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Preparation and Properties of Polyorganosiloxane Modified Polyurethane Dispersion  

Kang, Doo Whan (Department of Polymer Science & Engineering, College of Engineering, Dankook University)
Yin, Yong Nan (Department of Polymer Science & Engineering, College of Engineering, Dankook University)
Publication Information
Applied Chemistry for Engineering / v.21, no.1, 2010 , pp. 46-51 More about this Journal
Abstract
Polyorganosiloxane modified polyurethane (PDMS-PU) polymers were prepared from copolymerization of ${\alpha}$,${\omega}$-hydroxypropyl terminated polyorganosiloxane with isophorone diisocyanate (IPDI), polypropylene glycol (PPG), and 2,2-bis(hydroxymethyl) propionic acid (DMPA). Hydrophobic polyorganosiloxane was introduced in polyurethane main chain as soft segment block unit. The isocyanate groups in PDMS-PU block copolymer was blocked with 2-butanon oxime and obtained PDMS-PU dispersions in water by neutralizing with triethylamine (TEA). The deblocking temperature of PDMS-PU polymer was measured from thermal analysis. The good stability of the PDMS-PU dispersion was obtained by dispersing into water. PDMS-PU prepolymers were prepared with various contents of DMPA under [NCO]/[OH] = 1.12~1.53 equivalent ratio. Increasing DMPA from 7.2, 13.4, and 18.7 mole% in preparation of PDMS-PU polymer, particle sizes were decreased from 156, 100, 65 dnm. Also contact angle and adhesive strength were measured.
Keywords
${\alpha}$,${\omega}$-hydroxypropyl terminated polyorgarosiloxane; polyorganosiloxane modified polyurethane;
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