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Opto-Chemical Characteristics of Visibility Impairment Using Semi-Continuous Aerosol Monitoring in an Urban Area during Summertime (에어로졸의 준실시간 관측에 의한 여름철 도시지역 시정 감쇄 현상의 광ㆍ화학적인 특성 분석)

  • 김경원;김영준
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.647-661
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    • 2003
  • For continuous monitoring of atmospheric visibility in the city of Kwanaju, Korea, a transmissometer system consisting of a transmitter and a receiver was installed at a distance of 1.91 km across the downtown Kwanaju. At the transmitter site an integrating nephelometer and an aethalometer were also installed to measure the scattering and absorption coefficients of the atmosphere, respectively. At the receiver site. an URG PM$_{2.5}$ cyclone sampler and an URG-VAPS (Versatile Air Pollutant Sampler) with three filter packs and two denuders were used to collect both PM$_{2.5}$ and PM$_{10}$ samples at a 2-hour or 12-hour sampling interval for aerosol chemical analysis. Sulfate, organic mass by carbon (OMC), nitrate, elemental carbon (EC) components of fine aerosol were the major contributors to visibility impairment. Diurnal variation of visibility during best-case days showed rapid improvement in the morning hours, while it was delayed until afternoon during the worst-case days. Aerosol mass concentration of each aerosol component for the worst-case was calculated to be 11.2 times larger than the best-case for (NH$_4$)$_2$SO$_4$(NHSO), 19.0 times for NH$_4$NO$_3$ (NHNO), 2.2 times for OMC, respectively. Also result shows that elemental carbon and fine soil (FS) were 3.7 and 2.2 times more than those of best-case. respectively- Sum of total contributions of wet NHSO and NHNO to light extinction was calculated to be 301 Mm$^{-1}$ for the worst-case. However, sum of contributions by dry NHSO and NHNO was calculated to be 123 Mm$^{-1}$ for the best case. Mass extinction efficiencies of fine and coarse particles were calculated to be 5.8$\pm$0.3 $m^2$/g and 1.8$\pm$0.1 $m^2$/g, respectively.ely.

Source Identification of Ambient PM-10 Using the PMF Model (PMF 모델을 이용한 대기 중 PM-10 오염원의 확인)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.701-717
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    • 2003
  • The objective of this study was to extensively estimate the air quality trends of the study area by surveying con-centration trends in months or seasons, after analyzing the mass concentration of PM-10 samples and the inorganic lements, ion, and total carbon in PM-10. Also, the study introduced to apply the PMF (Positive Matrix Factoriza-tion) model that is useful when absence of the source profile. Thus the model was thought to be suitable in Korea that often has few information about pollution sources. After obtaining results from the PMF modeling, the existing sources at the study area were qualitatively identified The PM-10 particles collected on quartz fiber filters by a PM-10 high-vol air sampler for 3 years (Mar. 1999∼Dec.2001) in Kyung Hee University. The 25 chemical species (Al, Mn, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, Ce, Pb, Si, N $a^{#}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, TC) were analyzed by ICP-AES, IC, and EA after executing proper pre - treatments of each sample filter. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols. the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided source profiles (scaled F matrix). So, 11 sources were qualitatively identified, such as secondary aerosol related source, soil related source, waste incineration source, field burning source, fossil fuel combustion source, industry related source, motor vehicle source, oil/coal combustion source, non-ferrous metal source, and aged sea- salt source, respectively.ively.y.

Study on Airborne Particulate Matter ($PM_{10}$) Monitoring in Urban and Rural Area by Using Gent SFU Sampler and Instrumental Neutron Activation Analysis (중성자 방사화분석법과 Gent SFU 샘플러를 이용한 도시의 농촌지역의 대기분지($PM_{10}$)관측 연구)

  • 정용삼;문종화;김선하;박광원;강상훈
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.5
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    • pp.453-467
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    • 2000
  • The aim of this research is to collect and characterize fine particles (FPM:$\leq$2.5${\mu}{\textrm}{m}$) and coarse particles (CPM: 2.5~10${\mu}{\textrm}{m}$) using a low volume air sampler provided by the IAEA, at urban (Taejon) and rural area(Wonju) for a period of about two years(April 1996 to May 1998) and to promote a use of nuclear analytical techniques for air pollution studies. For the collection of airborne particulate matter (PM(sub)10), the Gent stacked filter unit sampler and polycarbonate membrane filters were employed. The concentration of trace elements in collected APM samples were determined byu instrumental Neutron Activation Analysis. For validation of the analytical data, internal quality control were implemented by using both the comparison of the analytical results of standard reference materials(NIST SRM 1648) and interlaboratory comparison for proficiency test (NAT-3). The standard uncertainty was less than 15% and Z-score of two samples were within $\pm$1. The monitoring of (PM(sub)10) mass concentration and elemental concentrations were carried out weekly. The average mass concentration of (PM(sub)10) in urban and rural areas were 59.2$\pm$36.5$\mu\textrm{g}$/㎥ and 41.4$\pm$23.7$\mu\textrm{g}$/㎥, respectively. To investigate the emission source, the enrichment factors were calculated for the fine and coarse particle fractions at two sites, respectively and these values were classified for anthropogenic and soil origin elements.

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Isolation and physiological characteristics of cellulolytic bacteria (섬유소 분해세균의 분리 및 생리적인 특성)

  • Kwon, Oh-Jin;Chung, Yung-Gun
    • Applied Biological Chemistry
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    • v.37 no.4
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    • pp.226-233
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    • 1994
  • Three hundred and one cellulolytic bacterial were isolated from the 148 screening sources such as decomposed wood, soil, compost and leaf mold. Among them, strain KL-6 was found to have the highest of cellulase activity, and identified as species belonged to the genus Cellulomonas. Strain KL-6 was decompose up to 90% of the filter paper (whatman No. 1) substrate within 50 hours, and showed the colony halo formation (11 cm). The activities of CMCase (67 unit/ml), FPase (70 unit/ml) and ${\beta}-glucosidase$ (0.68 unit/ml) were obtained when this strain was cultured for 50 hrs at $30^{\circ}C$. Glucose was not found in detectable amounts at the FP medium. The optimum composition of nutrient medium for the cell growth by strain KL-6 was sucrose 0.5%, yeast extract 0.1%, $(NH_4)_2HPO_4\;0.1%$, $K_2HPO_4\;0.1%$, $MgSO_4{\cdot}7H_2O\;0.01%$, $CaCl_2\; 0.01%$, NaCl 0.6%, $CaCO_3\;0.1%$ and the optimum pH and temperature were 7.0 and $30^{\circ}C$, respectively.

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An Orchestrated Attempt to Determine the Chemical Properties of Asian Dust Particles by PIXE and XRF Techniques

  • Ma, Chang-Jin;Kim, Ki-Hyun;Choi, Sung-Boo;Kasahara, Mikio;Tohno, Susumu
    • Asian Journal of Atmospheric Environment
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    • v.4 no.3
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    • pp.189-197
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    • 2010
  • An orchestrated attempt was made to analyze samples of bulk and individual particulate matters (PM) collected at the Gosan ground-based station on the west coast of Jeju, Korea. A two-stage filter pack sampler was operated to collect particles in both large (> $1.2\;{\mu}m$) and small size fractions (< $1.2\;{\mu}m$) between the Asian dust (hereafter called "AD") storm event and non-Asian dust period. Elemental components in bulk and individual particles were determined by PIXE and synchrotron XRF analysis systems, respectively. To assess the transport pathways of air parcels and to determine the spatial distribution of PM, the backward trajectories of the Meteorological Data Explorer (Center for Global Environmental Research, 2010) and the NOAA's HYSPLIT dispersion-trajectory models were applied. In line with general expectations, Si and other crustal elements in large size particles showed considerably higher mass loading on AD days in comparison with non-AD days. Computation of the crustal enrichment factors [(Z/Si)$_{particle}$/(Z/Si)$_{desert}$ sand] of elements in large size particles (> $1.2\;{\mu}m$) allowed us to estimate the source profile and chemical aging of AD particles as well as to classify the soil-origin elements. On the basis of a single particle analysis, individual AD particles are classified into three distinct groups (neutralized mineral particles, S-rich mineral particles, and imperfectly neutralized particles).

A Study for Characteristics of PM10 in the Subway Passenger Cabins (지하철 전동차 객실에서의 PM10 오염특성 파악에 관한 연구)

  • Oh, Mi-Seok;Park, Duck-Shin;Park, Eun-Young
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.5
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    • pp.523-533
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    • 2011
  • This study had the aim of characteristics of $PM_{10}$ in subway cabins. $PM_{10}$ was measured by times of day (rush and non rush hours) and seasons with real time $PM_{10}$ sampler on the subway cabins of line 7. Filter samples were collected for evaluation of their elemental composition as well as identification of major sources of $PM_{10}$ using a receptor model, PMF. $PM_{10}$ concentration were the highest in the winter season both in the rush and non rush hours at 152.8 ${\mu}g/m^3$, 90.2 ${\mu}g/m^3$ respectively. The $PM_{10}$ concentrations in rush hour were 30% higher compared to non rush hours. Based on the chemical information, the composition rare of inorganic elements was 52.5%, anions were 10.2% and others were 37.3%. Fe was the most abundant element and significantly correlated (p.0.01) with Mn (r=0.97), Ti (r=0.91), Cr (r=0.88), Ni (r=0.89) and Cu (r=0.88). Characterized $PM_{10}$ sources by PMF in the cabin were soil and road dust related sources (27.2%), railroad related sources (47.5%), secondary nitrate sources (16.2%) and a Cl-factor mixed with a secondary sulfate source (9.1%).

Isolation and Characterization of an Alkalophilic Cellulolytic Bacterium Pseudomonas sp. (호알칼리성 섬유소분해세균 Pseudomonas sp.의 분리 및 특성)

  • Lim, Sang-Ho;Yoon, Min-Ho;Choi, Woo-Young
    • Korean Journal of Agricultural Science
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    • v.25 no.1
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    • pp.124-130
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    • 1998
  • An alkalophilic bacterium, the strain AC-711 as a potent producer of alkaline cellulase, was selected among many isolates from soil environments. Morphological, physiological and chemical characteristics of the strain AC-711 suggested that it belongs to the genus Pseudomonas according to the Bergey's Manual of Systematic Bacteriology, however the G+C mol% (54.43) of its chromosomal DNA is lower than the normal values of the genus. The major cell wall fatty acids were determined as 15:0 and 17:0 anteiso. The production of alkaline CMCase by the strain was maximal when grown on the mediun containing 1% carboxymethyl cellulose, 0.1% $KH_2PO_4$, 0.02% $CoCl_2$, 0.02% Tween 80, 0.5% $Na_2CO_3$, 0.8% yeast extract, pH 10.3 at $30^{\circ}C$ for 3 days, and the most of enzyme was excreted into culture mediun.

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A Study on Performance of Double-Core PBD for Improving Thick Reclaimed Ground (대심도 연약지반 개량을 위한 이중코어 PBD 성능연구)

  • Yang, Jeong-Hun;Hong, Sung-Jin;Lee, Woo-Jin;Choi, Hang-Seok;Kim, Hyung-Sub
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.281-292
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    • 2008
  • Prefabricated Board Drains (PBDs) recently become more widely used than conventional sand drains in improving soft ground because the PBD is more time and cost effective. The performance of PBDs is affected by disturbance in the adjacent soil formation during inserting mandrels, the intrusion of fine particles into filter fabric, and necking of the drain by excessive lateral pressure especially occurring in very deep clay formation such as the Busan New Port site. In this study, the PBD with double-core is introduced, which seems to overcome the shortcomings of usual single-core PBDs. An in-situ test program was established in the Busan New Port site, in which a set of the double-core PBDs and the single-core PBDs was installed to compare the efficiency of each of the drains. The discharge capacity of the double-core and the single-core PBDs was compared for various confining pressures in the modified Delft test and the chamber test. A series of CRS consolidation tests was performed in order to obtain profiles of void ratio-effective stress and void ratio-permeability relationships in the Busan New Port site that are used as input date in performing a numerical program ILLICON. The numerically simulated settlements of ground surface in the test site are in good agreement with those of in-situ measurements. In addition, the performance of the double-core and single-core PBDs has been experimentally and numerically compared in this paper.

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The Physio-Chemical Characteristics of Aerosol in Urban Area During Snowfall (강설시 도심지역 에어러솔의 물리.화학적 특성)

  • 김민수;이동인;유철환
    • Journal of Environmental Science International
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    • v.10 no.3
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    • pp.201-208
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    • 2001
  • To investigate the physio-chemical components and properties of aerosol particles in urban area sampling of aerosol particles was carried out in the campus of Hokkaido University, Sapporo, Japan, during snowfall. Aerosol particles were collected on millipore filter papers using a low volume air sampler. Their shapes, sizes and chemical components were analyzed by a SEM(Scanning Electron Microscope) and an EDX(Energy Dispersive X-ray). As a results, ice crystals of dendrite and column types were predominantly shown at mature and developing stage of snowfall intensity. The denerite and sector plate types of ice crystals were mainly originated from the sea but column types were come from soil. Scavenging effect by snowfall was greatly also shown at dendrite type ice crystals that embryo was fully developd. Al, Si elements were shown at high frequencies as compared with others. Na, Cl components were especially shown at high frequencies under the sea-breeze wind during snowfall. Anthropogenic aerosol particles had shown with irregular shapes and sizes, relatively. Mainly 3-7$\mu$m aerosol particles were abundant and coarse particles also could be seen during snowfall. Ca, Zn, Fe components mainly caused by spike tires from vehicles in winter season were dominant before snowfall, however the element S mainly caused by human activity was rich after snowfall. The pH values of snow in Sapporo city were higher than those at coastal area. The concentration of chemical components in aerosol particles was also affected by surface winds. Aerosol particles in urban area, Sapporo were mainly affected by human activities like vehicles and combustion with wind system. And their types were related with snowfall intensity.

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Screening and Identification of Antifungal Bacillus sp. #72 against the Pathogenic Stem-end Rot of Kiwi Fruit (참다래 꼭지썩음병을 일으키는 Diaporthe actinidiae을 억제하는 길항성 Bacillus sp. #72의 분리 및 동정)

  • Cho, Jung-Il;Cho, Ja-Yong;Park, Yong-Seo;Yang, Seung-Yul;Heo, Buk-Gu
    • The Korean Journal of Community Living Science
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    • v.18 no.2
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    • pp.241-246
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    • 2007
  • This study was conducted to select and screen for an antifungal bacterial strain showing pathogen inhibitory activity against Diaporthe actinidiae, which causes stem-end rot in kiwi fruit. Four bacterial strains were isolated which strongly inhibit Diaporthe actinidiae from among two hundred and fifty bacterial strains screened from the soil where kiwi fruit were grown. By co-culturing bacterial strain #72 and the pathogen causing the stem-end rot of kiwi fruit, bacterial strain #72 showed 81.0% antifungal activity against Diaporthe actinidiae. Bacterial strain #72 was identified to be from the genus Bacillus sp. based on morphological and biochemical characterization. The bacterialization of culture broth for Bacillus sp. #72 which was sterilized at $121^{\circ}C$ for 15 minutes and than purified by $0.45{\mu}m$ membrane filter showed almost all of the antagonistic activity against Diaporthe actinidiae. We have also confirmed that in vitro treatment of Bacillus sp. #72 cultured in SD+B+P(sugar 5%, soy sauce 3%, beef extract 0.2%, peptone 0.2%) medium efficiently inhibited the growth of Diaporthe actinidiae responsible for stem-end rot in kiwi fruit.

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