• Title/Summary/Keyword: Soft particle

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Effect of Latex Particle Morphology on the Film Formation and Film Properties of Acrylic Coatings (III);Film Properties of Model Composite Latex (라텍스 입자구조가 필름형성 및 필름물성에 미치는 영향 (III);모델 복합라텍스 입자의 필름물성)

  • Ju, In-Ho;Byeon, Ja-Hun;Wu, Jong-Pyo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.3
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    • pp.259-266
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    • 2004
  • Film properties of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. Tensile strength and tensile elongation at break of final films were evaluated. Those properties can be interpreted in terms of PBA/PMMA phase ratio and their morphology. The interfacial adhesion strength was also evaluated using $180^{\circ}$ peel strength measurement and cross hatch cutting test.

Dispersity of Silver Particles in Polyurethane Matrix: Effect of Polyurethane Chemical Structure (폴리우레탄 구조 변화에 따른 은 입자의 분산 특성)

  • Im, Hyun-Gu;Lee, Hyuk-Soo;Kim, Joo-Heon
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.543-549
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    • 2007
  • We synthesized various polyurethanes(PU) haying different hard segments with different molecular weights of the soft segment to explore the effect of structure on the dispersion of silver particle in the phase of synthesized polyurethanes matrix. The thermal stability was increased by increasing the number of aromatic compound, while the degree of dispersion for silver particle was decreased. Silver particles showed better dispersion in the PU matrix having aromatic compounds when the soft segments were held constant. On the contrary, when the hard segment was held constant, silver particles on the PU matrix haying low $M_w$ of soft segment showed better dispersion than high $M_w$ of soft segment because poor chain mobility of low $M_w$ of soft segment restricted re-aggregation of silver particle. A sheet resistance of composite materials showed different aspects. In this case, the inter connection between silver particles was more important than its dispersion. In this study, the NDI-PEG 900/silver particle composite film showed the best thermal stability and electro conductivity.

Effect of Latex Particle Morphology on the Film Properties of Acrylic Coatings (II);Film Forming Behavior of Model Composite Latex (라텍스 입자구조가 필름형성 및 필름물성에 미치는 영향 (II);모델 복합 라텍스 입자의 필름형성 거동)

  • Ju, In-Ho;Wu, Jong-Pyo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.2
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    • pp.132-139
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    • 2004
  • Film forming behavior of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. The film forming behavior was evaluated using pseudo on-line measurements of the cumulative weight loss, the UV transmittance, and the tensile fracture energy. Each stages of film formation I, II were not sensitive to the morphology of model latexes, but stage-ill was largely dependent on the morphology of model latexes. The chain mobility of polymer which composed the shell component was found to dominantly determine the behavior of film forming stage-III.

Characteristics of Rigid-Soft Particle Mixtures with Size Ratio (입자크기비에 따른 강-연성 혼합재의 공학적 특성)

  • Lee, Chang-Ho;Yoon, Hyung-Koo;Kim, Rae-Hyun;Lee, Woo-Jin;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.24 no.8
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    • pp.125-135
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    • 2008
  • Rigid-soft particle mixtures, which consist of sand and rubber, are investigated for the understanding of the stress-deformation and elastic moduli. Specimens are prepared with various size ratio sr between sand and rubber particles, and different volumetric sand fraction sf. Small strain shear waves are measured under $K_o$-loading condition incorporated with the stress-deformation test by using oedometer cell with bender elements. The stress-deformation and small strain shear wave characteristics of rigid-soft particle mixtures show the transition from a rigid particle behavior regime to a soft particle behavior regime under fixed size ratio. A sudden rise of $\Lambda$ factor and the maximum value of the $\zeta$ exponent in $G_{max}=\;{\Lambda}({\sigma}'_{o}/kPa)^{\zeta}$ are observed at $sf\;{\approx}\;0.4{\sim}0.6$ regardless of the size ratio sf. Transition mixture shows high sensitivity to confining stress. The volume fraction for the minimum porosity may depend on the applied stress level in the rigid-soft particle mixtures because the soft rubber particles easily distort under load. In this experimental study, the size ratio and volumetric sand fraction are the important factors which determine the behavior of rigid and soft particle mixtures.

Effect of Latex Particle Morphology on the Film Formation and Film Properties of Acrylic Coatings ( I );Preparation and Characterization of Model Composite Latex (라텍스 입자구조가 필름형성 및 필름물성에 미치는 영향( I );모델 복합 라텍스 입자의 제조 및 특성)

  • Ju, In-Ho;Ahn, Jae-Won;Byun, Ja-Hoon;Wu, Jong-Pyo
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.1
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    • pp.69-75
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    • 2004
  • In this study, various model composite latexes were synthesized using n-butyl acrylate and methyl methacrylate as comonomers by seeded multi-staged emulsion polymerization. Monodispersed model composite latex particles with size of 190 nm and polydispersity index of 1.05, which have various morphology including random copolymer particle, soft-core/hard-shell particle, hard-core/soft shell particle, and gradient-type copolymer particle, homopolymers particles were prepared. The designed morphology of model composite particles were confirmed.

Effect of Inclusion of Hard Versus Soft Wheat Bran with Different Particle Size on Diet Digestibility, Growth Performance and Carcass Traits of Fattening Rabbits

  • Laudadio, V.;Dario, M.;Addonizio, F.;Tufarelli, Vincenzo
    • Asian-Australasian Journal of Animal Sciences
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    • v.22 no.10
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    • pp.1377-1385
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    • 2009
  • Effect of inclusion of hard vs. soft wheat bran with different particle size on diet digestibility, growth performance and some slaughter traits was evaluated in fattening rabbits. Four isonitrogenous and isocaloric diets were used according to the origin of wheat bran (hard (HWB) - Triticum durum - and soft (SWB) - Triticum aestivum) combined with wheat bran particle size sieved by 2 mm (fine: 2) or by 8 mm (coarse: 8) in a bifactorial (2${\times}$2) study. A growth trial was conducted to measure the effect of treatments on performance in one hundred and twenty New Zealand White${\times}$Californian rabbits fed experimental diets from 50 to 87 days of age. Faecal apparent digestibility was determined within the last week in twenty animals per diet. Digestibility of nutrients was higher (p<0.05) in the diet containing HWB2, except for crude protein, ether extract and ash, than fine and coarse soft wheat bran diets. Final live weight, feed intake and feed consumption of rabbits on the diet with fine hard wheat bran were higher and resulted in greater daily weight gains (p<0.01) than for animals on the other diets. The slaughter yield and percentage value of organs were not significantly (p>0.05) affected by the diets fed; however, the diet containing fine hard wheat bran led to lower (p<0.05) percentages of skin, abdominal fat and carcass drip loss than the other dietary treatments. It is concluded that fine hard wheat bran can be better included in the diet than soft wheat bran to maximize growth performance without affecting carcass traits of fattening rabbits.

Microstructure and Soft Magnetic Properties of Fe-6.5 wt.%Si Sheets Fabricated by Powder Hot Rolling

  • Kim, Myung Shin;Kwon, Do Hun;Hong, Won Sik;Kim, Hwi Jun
    • Journal of Powder Materials
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    • v.24 no.2
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    • pp.122-127
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    • 2017
  • Fe-6.5 wt.% Si alloys are widely known to have excellent soft magnetic properties such as high magnetic flux density, low coercivity, and low core loss at high frequency. In this work, disc-shaped preforms are prepared by spark plasma sintering at 1223 K after inert gas atomization of Fe-6.5 wt.% Si powders. Fe-6.5 wt.% Si sheets are rolled by a powder hot-rolling process without cracking, and their microstructure and soft magnetic properties are investigated. The microstructure and magnetic properties (saturation magnetization and core loss) of the hot-rolled Fe-6.5 wt.% Si sheets are examined by scanning electron microscopy, electron backscatter diffraction, vibration sample magnetometry, and AC B-H analysis. The Fe-6.5 wt.% Si sheet rolled at a total reduction ratio of 80% exhibits good soft magnetic properties such as a saturation magnetization of 1.74 T and core loss ($W_{5/1000}$) of 30.7 W/kg. This result is caused by an increase in the electrical resistivity resulting from an increased particle boundary density and the oxide layers between the primary particle boundaries.

The Development of Slag Based Materials for the Reformation of Soft Ground

  • Byeon, Tae-Bong;Kim, Hyung-Suek;Han, Ki-Hyun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.537-541
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    • 2001
  • For the development of reformation material of soft ground using the LD slag, the relation to the particle condition of LD slag and the pH behavior of slag dissolution water, extraction properties of slag, and origination of white water were investigated. When the LD slag is mixed with sea water, the pH of solution ranged between 9.47 and 10.0. On the other hand, when mixed with distilled water, the pH was about 10.4 to 12.1. For the as-received slag and the aged slag in sea water, a pH of 11.5 to 12.0 was observed when the particle size was less than 0.5mm. For the reoxidized slag in seawater, the pH of the solution was lower than 9.5 when the particle size was bigger than 0.075mm. For the aged slag and reoxidized slag, the pH of the solution remained constant when the addition ratio of sea water to the slag was higher than 500 times. The main elements dissolved from the slag were Ca and Mg ions. When the pH went over 9.0, the white water started to font which was caused by the CaCO$_3$and Mg(OH)$_2$.

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Analysis of Accelerated Soft Error Rate for Characteristic Parameters on Static RAM (정적 RAM 특성 요소에 의한 소프트 에러율의 해석)

  • Gong, Myeong-Kook;Wang, Jin-Suk;Kim, Do-Woo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.4
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    • pp.199-203
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    • 2006
  • This paper presents an ASER (Accelerated Soft Error Rate) integral model. The model is based on the facts that the generated EHP/s(electron hole pairs) are diminished after some residual range of the incident alpha particle, where residual range is a function of the incident angle and the capping layer thickness over the semiconductor junction. The ASER is influenced by the flux of the alpha particles, the junction area ratio, the alpha particle incident angle when the critical charge is same as the collected charge, and the sizes of the alpha source and the chip. The model was examined with 8M static RAM samples. The measured ASER data showed good agreement with the calculated values using the model. The ASER decreased exponentially with respect to the operational voltage. As the capping layer thickness increases up to $16{\mu}m$, the ASER increases, and after that thickness, the ASER decreases. The ASER increased as the depth of BNW increased from $0{\mu}m\;to\;4{\mu}m$. and then saturated. The ASER decreased as the node capacitance increased from 2fF to 5fF.