dry-transferred graphene is seen to be about 3% higher for each layer than that of the fully dry-transferred graphene. Furthermore, the sheet resistance of the partially dry-transferred graphene is relatively lower than that of the fully dry-transferred graphene, with the minimum sheet resistance being 179 Ω/sq. In addition, the fully dry-transferred graphene is easily damaged during the solution process, so that the performance of the organic photovoltaics (OPV) does not occur. In contrast, the best efficiency achievable for OPV using the partially dry-transferred graphene is 2.37% for 4 layers.

국내 주택부문 태양광 보급정책에 대한 시민 인식분석 (Analysis of Citizens' Recognition on Photovoltaic System Supply Policies in Domestic Housing Sector)

  • 반영운;이태호
    • 한국태양에너지학회 논문집
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    • 제30권2호
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    • pp.1-9
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    • 2010
  • This study has intended to analyze citizen's recognition on Photovoltaic (PV) System Supply Policy in Korea. To reach this goal, this study has employed a survey method and statistical analysis. We have asked 140 citizens knowing the policy to some degree to answer questionnaires including various contents related to PV supply policy driven by central government of Korea. The contents of questionnaires consist of three parts: 1) supply policies, 2) PV system and 3) expected effect from the policy. To verify any differences among the characteristics of respondents, ANOVA (Analysis of Variance) was carried out in 95% confidence level. This study has found the following results: 1) most citizens were positive about the 'Photovoltaic System Supply Policies'; 2) most citizens anticipated the policy would be helpful to cope with the environmental problems and energy crisis and 3) there exit subtle differences between residents according to the respondent's characteristics such as sex, age, occupation, and housing type.

실리콘 태양전지 재자원화를 위한 초임계 CO2 및 헥산을 이용한 구리 및 산화구리 제거기술 개발 (Development of Copper and Copper Oxide Removal Technology Using Supercritical CO2 and Hexane for Silicon Solar Cell Recycling)

  • 이효석;조재유;허재영
    • Current Photovoltaic Research
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    • 제7권1호
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    • pp.21-27
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    • 2019
  • Lifetime of Si photovoltaics modules are about 25 years and a large amount of waste modules are expected to be discharged in the near future. Therefore, the extraction and collection of valuable metals out of discharged Si modules will be one of the important technologies. In this study, we demonstrated that supercritical $CO_2$ extraction method can be effectively used to remove Cu, one of the abundant elements in the module, as well as its oxide form, $Cu_2O$. Especially, we proved that the addition of hexane as co-solvent is effective for the removal of both materials. The optimal ratio of $CO_2$ and hexane was 4:1 at a fixed temperature and pressure of $250^{\circ}C$ and 250 bar, respectively. In addition, it was proven that the removal of $Cu_2O$ was preceded via reduction of $Cu_2O$ to Cu.

Electrical Loss Reduction in Crystalline Silicon Photovoltaic Module Assembly: A Review

  • Chowdhury, Sanchari;Kumar, Mallem;Ju, Minkyu;Kim, Youngkuk;Han, Chang-Soon;Park, Jinshu;Kim, Jaimin;Cho, Young Hyun;Cho, Eun-Chel;Yi, Junsin
    • Current Photovoltaic Research
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    • 제7권4호
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    • pp.111-120
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    • 2019
  • The output power of a crystalline silicon (c-Si) photovoltaic (PV) module is not directly the sum of the powers of its unit cells. There are several losses and gain mechanisms that reduce the total output power when solar cells are encapsulated into solar modules. Theses factors are getting high attention as the high cell efficiency achievement become more complex and expensive. More research works are involved to minimize the "cell-to-module" (CTM) loss. Our paper is aimed to focus on electrical losses due to interconnection and mismatch loss at PV modules. Research study shows that among all reasons of PV module failure 40.7% fails at interconnection. The mismatch loss in modern PV modules is very low (nearly 0.1%) but still lacks in the approach that determines all the contributing factors in mismatch loss. This review paper is related to study of interconnection loss technologies and key factors contributing to mismatch loss during module fabrication. Also, the improved interconnection technologies, understanding the approaches to mitigate the mismatch loss factors are precisely described here. This research study will give the approach of mitigating the loss and enable improvement in reliability of PV modules.

Hole and Pillar Patterned Si Absorbers for Solar Cells

  • Kim, Joondong;Kim, Hyunyub;Kim, Hyunki;Park, Jangho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.226-226
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    • 2013
  • Si is a dominant solar material, which is the second most abundant element in the earth giving a benefit in the aspect in cost with low toxicity. However, the inherent limit of Si has an indirect band gap of 1.1 eV resulting in the limited optical absorption. Therefore, a critical issue has been raised to increase the utilization of the incident light into the Si absorber. The enhancement of light absorption is a crucial to improve the performances and thus relieves the cost burden of Si photovoltaics. For the optical aspect, an efficient design of a front surface, where the incident light comes in, has been intensively investigated to improve the performance of photon absorption. Lambertian light trapping can be attained when the light active surface is ideally rough to increase the optical length by about 50 compared to a planar substrate. This suggests that an efficient design may reduce thickness of the Si absorber from the conventional 100~300 ${\mu}m$ to less than 3 ${\mu}m$. Theoretically, a hole-array structure satisfies an equivalent efficiency of c-Si with only one-twelfth mass and one-sixth thickness. Various approaches have been applied to improve the incident light utilization in a Si absorber using textured structures, periodic gratings, photonic crystals, and nanorod arrays. We have designed hole and pillar structured Si absorbers. Four-different Si absorbers have been simultaneously fabricated on an identical Si wafer with hole arrays or pillar arrays at a fixed depth of 2 ${\mu}m$. We have found that the significant enhanced solar cell performances both for the hole arrayed and pillar arrayed Si absorbers compared to that of a planar Si wafer resulting from the effective improvement in the quantum efficiencies.

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태양광발전시스템의 건물 적용에 대한 인식 조사 연구 (A Survey of the Recognition of Photovoltaic System for Building Application)

  • 이충국;유권종;서승직
    • 한국태양에너지학회 논문집
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    • 제23권1호
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    • pp.17-28
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    • 2003
  • This study aims to investigate and analyze the overall recognition of the photovoltaic system for the application of BIPV(Building Integrated Photovoltaic) in Korea. For this purpose, a survey was carried on through questionnaires answered by 6 groups of experts such as construction engineers, registered architects, mechanical engineers, electrical engineers, university or college professors, and others who are ranked high in their companies or universities or colleges and who mostly seem to be eager to participate in the development of the PV system and to make a business of the system. The results of the survey are as follows: 1. About 95% of those experts who answered the questionnaire have known about renewable energy, and 93% of them are interested in solar energy as alternative energy 2. Host experts have a lot of information on the solar energy system, but have scanty information on the PV system. 3. The experts in the educational and research field have researched for the reasonable period of the participation in the development of the PV system and the period of making a business of the system. They judge that companies in the mechanical and electrical field will participate in the development of the PV system and will make a business of the system in 5 years. 4. The experts have thought that the PV system is designed not for economy but for the environment of the earth and that PV system technology in Korea is much lower than that in the advanced countries. 5. The experts hesitate to participate in the development of the PV system and to make a business of the system because they have little confidence in the economy of the PV system now and because they have thought that they will bear a great financial burden of construction cost 6. The experts judge that it is most desirable to apply the PV system to the rooftops of buildings. And they are greatly interested in the BIPV.

도심 수목이 분산형 주거 태양광에너지 잠재량에 미치는 영향 (The Effect of Urban Trees on Residential Solar Energy Potential)

  • 고예강
    • 한국조경학회지
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    • 제42권1호
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    • pp.41-49
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    • 2014
  • 본 연구는 미국 샌프란시스코시 수목 음영이 개별 건물 지붕 및 옥상에 입사되는 태양에너지 잠재량에 미치는 영향을 LiDAR를 이용한 고해상도 3차원 수치모델을 이용하여 공간적으로 정량화하였다. 최근 분산형 태양광 발전이 기후변화 대응에 중요한 부분으로 주목받고 있으나, 이러한 도심 태양광 발전은 주변부의 지형, 건물, 지붕모양, 수목 등의 음영에 의해 발전량이 제한되는 특성이 있다. 특히 건물 주변의 수목의 경우 도시열섬현상의 저감, 냉난방 에너지 수요량의 절감 등의 순기능과 태양광 발전량 감소의 역기능을 동시에 가지고 있어 두 가지 효용의 상충을 최소화하기 위해 해당 위치에 대한 공간적 분석이 요구된다. 샌프란시스코시 전체 건물 지붕면적의 태양에너지 총량은 년간 18,326,671 MWh으로, 수목의 음영에 의한 감소량은 326,406 MWh로 총량의 1.78%에 해당하였다. 건물지붕의 단위 면적당 일조량은 $34.4kWh/m^2/year$에서 $1,348.4kWh/m^2/year$ 범위로 산출되었다. 본 연구를 통해 도심 수목에 의한 건물별 일조에너지 감소량의 공간자료가 구축되었으며, 개별 건물지붕에 일조량의 변이를 주변 수목의 밀도, 평균수고, 수고의 분산값을 이용한 회귀모델을 통해 설명하였다. 본 연구는 도심수목의 환경적 순기능을 유지함과 동시에 태양광 발전 감소량의 최소화 할 수 있는 방법을 제공함으로써 지속가능한 도시를 구축하는데 기여할 것으로 기대된다.