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http://dx.doi.org/10.12925/jkocs.2004.21.1.9

Effect of Latex Particle Morphology on the Film Formation and Film Properties of Acrylic Coatings ( I );Preparation and Characterization of Model Composite Latex  

Ju, In-Ho (Department of Chemical Engineering, Myongji University)
Ahn, Jae-Won (Department of Chemical Engineering, Myongji University)
Byun, Ja-Hoon (Department of Chemical Engineering, Myongji University)
Wu, Jong-Pyo (Department of Chemical Engineering, Myongji University)
Publication Information
Journal of the Korean Applied Science and Technology / v.21, no.1, 2004 , pp. 69-75 More about this Journal
Abstract
In this study, various model composite latexes were synthesized using n-butyl acrylate and methyl methacrylate as comonomers by seeded multi-staged emulsion polymerization. Monodispersed model composite latex particles with size of 190 nm and polydispersity index of 1.05, which have various morphology including random copolymer particle, soft-core/hard-shell particle, hard-core/soft shell particle, and gradient-type copolymer particle, homopolymers particles were prepared. The designed morphology of model composite particles were confirmed.
Keywords
seeded emulsion polymerization; composite latexes; acrylates;
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1 이해준, 김중현, 화학공업과 기술, 14, 529 (1996)
2 S. T. Eckersley and A.Rudin, J. Coat. Technol., 62, 89 (1990)
3 D. P. Sheetz, J. Appl. Polym. Sci., 9. 3759 (1965)   DOI
4 G. A. Vandezande and A. Rudin, J. Coat. Technol., 66, 99 (1994)
5 D. R. Bassett and A, Hanselec, ACS Symp. Series No. 166, ACS (1981)
6 T. Min, A. KIein, M.S, El-Aasser, and J.W. Vanderhoff, J. Polym. Sci., PoIym. Chem. Ed., 21, 2845 (1983)   DOI
7 H. Jotischky, JOCCA, 7, 269 (1992)
8 R. E. Dillon, L. A. Matheson, and E. B. Bradford, J. Colloid Sci., 6, 108 (1951)   DOI   ScienceOn
9 J. Rayssaw, M. Podkoscielny, and J. Widomski, J. Appl. Polym. Sci., 49, 835 (1993)   DOI   ScienceOn
10 H. C. Miller, Modern Paint & Coat., 83, 40 (1993)
11 D. C. Sunberg and Y. G. Durant, Macromol. Symp., 92, 43 (1995)   DOI
12 W. V. Smith and R. H. Ewart, J. Chem. Phys., 16, 592 (1948)   DOI
13 G. L. Brown, J. Polym. Sci., 22, 423 (1956)   DOI
14 J. M. Asua (ed.), 'Polymeric Dispersions : Principles and Applications', 397, Kluwer Academic Pub.(1997)
15 I. Cho and K. Lee, J. Polym. Sci., 30, 1903 (1985)
16 M. Qkubo, Y. Katsuta, and T. Matsumoto, J. Polym. Sci., Polym. Chem. Ed., 18, 481 (1980)   DOI
17 M. Hidalgo, J. Y. Guillot, J. Guyot, C. Pichot, L. Rios, and R. Vassoille, Colloid Polym. Sci., 270, 1208 (1992)   DOI
18 A. Priola and F. Renzi, J. Mater. Sci., 20, 2889 (1985)   DOI   ScienceOn