• Title/Summary/Keyword: Soft segment

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The Effect of Ionic Group and MMA Contents on the Physical Properties of PU/PMMA Hybrids (PU/PMMA Hybrids의 물성에 대한 이온성기와 MMA함량의 영향)

  • Jeong, Chang Nam;Cho, Hang Kyu;Noh, Si Tae
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.575-581
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    • 1997
  • UDs were synthesized from two different polyols(PTMG, PBEAG), ionic chain extender(DMPA), EDA with $H_{12}-MDI$. PU/PMMA hybrids were prepared with free radical polymerization of MMA monomer in MMA-swelled PUD. PUD particle size and film properties were investigated ionic content and polyol type. Mechanical and thermal properties of PU/PMMA hybrid film were studied in terms of PU's ionic content and the venation of PU/PMMA compositions. As DMPA content increased from 2wt% to 10wt% in PUD, particle size of PUD decreased. PUD's particle size with ester type polyol was found to be smaller then ether type polyol used. Phase separation between hard segment(HS) and soft segment(SS) with ionic contents in PU was shown by the thermal, mechanical property measurement. Although the composition of MMA was changed from 0 to 40 wt% in PU/PMMA hybrid, the particle size of the hybrid did not increase. Using the ester type polyol, tensile strength of hybrid was found to increase by 2wt% - 6wt% DPMA content, but as higher content the strength of hybrid decreased. Moreover with the ether type polyol, tensile strength of hybrid was observed to increase by 2wt% - 4wt% DMPA content, while decreasing at higher content. PU and PMMA polymer molecule being mixed in molecular level was confirmed from the pattern of $T_g$ in DSC thermogram.

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Preparation and Properties of Polyorganosiloxane Modified Polyurethane Dispersion (Polyorganosiloxane 변성 Polyurethane Dispersion의 제조와 그 특성)

  • Kang, Doo Whan;Yin, Yong Nan
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.46-51
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    • 2010
  • Polyorganosiloxane modified polyurethane (PDMS-PU) polymers were prepared from copolymerization of ${\alpha}$,${\omega}$-hydroxypropyl terminated polyorganosiloxane with isophorone diisocyanate (IPDI), polypropylene glycol (PPG), and 2,2-bis(hydroxymethyl) propionic acid (DMPA). Hydrophobic polyorganosiloxane was introduced in polyurethane main chain as soft segment block unit. The isocyanate groups in PDMS-PU block copolymer was blocked with 2-butanon oxime and obtained PDMS-PU dispersions in water by neutralizing with triethylamine (TEA). The deblocking temperature of PDMS-PU polymer was measured from thermal analysis. The good stability of the PDMS-PU dispersion was obtained by dispersing into water. PDMS-PU prepolymers were prepared with various contents of DMPA under [NCO]/[OH] = 1.12~1.53 equivalent ratio. Increasing DMPA from 7.2, 13.4, and 18.7 mole% in preparation of PDMS-PU polymer, particle sizes were decreased from 156, 100, 65 dnm. Also contact angle and adhesive strength were measured.

Anatomical Review of Fibular Composite Free Flap for Oral and Maxillofacial Reconstruction (구강악안면재건을 위한 비골복합유리피판의 해부학적 고찰)

  • Kim, Soung Min;Cao, Hua Lian;Seo, Mi Hyun;Myoung, Hoon;Lee, Jong Ho
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.35 no.6
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    • pp.437-447
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    • 2013
  • The fibula is one of the most useful sources for harvest of a vascularized bone graft. The fibula is a straight, long, tubed bone, much stronger than any other available bone that can currently be used for a vascularized graft. It has a reliable peroneal vascular pedicle with a large diameter and moderate length. There is a definite nutrient artery that enters the medullary cavity, as well as multiple arcade vessels, which add to the supply of the bone through periosteal circulation. The vascularized fibula graft is used mainly for long segment defects of the long tubed bone of the upper and lower extremities. It can provide a long, straight length up to 25 cm in an adult. The fibula can be easily osteotomized and can be used in reconstruction of the curved mandible. Since the first description as a vascularized free fibula bone graft by Taylor in 1975 and as a mandibular reconstruction by Hidalgo in 1989, the fibula has continued to replace the bone and soft tissue reconstruction options in the field of maxillofacial reconstruction. For the better understanding of a fibular free flap, the constant anatomical findings must be learned and memorized by young doctors during the specialized training course for the Korean National Board of Oral and Maxillofacial Surgery. This article reviews the anatomical basis of a fibular free flap with Korean language.

MAGNETIC HELICITY PUMPING BY TWISTED FLUX TUBE EXPANSION

  • CHAE JONGCHUL;MOON Y.-J.;RUST D. M.;WANG HAIMIN;GOODE PHILIP R.
    • Journal of The Korean Astronomical Society
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    • v.36 no.1
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    • pp.33-41
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    • 2003
  • Recent observations have shown that coronal magnetic fields in the northern (southern) hemisphere tend to have negative (positive) magnetic helicity. There has been controversy as to whether this hemispheric pattern is of surface or sub-surface origin. A number of studies have focused on clarifying the effect of the surface differential rotation on the change of magnetic helicity in the corona. Meanwhile, recent observational studies reported the existence of transient shear flows in active regions that can feed magnetic helicity to the corona at a much higher rate than the differential rotation does. Here we propose that such transient shear flows may be driven by the torque produced by either the axial or radial expansion of the coronal segment of a twisted flux tube that is rooted deeply below the surface. We have derived a simple relation between the coronal expansion parameter and the amount of helicity transferred via shear flows. To demonstrate our proposition, we have inspected Yohkoh soft X-ray images of NOAA 8668 in which strong shear flows were observed. As a result, we found that the expansion of magnetic fields really took place in the corona while transient shear flows were observed in the photosphere, and the amount of magnetic helicity change due to the transient shear flows is quantitatively consistent with the observed expansion of coronal magnetic fields. The transient shear flows hence may be understood as an observable manifestation of the pumping of magnetic helicity out of the interior portions of the field lines driven by the expansion of coronal parts as was originally proposed by Parker (1974).

Synthesis and Properties of Water Dispersion Polyurethane Containing Fluorine (불소기 함유 수분산 폴리우레탄의 합성과 물성)

  • Lee Jung Eun;Kim Hyung Joong
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.172-176
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    • 2005
  • Environmentally friendly water dispersion polyurethanes containing fluorine were prepared with a fluorinated polyol having $62\%$ of fluorine $(Fluorolink^{(R)}\;M_n\;1000)$. In order to control the fluorine contents of the synthesized polyurethanes polytetramethylene glycol (PTMG2000) and $Fluorolink^{(R)}$ were mixed at assigned ratios and reacted with isophorone diisocyanate (IPDI) as a diisocyanate used. Introducing hydrophilic anion to the polymer chain was achieved by applying dimethyl propionic acid (DMPA). The ionic groups were neutralized with triethyl amine (TEA) before dispersion into water. Chain extension was executed by adding ethylene diamine at the final stage. Mechanical properties of the polymers showed that modulus increased with increasing $Fluorolink^{(R)}$ content. Surface energy values obtained from contact angle measurement decreased with increasing $Fluorolink^{(R)}$ content up to $20\%$. We expect that the synthesized polyurethanes present reliable effect from the fluorine atoms incorporated even at a small amount of $Fluorolink^{(R)}$.

Strategy for Paid Digital Contents after the Advent of N-screen Era: Focused on News-contents Business Models of Foreign Newspaper Companies (N-스크린 환경 도래에 따른 디지털 콘텐츠 유료화 전략 : 해외 신문사의 뉴스 콘텐츠 사업 모델을 중심으로)

  • Kim, Daewon;Woo, Hyejin;Kim, Seongcheol
    • The Journal of the Korea Contents Association
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    • v.15 no.9
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    • pp.509-526
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    • 2015
  • The study investigated the N-Screen strategies of paid digital contents of foreign newspapers belonging to advanced companies: USA, United Kingdom, and Japan. This research employed the time to launch paid digital content business, whether or not to segment market, and 4p marketing mix strategies for analyzing the strategies. The results show that the strategies, starting around the year 2000, had experience chasm, and then revived since the year 2010, when the penetration rate of mobile devices proliferated. Most newspapers still supply contents under the assumption that they paly in a mass market. The items of paid digital contents are mainly composed of e-paper and digital contents. Regarding the price strategy, soft paywall and combination paywall are largely used. Distribution strategy is subject to whether or not to discriminate the path of digital contents. As for promotion strategy, bundling strategy with newspaper is mostly utilized. The difference between western countries and Japan was found in term of the free trial service.

EFFECTS OF OSSEOINTEGRATION ACCORDING TO IMPLANT PLACEMENT TIMING IN THE DISTRACTED ALVEOLAR BONE OF DOGS (치조골 신연 후 임프란트 매식 시기에 따른 골유착 효과)

  • Jung, Hyun;Oh, Hee-Kyun;Ryu, Sun-Youl
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.26 no.3
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    • pp.238-244
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    • 2000
  • The present study was aimed to investigate the effect of osseointegration according to implant placement timing in the distracted alveolar bone using intraoral distraction device. Six adult mongrel dogs of either sex, weighing about 15kg, were used. The animals were divided into 4-week and 8-week groups according to the timing of implant installation. The left upper and lower premolars and first molars were extracted and an alveoloplasty was performed to simulate an atrophic ridge. After 12 weeks of healing, a segmental osteotomy was made and an intraoral distraction device which was designed for augmentation of vertical height of the edentulous ridge was applied. Latency period was allowed for 5 days and then distraction was made at a rate of 1.2mm/day for 8 days. Four or eight weeks after distraction, implants were installed. Twelve weeks after implant installation, the animals were sacrificed. Macroscopic, radiographic, and histologic examinations of distracted alveolar ridge were performed. No significant abnormalities such as infection and dehiscence of overlying soft tissue were observed. Radiographically, there was slight bone resorption around the medial and distal edges of the alveolar bone segment, and a new bone deposition was observed in the neighboring alveolar crest area in the both groups. The satisfactory osseointegration was achieved in the distracted gap of the both groups, but fibrous tissue appeared on the buccal side of implant in the distracted gap in 4-week group. These results suggest that proper timing of implant installation is 8 weeks rather than 4 weeks after distraction when dental implant is to be placed onto the distracted bone.

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Comparison of the Effects of Non-elastic Taping on Patellar tendon Pain, Knee Muscle Strength and Gait in Patients with Patellofemoral Joint Pain Syndrome (비탄력 테이핑이 슬개대퇴관절 통증증후군 환자의 슬개건 통증과 슬관절부 근력, 보행에 미치는 영향 비교)

  • Jung, Sang-mo;Jung, Young-jun;Ahn, Seung-won
    • The Journal of Korean Academy of Orthopedic Manual Physical Therapy
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    • v.25 no.2
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    • pp.39-46
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    • 2019
  • Background: Ground repulsion or impact on the ground during daily activities, sports, or occupational activities may cause injury to the knee when walking. Non-elastic taping is effective in treating these problems in previous studies. Non-elastic taping strengthens the structure of the soft tissues of the injured knee joint to maintain constant tension, improves muscle rearrangement and function, and improves proprioception. Based on previous studies, we intended to see the therapeutic changes of non-elastic taping in patients with patellofemoral joint pain syndrome. Methods: The non-elastic taping application method was applied to the patient three times for five hours for one week. Non-elastic taping was applied to the patellar tendon with little space above the skin segment of the patellar femur, with both sides fixed by taping. Muscle strength and gait change were evaluated with non-elastc taping. Results: The knee flexion, extension strength and gait evaluation of the knee joint with inelastic taping showed significant differences after treatment. There was a significant difference in the comparison between the two groups after the treatment method was applied (p<.05). Conclusion: As a result, this study confirms that the non-elastic taping method applied for the treatment of patellar femoral joint pain syndrome is effective in the treatment.

Treatment and Rehabilitation of Repetitively Recurrent Langerhans Cell Histiocytosis: A Case Report

  • Yoo, Hee Young;Park, Kyung Soo;Lee, Baek Soo;Kwon, Yong Dae;Choi, Byung Joon;Ohe, Joo Young;Lee, Jung Woo
    • Journal of Korean Dental Science
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    • v.9 no.1
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    • pp.35-41
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    • 2016
  • Langerhans cell histiocytosis (LCH) is characterized by proliferation of histiocyte-like cells (Langerhans cell histiocytes) with characteristic Birbeck granules, accompanied by other inflammatory cells. Treatments of LCH include surgery, chemotherapy, and radiotherapy. One of the representative forms of chemotherapy is intralesional injection of steroids. Surgical treatment in the form of simple excision, curettage, or even ostectomy can be performed depending on the extent of involvement. Radiotherapy is suggested in case of local recurrence, or a widespread lesion. This article shows the case of repetitively recurrent LCH of a 56-year-old man who had been through surgical excision and had to have marginal mandibulectomy and radiotherapy when the disease recurred. After the first recurrence occurred, lesions involved the extensive part of the mandible causing pathologic fracture, so partial mandibular bone resection was performed from the right molar area to the left molar area followed by the excision of the surrounding infected soft tissues. The resected mandibular bone was reconstructed with a segment of fibula osteomyocutaneous free flap and overdenture prosthesis supported by osseointegrated implants.

VERTICAL DISTRACTION OF ALVEOLAR BONE FOR PLACEMENT OF DENTAL IMPLANT (치과 임플란트 식립을 위한 치조골의 수직적 신장술)

  • Oh, Jung-Hwan;Lazar, Frank;Zoeller, Joachim E.
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.28 no.4
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    • pp.326-329
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    • 2002
  • Adequate alveolar bone height and width are required for the successful placement of dental implants. Conventional therapeutic regimens for alveolar atrophy are bone grafts or augmentation using allografts and membrane (GBR). Conventional graft techniques have some limitations and complications such as infection, soft tissue problem and high resorption rate. Recently, distraction osteogenesis of alveolar bone is considered as a new alternative for ridge augmentation. Distraction osteogenesis was originally defined and popularized by Ilizarov for lengthening of long bone. Some clinicians have tried to apply distraction osteogenesis in treatment of maxillofacial discrepancies. It was also used to augment alveolar bone. Cologne study group successfully applied the technique for augmentation of alveolar bone and designed several miniplate-distractor systems fabricated by Martin Medizintechnik GmbH in Germany. Vertical distraction of alveolar bone was successfully completed in 104 patients with miniplate-distractor systems. The mean distance of distraction was 10.2mm (range: 6-15 mm) and the mean length of segment was 45 mm (range: 6-127 mm). 162 dental implants in 54 patients were placed immediately or 4 weeks later after removal of the distractor. The results of our study show that vertical distraction of alveolar bone is an effective and reliable technique to restore alveolar atrophy and alveolar vertical defect caused by trauma or tumor.