• Journal of Soil and Groundwater Environment
• /
• v.10 no.1
• /
• pp.6-12
• /
• 2005

Contamination of soils and groundwater by leakage of petroleum compounds from underground storage tanks (USTs) has become great environmental issues. Conventional methods such as soil vapor extraction (SVE) used for the remediation of unsaturated soils contaminated with volatile organic compounds might not be applied for the removal of semi-volatile organic compounds such as diesel fuels and PCBs, which have low volatility and high hydrophobicity. The objective of this study is to develop a hot air injection method to remove semi-volatile compounds. Additionally, operation parameters such as temperature, air flow rate, and water content are evaluated. Experimental results show that diesel ranged organics (DROs) are removed in the order of volatility of organic compounds. As expected, removal efficiency of organics is highly dependent on the temperature. It is considered that more than $90\%$ of organic contaminants whose carbon numbers range between 17 and 22 can be removed efficiently by the hot air injection-extraction method (modified SVE) over the $100^{\circ}C$. It is also found that increased air flow rate resulted in high removal rate of contaminants. However, air flow rate over 40 cc/min is not effective for the operation aspects, due to mass transfer limitation on the volatilization rate of the contaminants. The effect of the water content on the decane removal is minimal, but some components show large dependence on the removal efficiency with increasing water content.

• Geophysics and Geophysical Exploration
• /
• v.19 no.1
• /
• pp.37-44
• /
• 2016

$CO_2$-EOR (Carbon Dioxide-Enhanced Oil Recovery), one of the enhanced oil recovery methods, helps to not only enhance the production of oil, but also store carbon dioxide in underground. However, if micro fractures occur when during the injection of $CO_2$, it is difficult to make permanent storage of $CO_2$ in reservoir and can cause contamination of groundwater and soil. Therefore, in this study, we performed microseismic monitoring to investigate the occurrence of fractures during the $CO_2$ injection at the Meruap oil reservoir, Indonesia. To pick the first arrivals of microseismic events, Improved MER (Modified Energy Ratio) method was used. After picking the first arrivals, hodogram analysis was carried out by using the data recorded at three component geophones to calculate the back azimuth of events. Finally, locations of microseismic events were decided by using the results of first arrival picking and hodogram analysis. Estimated locations showed that all microseismic events were occurred at surface and any fracture did not occur around the reservoir. Moreover, by analyzing noise characteristic, we confirmed that almost of picked first arrivals were due to the repetitive mechanical noise.

• Journal of Climate Change Research
• /
• v.2 no.3
• /
• pp.191-201
• /
• 2011

This study investigates how green infrastructure, including natural and open space such as forests, rivers, parks, and streets, could effectively counteract climate change in terms of mitigation and adaption, respectively. As a result, green infrastructure, such as forests, parks, vegetable gardens, roof gardens, pedestrian walkways, bike lanes, etc, could effectively mitigate climate change: 1) Carbon storage and sequestration; 2) Fossil fuel substitution; 3) Material substitution; 4) Food production 5) Reducing the need to travel by car. Secondly, green infrastructure, such as rivers, tree-lined streets, farmland, wetlands, dunes, wind ways, etc, could adapt to climate change: 1) Managing high temperatures; 2) Managing water supply; 3) Managing ravine flooding; 4) Managing costal flooding; 5) Managing surface water; 6) Reducing soil erosion; 7) Helping other species to adapt.

• Journal of the Korean Society of Groundwater Environment
• /
• v.7 no.1
• /
• pp.55-58
• /
• 2000

Methyl tertiary butyl ether (MTBE) is a gasoline additive that boosts the oxygen content in fuel (an oxygenate), resulting in less air-polluting carbon monoxide being released from vehicle exhaust systems. Then, groundwater contamination problems have been developed in areas where the chemical is used. Common sources of water contamination by MTBE include leaking underground gasoline storage tanks and leaks and spills from above ground fuel storage tanks, etc.. Studies on the chemical and these problems are going on abroad vigorously. These studies should be performed in our country as well more actively. This paper reviews on articles on these studies and focuses on the identification of the chemical as a groundwater contamination source.

• Journal of Cadastre & Land InformatiX
• /
• v.46 no.2
• /
• pp.27-42
• /
• 2016

Forest accounts for almost 64 percents of total land cover in South Korea. For inventorying, monitoring, and managing such large area of forest, application of remote sensing and geographic information system (RS/GIS) technology is essential. On the basis of spectral characteristics of satellite imagery, forest cover and tree species can be classified, and forest cover map can be prepared. Using three dimensional data of LiDAR(Light Detection and Ranging), tree location and tree height can be measured, and biomass and carbon stocks can be also estimated. In addition, many indices can be extracted using reflection characteristics of land cover. For example, the level of vegetation vitality and forest degradation can be analyzed with VI (vegetation Index) and TGSI (Top Grain Soil Index), respectively. Also, pine wilt disease and o ak w ilt d isease c an b e e arly detected and controled through understanding of change in vegetation indices. RS and GIS take an important role in assessing carbon storage in climate change related projects such as A/R CDM, REDD+ as well. In the field of climate change adaptation, impact and vulnerability can be spatio-temporally assessed for national and local level with the help of spatio-temporal data of GIS. Forest growth, tree mortality, land slide, forest fire can be spatio-temporally estimated using the models in which spatio-temporal data of GIS are added as influence variables.

• Journal of Soil and Groundwater Environment
• /
• v.17 no.2
• /
• pp.15-21
• /
• 2012

MTBE (Methyl tertiary-butyl ether) has been commonly used as an octane enhancer to replace tetraethyl lead in gasoline, because MTBE increases the efficiency of combustion and decreases the emission of carbon monoxide. However, MTBE has been found in groundwater from the fuel spills and leaks in the UST (Underground Storage Tank). Fenton's oxidation, an advanced oxidation catalyzed with ferrous iron, is successful in removing MTBE in groundwater. However, Fenton's oxidation requires the continuous addition of dissolved $Fe^{2+}$. Zero-valent iron is available as a source of catalytic ferrous iron of MFO (Modified Fenton's Oxidation) and has been studied for use in PRBs (Permeable Reactive Barriers) as a reactive material. Therefore, this study investigated the condition of optimization in MFO-PRBs using waste zero-valent iron (ZVI) with the waste steel scrap to treat MTBE contaminated groundwater. Batch tests were examined to find optimal molar ratio of MTBE : $H_2O_2$ on extent to degradation of MTBE in groundwater at pH 7 with 10% waste ZVI. As the results, the ratio of optimization of MTBE to hydrogen peroxide for MFO was determined to be 1:300[mM]. The column experiment was conducted to know applicability of MFO-PRBs for MTBE remediation in groundwater. As the results of column test, MTBE was removed 87% of the initial concentration during 120days of operational period. Interestingly, MTBE was degraded not only within waste ZVI column but also within sand column. It means the aquifer may affect continuously the MTBE contaminated groundwater after throughout the waste ZVI barrier. The residual products showed acetone, TBF (Tert-butyl formate) and TBA (Tert-butyl acetate) during this test. The results of the present study showed that the recycled materials can be effectively used for not only a source of catalytic ferrous iron but also a reactive material of the MFO-PRBs to remove MTBE in groundwater.

• Journal of Korean Society of Forest Science
• /
• v.107 no.4
• /
• pp.351-360
• /
• 2018

This study was conducted to analyze the responses of chlorophyll contents and growth of Pinus densiflora and Quercus variabilis seedlings on distance from the well and $CO_2$ flux after the artificial $CO_2$ release. From June 1 to 30, 2016, $CO_2$ gas was injected at the rate of $6L\;min^{-1}$ at the study site in Eumseong. Chlorophyll content was analyzed in the middle of July, 2016, and root collar diameter (RCD), height (H), and biomass were measured in May and December, 2016 after planting 2-year-old P. densiflora and 1-year-old Q. variabilis seedlings in May, 2015. The chlorophyll content of P. densiflora seedlings did not show a significant correlation with $CO_2$ flux, whereas the chlorophyll content of Q. variabilis seedlings showed a significant negative correlation with increasing $CO_2$ flux (P<0.05). The RCD and H growth rates of both species showed the significant difference in the distance from the well of the $CO_2$ anthropogenic release treatment. In particular, the RCD and H growth rate of P. densiflora seedlings and the RCD growth rate of Q. variabilis seedlings increased significantly as the seedlings were closer to the well, but the H growth rate of Q. variabilis seedlings decreased significantly. In addition, as the $CO_2$ concentration in the ground increases, ${\Delta}R/S$ ratio increases in both species, suggesting that the high $CO_2$ concentration in the soil promotes carbon distribution relative to the root part. The results of this study can be used as data necessary to monitor the $CO_2$ leakage and physiological and growth responses of both species to leakage of stored $CO_2$ in the future.

• Journal of Soil and Groundwater Environment
• /
• v.11 no.6
• /
• pp.69-75
• /
• 2006

Improper disposal of petroleum and spills from underground storage tanks have created large areas with highly toxic contamination of the soil and groundwater. Methyl tert-butyl ether (MTBE) is widely used as a fuel additive because of its advantageous properties of increasing the octane value and reducing carbon monoxide and hydrocarbon exhausts. However, MTBE is categorized as a possible human carcinogen. This research investigated the Modified Photo-Fenton system which is based on the Modified Fenton reaction and UV light irradiation. The Modified Fenton reaction is effective for MTBE degradation near a neutral pH, using the ferric ion complex composed of a ferric ion and environmentally friendly organic chelating agents. This research was intended to treat high concentrations of MTBE; thus, 1,000 mg/L MTBE was chosen. The objectives of this research are to find the optimal reaction conditions and to elucidate the kinetic and mechanism of MTBE degradation by the Modified Photo-Fenton reaction. Based on the results of experiments, citrate was chosen among eight chelating agents as the candidate for the Modified Photo-Fenton reaction because it has a relatively higher final pH and MTBE removal efficiency than the others, and it has a relatively low toxicity and is rapidly biodegradable. MTBE degradation was found to follow pseudo-first-order kinetics. Under the optimum conditions, [$Fe^{3+}$] : [Citrate] = 1 mM: 4 mM, 3% $H_2O_2$, 17.4 kWh/L UV dose, and initial pH 6.0, the 1000 ppm MTBE was degraded by 86.75% within 6 hours and 99.99% within 16 hours. The final pH value was 6.02. The degradation mechanism of MTBE by the Modified Photo-Fenton Reaction included two diverse pathways and tert-butyl formate (TBF) was identified to be the major degradation intermediate. Attributed to the high solubility, stability, and reactivity of the ferric-citrate complexes in the near neutral condition, this Modified Photo-Fenton reaction is a promising treatment process for high concentrations of MTBE under or near a neutral pH.

• Korean Journal of Remote Sensing
• /
• v.28 no.1
• /
• pp.159-169
• /
• 2012

The purpose of this study was to assess the vulnerability of forest ecosystem to climate change in South Korea using socio-environmental indicators and the results of two vegetation models named as Hydrological and Thermal Analogy Group(HyTAG), and MAPSS-Century 1(MC1). The changing frequency and direction of biome types estimated by HyTAG model was used for quantifying sensitivity and adaptive capacity of forest distribution. Similarly, the variation and changing tendency of net primary production and soil carbon storage estimated by MC1 model was used for quantifying sensitivity and adaptive capacity of forest function. As socio-environmental indicators, many statistical data such as financial autonomy rate and the number of forestry officer was prepared. All indicators were standardized, and then calculated using the vulnerability assessment equation. The period of vulnerability assessment was divided into the past(1971-2000) and the future(2021-2050). To understand what policy has a priority to climate change, distribution maps of each indicators was depicted and the vulnerability results were compared among administrative districts. Evident differences could be found in entire study area. These differences were mostly derived from regionalspecific adaptive capacity. The result and methodology of this study would be helpful for the development of decision-making supporting system and policy making in forest management with respect to climate change.

• Journal of Wetlands Research
• /
• v.22 no.4
• /
• pp.312-320
• /
• 2020

Various LIDs with natural water circulation function are applied to reduce urban environmental problems and environmental impact of development projects. However, excessive Infiltration and evaporation of LID facilities dry the LID internal soil, thus reducing plant and microbial activity and reducing environmental re duction ability. The purpose of this study was to develop a real-time measurement system with complex sensors to derive the management plan of LID facilities. The test of measurable sensors and Internet of Things (IoT) application was conducted in artificial wetlands shaped in acrylic boxes. The applied sensors were intended to be built at a low cost considering the distributed LID and were based on Arduino and Raspberry Pi, which are relatively inexpensive and commercialized. In addition, the goal was to develop complex sensor measurements to analyze the current state o f LID facilities and the effects of maintenance and abnormal weather conditions. Sensors are required to measure wind direction, wind speed, rainfall, carbon dioxide, Micro-dust, temperature and humidity, acidity, and location information in real time. Data collection devices, storage server programs, and operation programs for PC and mobile devices were developed to collect, transmit and check the results of measured data from applied sensors. The measurements obtained through each sensor are passed through the Wifi module to the management server and stored on the database server in real time. Analysis of the four-month measurement result values conducted in this study confirmed the stability and applicability of ICT technology application to LID facilities. Real-time measured values are found to be able to utilize big data to evaluate the functions of LID facilities and derive maintenance measures.