• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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• pp.393-396
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• 2003

Soil contains the several kinds of metal oxides. Magnetite in soil may contribute the generation of secondary waste during the decontamination of soil by citric acid. Dissolution of magnetite powders by citric acid was investigated in the pH range between 2.0 and 5.0. The dissolution behaviour of magnetite was well described by the equation, A[1 - $e^{-B(x-c)}$]. The parameters of the equation were optimized by the iteration method, and the physical meaning of each parameter was explained. Concentration of each of the dissociated chemical species of citric acid was calculated using the ionization constants. The dissolution reaction was explained by the concentration of the dissociated chemical species of citric acid.d.

• 조명전기설비학회논문지
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• 제24권4호
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• pp.103-109
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• 2010

이 논문은 동축원통형 전극계에서 임펄스전류에 의한 토양의 절연파괴특성에 관한 것으로 4종의 토양에 대한 절연파괴전압과 전류를 측정하고, 절연파괴를 일으키는 전계의 세기, 절연파괴까지의 지연시간과 전압-전류곡선을 분석하고 검토하였다. 그 결과, 절연파괴전압과 전류 파형은 토양입자의 크기에 의존하며, 자갈과 모래의 절연파괴 전압과 전류 파형은 마사토와 황토의 파형과는 다르게 나타났다. 절연파괴를 일으키는 전계의 세기는 자갈, 모래, 황토, 마사토의 순으로 높았으며, 모든 시료의 전압-전류곡선은 ${\infty}$모양의 교차폐곡선을 나타내었다. 또한 자갈과 모래의 절연파괴까지의 시간지연은 마사토나 황토보다 길게 나타났다. 본 연구 결과는 토양의 이온화를 고려하여 낙뢰전류가 입사되는 접지전극시스템의 과도적 성능의 향상을 위한 설계에 유용한 정보가 될 것이다.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2008년도 추계학술대회 논문집
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• pp.211-215
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• 2008

This paper deals with the transient ground impedance of small-sized needle-rod installed in a test field, Impulse voltage generator was used to inject lightning impulse on a ground electrode and modified fall-of potential method was proposed to measure the high ground potential rise. Transient ground impedance was analysed with impedance curve and I-V curve as respects the resistivity of soil. Soil ionization near the ground electrode is activated in high resistivity soil and have an effect on the reduction of transient ground impedance significantly.

• Bulletin of the Korean Chemical Society
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• 제21권11호
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• pp.1101-1105
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• 2000

A simultaneous determination method of BTEX (benzene, toluene, ethylbenzene, o,m.p-xylene) and TPH (kerosene, diesel, jet fuel and bunker C) in soil with gas chromatography/flame ionization detection (GC-FID) was described. The effects of extracti on method, extraction solvent, solvent volume and extraction time on the extraction performance were studied. A sonication method was simpler and more efficient than Soxhlet or shaking methods. Sonication with 10 mL of acetone/methylene chloride (1 : 1, v/v) for 10 min was found to be optimal extraction conditions for 20 g of soil. Peak shapes and quantification of BTEX and TPH were excellent, with linear calibration curves over a wide range of 1-500 mg/L for BTEX and 10-5000 mg/L for TPH. Good reproducibilities by sonication were obtained, with the RSD values below 10%. By using about 20 g of soil, detection limits were 0.8 mg/L for BTEX and 10 mg/L for TPH. The advantages of this procedure are the use of simple and common equipment, reduced volumes of organic solvents, rapid extraction periods of less than 20 min, and simultaneous analysis of volatile and semivolatile compounds.

• 조명전기설비학회논문지
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• 제28권4호
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• pp.62-69
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• 2014

This paper deals with the fundamental characteristics of transient and conventional ground impedances associated with soil discharges when the lightning impulse voltage was applied to a small-sized ground rod. The potential rise responses of the test ground rod to impulse currents were observed. The current-voltage (I-V)curves, transient and conventional ground impedance curves were examined.. To analyze the transient behaviors of ground rod attendant upon soil discharges, the impulse responses of ground rod were compared with those of non-inductive resistor. As a consequence, the potential rise and impedance of ground rod were reduced and the currents dispersed into the earth were increased due to soil discharges near the ground rod. Soil discharges are classified into two regimes; ionization and breakdown phenomena. The potential rise and impulse impedance of ground rod are significantly decreased by breakdown processes in soil.

• 한국토양환경학회지
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• 제3권1호
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• pp.3-9
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• 1998

본 연구는 휘발성 유기 화합물로 오염된 가솔린 지역에서 soil-gas의 분석결과로부터 오염도를 유추하는 기법에 대하여 서술 하였다. Soil-gas의 채취방법으로는 펌프를 이용한 1)grab sampling법과 흡착제 trap을 사용한 2)passive sampling법이 있다. Grab sampling법은 특정시간에 특정장소에서의 오염도를 보여주며, 반면에 passive sampling법은 특정위치에서 시간에 따른 오염도의 변화를 보여 준다. Soil-gas의 분석은 1)PID나 FID와 같은 작은 검지기에 의해서 총괄 탄화수소량을 측정할수도 있고 2)기체농도에 따라서 색깔이 변하는 지시약이 채워진 기체검지기 튜브를 사용할수도 있으며 3)여러가지 화합물을 한 번에 분석할수 있는 이동형 GC를 사용할수도 있다. Soil-gas를 이용한 측정법은 매우 값싸며 세밀한 정밀조사를 하기 위한 전단계에서 사용할 수 있는 유용한 방법으로 추천할만하다 하겠다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 추계학술발표회
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• pp.458-461
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• 2003

Solid-phase microextraction (SPME) and gas chromatography/headspace techniques(HS) and flame ionization detection (GC/FID) have been combined for determination of very polar compounds in water, including the widely used gasoline oxygenates and by-products. A relatively simple extraction method using a CAR/PDMS(75${\mu}{\textrm}{m}$) SPME fiber was optimized for the routine analysis of gasoline oxygenates and by-products in groundwater and reagent water. A sodium chloride concentration of 25%(w/w) combined with an extraction time of 20 min provided the greatest sensitivity while maintaining analytical efficiency Replicate analyses in fortified reagent and groundwater spiked with microgram per liter concentrations of gasoline oxygenates and by-products indicate quantitative and reproducible recovery of these and related oxygenate compounds. Method dynamic range was 50$\mu\textrm{g}$ L-1 to 3000$\mu\textrm{g}$ L-1 for gasoline oxygenates and by-products.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 제39회 하계학술대회
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• pp.1362-1363
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• 2008

It has been known that the values of soil resistance drops when a high impulse current is injected into a grounding electrode. In this study, the electrical characteristics of medium grain size sand to different water contents are investigated. The results were discussed based on its voltage and current traces, impulse resistances and I-V curve.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2006년도 총회 및 춘계학술발표회
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• pp.338-341
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• 2006

본 연구에서는 지하수내 TCE 농도가 높은 2개 지역을 선정하여 3회에 걸쳐 공기탈기법 시험을 실시하였다. 2개 지역의 지하수내 TCE 배경 농도는 각각 0.360, 0.317 mg/L이며 반응조에 주입된 공기는 각각 17.14, 44.78, 76.51 L/min의 비율로 주입하였다. 또한 반응조에서 배출되는 기체내의 TCE의 농도를 측정하기위해 PID(photo-ionization detector)를 장착하여 측정하였다. PID를 이용하여 배출되는 기체를 측정한 결과, TCE 농도는 $6{\sim}8$분만에 최고 농도로 배출되었고 시간이 지날수록 천천히 감소하는 형태를 나타내었다. 반응조내의 TCE 농도 변화는 공기 유입 속도에 따라 매우 큰 변화를 나타내었다. TCE가 17.14 L/min의 공기유입속도에서 160분 동안 64%, 44.78 L/min에서 135분 동안 93%, 76.51 L/min에서 120분 동안 95.3%가 제거되었다. 따라서 TCE를 제거하기 위한 DAS 기법은 공기의 주입비율에 따라 제거 속도의 큰 변화를 보였다.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2003년도 총회 및 춘계학술발표회
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• pp.405-408
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• 2003

The soild phase microextraction(SPME)fiber which contains 100${\mu}{\textrm}{m}$ polydimethyl siloxane of a stationary phase was used for the analysis of volatile organic compounds contained in aqueous solution. volatile organic compounds, which were spiked in blank water and extracted by the headspace SPME techique, were analyzed by gas chromatography/flame ionization detector(GC/FID). The optimu condition of SPME fiber is determined that the analytes were extracted for 40min from extracts by using PDAfS100${\mu}{\textrm}{m}$ fiber. This new method could have wide application for the analysis of VOCs in aqueous solution.