• Title/Summary/Keyword: Sodium dodecyl sulfate

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The Study on Sound Absorption According to Content of Foaming Agent In Lightweight Concrete (경량화 콘크리트에서 기포제의 함량에 따른 흡음특성에 관한 연구)

  • Hong, D.K.;Ahn, C.W.;Kang, J.G.;Woo, B.C.;Choi, J.G.;Kang, H.C.
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.955-958
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    • 2006
  • The purpose of this study is to find ways of recycling a great amount of gypsum as by-product from the manufacture of phosphate fertilizer. For the purpose, this researcher investigated physical properties of light weight Porous material using waste gypsum and a foaming agent, Sodium n-dodecyl Sulfate to utilize it as a interior material of construction. To determine such properties, the study examined pore size distribution and pore rate in accordance with contents of Sodium n-dodecyl Sulfate added. Then expanded vermiculite as light-weight aggregate was also added, when pore size distribution, pore rate and sound absorption rate were surveyed and measured.

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Voltammetric Study of Surfactant-Modified Carbon Electrode: $Ru(ph){_3}^{2+}$ in Sodium Dodecyl Sulfate Solution

  • Ko, Young Chun;Chung, Keun Ho
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.643-648
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    • 1995
  • Cyclic voltammetric method is used to survey microscopic environments which take place at the surfactant-modified carbon electrode when the hydrophobic and hydrophilic environments of $Ru(ph){_3}^{2+}$(tris 1,10-phenanthroline ruthenium(II) chloride) is created by the addition of anionic surfactant, sodium dodecyl sulfate(SDS). Critical micelle concentration(CMC) of SDS in $Ru(ph){_3}^{2+}$ measured by cyclic voltammetry(CV) is in aggrement with that by surface tensiometry. Influence of the concentration of supporting electrolyte at surfactant-modified carbon electrode is investigated.

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The transformation of the complex of high charge density cationic polymer with sodium dodecyl sulfate into vesicles by nonionic surfactant (고전하밀도 양이온성폴리머와 Sodium dodecyl sulfate가 만드는 콤플렉스에 대한 비이온계면활성제의 영향)

  • Lee, Jung-No;Kang, Kye-Hong
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.205-210
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    • 2008
  • The transformation of the liquid crystal complex made by binding of anionic surfactant, sodium dodecyl sulfate (SDS), into high charge density cationic polymer, the homopolymer of diallyldimethylammonium chloride (PDADMAC) was induced by adding of nonionic surfactants and investigated by means of microscopy and FE.SEM. Among nonionic surfactants in this experiments polyethylene glycol (3 mol) ether of lauryl alcohol (laureth-3) made variation in the complex. The laureth-3 transformed the complex into spherulite vesicle with the size of ca.$100{\mu}m$. This change increased the viscosity and the turbidity of the solution phase separated originally. Microscope showed that they are spherulite particles and polarized microscope suggested they are multi.lamellar liquid crystals. FE-SEM also proved that explicitly.

A NMR Study on the Micellization of Sodium Dodecyl Sulfate in ω-Phenylalkylammonium Salt Solution (1H NMR을 이용한 ω-Phenylalkylammonium Salt의 수용액에서 Sodium Dodecyl Sulfate의 미셀에 관한 연구)

  • Oh, Jung Hee
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.628-634
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    • 1999
  • The orientational binding of ${\omega}$-phenylakylammonium ions to the sodium dodecyl (SDS) micellar interface has been studied from $^{1}H\;NMR$ chemical shift data. The NMR resonaces of the methylene protons of SDS and aromatic protons embedded into the micellar interior have shown the upfield shift. The aromatic induced chemical shifts of the alkyl chain methylene protons of SDS demonstrate the deep penetration into the palisade layer by these organic salts. Alkylammonium groups have been considered to be oriented toward outside of the micellar interface. Aromatic rings have been thought to be oriented toward the micellar core. The depth of penetration by organic salts has been observed to increase with the length of alkyl chain.

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Enhanced Electrogenerated Chemiluminescence of Tris (2,2'-bipyridyl) Ruthenium (II)-$S_2O_8^{2-}$ System by Sodium Dodecyl Sulfate

  • Kang, Sung-Chul;Oh, Soo-Il;Kim, Kang-Jin
    • Bulletin of the Korean Chemical Society
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    • v.11 no.6
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    • pp.505-508
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    • 1990
  • The electrochemical reduction and electrogenerated chemiluminescence (ECL) of $Ru(bpy)_3^{2+}-S_2O_8^{2-}\;in\;CH_3CN-H_2O$ solution were studied in the presence of sodium dodecyl sulfate (SDS) as an anionic surfactant. SDS enhanced the ECL and the fluorescence intensities and lengthened the duration of ECL due to the solubilization of reactants and possibly to the stabilization of ECL intermediates in the SDS micellar environment.

Solution properties of sodium n-dodecyl sulfate in the presence of meso-tetrakis (N-methylpyridinium-4-yl) porphyrin (Meso-tetrakis (N-methylpyridinium-4-yl) porphyrin 존재 하에서 sodium n-dodecyl sulfate 용액 성질)

  • Hassanpour, Azin;Azani, Mohammad-Reza;Bordbar, Abdol-Khalegh
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.335-340
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    • 2011
  • The solution properties of sodium n-dodecyl sulfate, as an anionic surfactant in the presence of a cationic watersoluble 5, 10, 15, 20-tetrakis (N-methylpyridinium-4-yl) porphyrin (TMPyP) has been comprehensively studied by means of conductometry, UV-vis and resonance light scattering (RLS) spectroscopies. The results represent the decreasing of critical micelle concentration of SDS solution due to increasing of TMPyP concentration. The stabilization of SDS micelle is due to neutralization of negative charge at the micelle surface. The presence of three different species of TMPyP in SDS solution has been unequivocally demonstrated: free porphyrin monomers, porphyrin monomers or aggregates bound to the micelles, and nonmicellar porphyrin/surfactant aggregates. Our results show SDS induced an aggregation in TMPyP. In fact two kinds of J-aggregations were observed: one of them for porphyrin monomers or aggregates bound to the micelles and the other for nonmicellar porphyrin/surfactant aggregates. However, the results represent the electrostatic interaction of TMPyP with SDS anion below the cmc.

The Effect of Salt and Organic Solvents on the Interaction of Thionin-Sodium Dodecyl Sulfate System (Thionin-Sodium Dodecyl Sulfate계의 상호작용에 있어서 염 및 유기용매의 첨가효과에 관한 연구)

  • Kim, Sung-Hyun;Song, Ki-Dong
    • Applied Chemistry for Engineering
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    • v.5 no.5
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    • pp.779-785
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    • 1994
  • The interaction between the cationic dye, thionin(Th) and the anionic surfactant, sodium dodecyl sulfate (SDS) has been investigated by absorption spectra. As the temperature of surfactant solution was increased in premicellar range(S/D=10, 80, and 160) which was much lower than the critical micelle concentration(CMC), the increment or decrement of the molar extinction coeffecient ratio appeared. It was found that the most stable temperature range of the oligomer aggregate in Th-SDS system at S/D=160 was below $60^{\circ}C$. With increasing the concentration of inorganic salt and organic solvents in Th-SDS system, ${\alpha}$-band was increased, but ${\gamma}$=band or J-band was decreased. The orders of ${\alpha}$-band increasing power were $Cl^-$>$ClO{_4}{^-}$>$SO{_4}{^{2-}}$>$NO{_3}{^-}$ and 2-propanol>ethanol>methanol>ethylene glycol.

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Effect of Molecular Weight of Chitosan on Flocculation of Suspended Solids in Rhodamine 6G-Sodium Dodecyl Sulfate System (키토산 분자량에 따른 Rhodamine 6G-Sodium Dodecyl Sulfate계의 응집효과에 관한 연구)

  • Kim, Sung Hyun;Nah, Jae Woon;Oh, Jeong Sun;Song, Ki Dong
    • Journal of the Korean Chemical Society
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    • v.42 no.6
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    • pp.672-678
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    • 1998
  • Chitin was extracted from crab shell of Portuns triberculatus and deacethylated to yield chitosan with various molecular weights. The absorption and the fluorescence spectra of Rhodamine 6G(Rh 6G)-sodium dodecyl sulfate(SDS) and Rh 6G-chitosan systems were obtained. From the spectra, we observed that the absorption and the fluorescence intensity of Rh 6G-SDS system decreased when S/D(the concentration of SDS to that of Rh 6G ratio) was below or at 32, while they increased when S/D was above 32. From the suspended solid(SS) removal rate and the transmittance of Rh 6G-SDS-chitosan system, we found that when S/D ratio was 32 its flocculating behaviour was much stronger than Rh 6G-SDS system. As the concentration and the molecular weight of chitosan increased, we also found that S/D range was extended from 32 to 100. With increasing the molecular weight of chitosan, the SS removal rate increased around pH 2~9 but decreased remarkably at pH>12.

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Immobilization of the Thenoyltrifluoroacetone on Sodium Dodecyl Sulfate Modified Magnetite Nanoparticles for Magnetic Solid Phase Extraction of Pb (II) from Water Samples

  • Sadeghi, Meysam;Yekta, Sina;Babanezhad, Esmaeil
    • Korean Chemical Engineering Research
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    • v.54 no.5
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    • pp.636-647
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    • 2016
  • Magnetite nanoparticles ($Fe_3O_4$ NPs) were synthesized by co-precipitating method under optimized condition. The $Fe_3O_4$ NPs coated with sodium dodecyl sulfate-thenoyltrifluoroacetone ($Fe_3O_4$ NPs-SDS-TTFA) were then exerted as the magnetic solid phase extraction (MSPE) adsorbent for the extraction process prior to introducing to a flame atomic adsorption spectrometry (FAAS). The synthesized $Fe_3O_4$ NPs-SDS-TTFA were applied for the extraction of Pb(II) ions from different water samples. The characterization studies of nanoparticles were performed via scanning electron microscopy-energy dispersive micro-analysis (SEM-EDAX), X-ray diffraction (XRD) and vibrating sample magnetometer (VSM) techniques. The substantial parameters affecting the extraction efficiency were surveyed and optimized. A dynamic linear range (DLR) of $10-400{\mu}g\;L^{-1}$ was obtained and the limit of detection (LOD, n=7) and relative standard deviation (RSD%, n= 6, $C=20{\mu}g\;L^{-1}$) were found to be $2.3{\mu}g\;L^{-1}$ and 1.9%, respectively. According to the results, the proposed method successfully applied for the extraction of Pb(II) ions from different environmental water samples and satisfactory results achieved.