• Title/Summary/Keyword: Sodium metal

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Dyeing Properties of Nylon 6 and Polyester Fabrics with Vat Dyes - Effect of Composition of Reducing Agent and Alkali on Color Change - (배트염료에 의한 나일론과 폴리에스테르 섬유의 염색성 - 색상 변화에 미치는 하이드로슬파이트와 NaOH의 영향 -)

  • ;;;Tomiji Wakida
    • Textile Coloration and Finishing
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    • v.14 no.5
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    • pp.284-293
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    • 2002
  • Nylon 6 and polyester taffeta fabrics are dyed in aqueous medium with vat dyes such as Indanthren Red FBB, Mikethren Blue ACE and Mikethren Blue HR varying the compositions of sodium hydrosulfite and NaOH. Also nylon UMF nonwoven and polyester UMF knitted fabrics are dyed with metal complex and disperse dyes as a reference, and the wash and rubbing fastnesses for these dyes are investigated. In vat dyeing of polyester and nylon taffeta, an optimum composition of sodium hydrosulfite/NaOH is existed at a range of 1∼2wt%/0.2wt%. A good build-up property for Mikethren Blue ACE on nylon 6 UMF nonwoven fabric is shown at high temperature. Vat dyeing of polyester with Mikethren Blue Ace shows a good color shade in a higher temperature, while dyeing with Mitsui Blue HR shows low temperatures. Vat dyes In dyeing of both nylon 6 UMF nonwoven and polyester UMF knitted fabrics have a better wash fastnesses compared with metal complex or disperse dyes.

Application of two different similarity laws for the RVACS design

  • Min Ho Lee;Ji Hwan Hwang;Ki Hyun Choi;Dong Wook Jerng;In Cheol Bang
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4759-4775
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    • 2022
  • The RVACS is a versatile and robust safety system driven by two natural circulations: in-vessel coolant and ex-vessel air. To observe interaction between the two natural circulations, SINCRO-IT facility was designed with two different similarity laws simultaneously. Bo' based similarity law was employed for the in-vessel, while Ishii's similarity law for the ex-vessel excluding the radiation. Compared to the prototype, the sodium and air system, SINCRO-IT was designed with Wood's metal and air, having 1:4 of the length reduction, and 1.68:1 of the time scale ratio. For the steady state, RV temperature limit was violated at 0.8% of the decay heat, while the sodium boiling was predicted at 1.3%. It showed good accordance with the system code, TRACE. For an arbitrary re-criticality scenario with RVACS solitary operation, sodium boiling was predicted at 25,100 s after power increase from 1.0 to 2.0%, while the system code showed 30,300. Maximum temperature discrepancy between the experiments and system code was 4.2%. The design and methodology were validated by the system code TRACE in terms of the convection, and simultaneously, the system code was validated against the simulating experiments SINCRO-IT. The validated RVACS model could be imported to further accident analysis.

Long-Term Life Test of A Stainless Steel-Sodium Heat Pipe (스테인리스 스틸-나트륨 히트파이프의 장기 수명 시험)

  • Park, S.Y.;Jung, E.G.;Boo, J.H.;Kang, H.K.;Yoo, J.H.;Park, S.H.
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1058-1062
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    • 2004
  • High-temperature cylindrical stainless steel/sodium heat pipe was manufactured and tested under long-term operation. The container material was stainless steel 316L and the working fluid was sodium. The heat pipe was 25.4 mm in diameter and 1000 mm in length with a two-layer screen mesh wick. The evaporator part was 600 mm and the condenser part was 300 mm in length. Total measurement points on heat pipe were 15 points and 12 points were located in condenser part. The heat pipe was heated for 142 days(3400 hours) at $800^{\circ}C$. In the test period, the maximum temperature difference was increased from $18^{\circ}C$ o $28^{\circ}C$ and the maximum thermal resistance was as low as $0.015^{\circ}CW$.

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Thermal Decomposition Characteristics on Sodium Azide and Metallic Oxide Mixtures (나트륨 아지드와 금속산화물과의 혼합물에 대한 열분해 특성)

  • 이내우;최재욱;박광수;설수덕;왕석주
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.106-113
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    • 1997
  • The thermal characteristics of two binary mixtures by sodium azide/manganese dioxide and ferric oxide, two ternary mixtures by sodium azide/silicon dioxide/manganese dioxide and ferric oxide were studied to obtain the basic data of gas-generating agents for air bags. The thermal reaction for all mixtures started at about $420^{\circ}C$, but the temperature at which the reaction rate reached a maximum was different with the states of samples. According to reaction results, nitrogen, nitrogen oxide and nitrogen dioxide were detected by GC-MS and so many kinds of new chemicals from sodium azide and metal oxide mixtures by XRD. NMS is considered as most stable and reasonable mixture for this types of gas-generating agents.

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Analysis of Sodium Spray Fire Using Gaussian Droplet Size Distribution (Gaussian 액적 크기 분포 함수를 이용한 분무형 화재 현상 해석)

  • Kim, B.H.;Hahn, D.H.;Suh, S.H.
    • Journal of Hydrogen and New Energy
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    • v.15 no.1
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    • pp.72-81
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    • 2004
  • Study on the analysis of sodium spray fire using Gaussian drop size distribution, which redistributes a droplet spectrum with given mean diameter if its size classes with critical diameter(D>8mm) occur, was carried out. In this case, the oversized droplets were reduced to a stable diameter. Results calculated by the code using Gaussian drop size distribution were in better agreement with AI experimental results than those of NACOM and SPRAY code. The effect of variance on pressure in the test cell appeared greatly by introducing Gaussian function, which could represent various sodium droplet size distribution. The increase of the variance with mean droplet size resulted had an important effect upon the pressure in the test cell.

Synthesis of Nickel Nanoparticles using Electron Beam Irradiation

  • Lee, Seung Jun;Kim, Hyun Bin;Oh, Seung Hwan;Kang, Phil Hyun
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.241-245
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    • 2015
  • A study on the preparation of nickel oxide nanoparticles using electron beam irradiation is described. Nickel nanoparticles were synthesized with nickel chloride hexahydrate as a metal precursor and different sodium hydroxide concentrations using electron beam irradiation. The effects of sodium hydroxide concentration and electron beam absorbed doses were investigated. The samples were synthesized at different sodium hydroxide concentrations and with absorbed doses of 100 to 500 kGy at room temperature. Synthesized nanoparticles were characterized by X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM) and a vibrating sample magnetometer (VSM). The nanoparticle morphologies seemed to be non-spherical and aggregated. The 1:1 molar ratio of nickel chloride hexahydrate and sodium hydroxide showed a higher purity and saturation magnetization value of 13.0 emu/g. The electron beam absorbed dose was increased with increasing nickel nanoparticle nucleation.

Conceptual Design for Accelerator-Driven Sodium-Cooled Sub-critical Transmutation Reactors using Scale Laws and Integrated Code System

  • Lee, Kwang-Gu;Chang, Soon-Heung
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05a
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    • pp.660-665
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    • 1998
  • The feasibility study on conceptual design methodology for accelerator-driven sodium-cooled sub-critical transmutation reactors has been conducted to optimize the design parameters from the scale laws and validates reactor performance with the integrated code system. A 1000 MWth sodium-cooled sub-critical transmutation reactor has been scale and verified through the methodology in this paper, which is referred to advanced Liquid Metal Reactor (ALMR). a Pb-Bi target material and a partitioned fuel are the liquid phases, and they are cooled by the circulation of secondary Pb-Bi coolant and by primary sodium coolant, respectively. Overall key design parameters are generated from the scale laws and they are improved and validated by the intergrated code system. Intergrated Code System (ICS) consist of LAHET, HMCNP, ORIGEN2, and COMMIX codes and some files. Through ICS the target region, the core region, and thermal-hydraulic related are analyzed once-through. Results of conceptual design are attached in this paper.

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Analysis of spray sodium fire phenomena in the containment vessel (격납용기내에서 분무형 나트륨화재 현상 해석)

  • 조병렬;권선길;황성태
    • Journal of the Korean Society of Safety
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    • v.11 no.2
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    • pp.79-88
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    • 1996
  • A hypothetical accident in the containment vessel of liquid metal reactor could cause a pressure, temperature rise, and a strong aerosol release. The computer codes relating to the modelization of these accident make it necessary to use various input parameter, among which is the dynamic shape factor of aerosols produced. Combustion experiments of sodium spray fire carried out in a closed vessel, which was vertical cylinder made of 1.2m in diameter and 1.8m hight with a volume of 1.7$m^3$. The results of theoretical analysis presented here was compared to data obtained from experiments. The experimental results were summarized as follows. 1) The aerodynamic diameter and geometric diameter of aerosols are decreasing with increasing of injection pressure and injection temperature of sodium 2) The dynamic shape factor of aerosol is proportional to the aerodynamic diameter for a given particle. 3) The correspondence between the aerodynamic diameter and geometric diameter can be as $D_{ae}=0.70 D_{ge}$. 4) Peak pressure rose with increase in pressure and temperature of injection sodium, being more sensitive to the injection pressure than the injection temperature.

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Pilymeric Membrane Sodium Ion-Selective Electrodes Based on Calix[4}arene Triesters

  • Kim, Yun Deok;Jeong, Hae Sang;Gang, Seong Ok;Nam, Gye Cheon;Jeon, Seung Won
    • Bulletin of the Korean Chemical Society
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    • v.22 no.4
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    • pp.405-408
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    • 2001
  • New lipophilic triesters of calix[4]arene and calix[4]quinone are investigated as sodium ion-selective ionophores in poly(vinyl chloride) membrane electrodes. For an ion selective electrode based on calix[4]arene triester I, the linear response is 1 ${\times}$10-3.5 to 1 ${\times}$ 10-1 M of Na+ concentrations. The selectivity coefficients for sodium ion over alkali metal and ammonium ions are determined. The detection limit (logaNa+ = -4.50) and the selectivity coefficient (logKNa+,K+pot = -1.86) are obtained for polymeric membrane electrode containing calix[4]arene triester I.

CHARACTERIZATION OF $YBa_2Cu_3O_{7-x}$ MADE BY A SOL-GEL PROCESS USING NITRATE SALTS AND SODIUM HYDROXIDE (질산염(窒酸鹽)과 수산화(水酸化)나트륨을 써서 졸-겔 법(法)으로 만든 $YBa_2Cu_3O_{7-x}$의 특성분석(特性分析))

  • Kim, Bong-Heup;Kang, Hyung-Boo;Kim, Hyun-Teak
    • Proceedings of the KIEE Conference
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    • 1990.11a
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    • pp.143-149
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    • 1990
  • A sol-gel processing of $YBa_2Cu_3O_{7-x}$ superconductor using metal nitrate salts and sodium hydroxide as the starting materials has been investigated because of the need to produce pure, hompgeneous superconducting materials. Since the precipitation of barium hydroxides can be obtained only at high basicities, the process has to be carried out Ca. pH 13 to get the simultaneous coprecipitation with the other metal hydroxides. The involved reaction mechanisms were investigated and intermediate and final products were characterized by means of thermogravimetric analysis(TGA), infra-red(IR) spectroscopy, X-ray diffraction(XRD) analysis, scanning electron microscopy(SEM), thermal mechanical analysis(TMA) and electrical measurement.

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