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http://dx.doi.org/10.5012/jkcs.2011.55.3.335

Solution properties of sodium n-dodecyl sulfate in the presence of meso-tetrakis (N-methylpyridinium-4-yl) porphyrin  

Hassanpour, Azin (Departamento de Quimica Inorganica, Facultad de Ciencias, Universidad Autonoma de Madrid)
Azani, Mohammad-Reza (Departamento de Quimica Inorganica, Facultad de Ciencias, Universidad Autonoma de Madrid)
Bordbar, Abdol-Khalegh (Laboratory of Biophysical Chemistry, Department of Chemistry, University of Isfahan)
Publication Information
Journal of the Korean Chemical Society / v.55, no.3, 2011 , pp. 335-340 More about this Journal
Abstract
The solution properties of sodium n-dodecyl sulfate, as an anionic surfactant in the presence of a cationic watersoluble 5, 10, 15, 20-tetrakis (N-methylpyridinium-4-yl) porphyrin (TMPyP) has been comprehensively studied by means of conductometry, UV-vis and resonance light scattering (RLS) spectroscopies. The results represent the decreasing of critical micelle concentration of SDS solution due to increasing of TMPyP concentration. The stabilization of SDS micelle is due to neutralization of negative charge at the micelle surface. The presence of three different species of TMPyP in SDS solution has been unequivocally demonstrated: free porphyrin monomers, porphyrin monomers or aggregates bound to the micelles, and nonmicellar porphyrin/surfactant aggregates. Our results show SDS induced an aggregation in TMPyP. In fact two kinds of J-aggregations were observed: one of them for porphyrin monomers or aggregates bound to the micelles and the other for nonmicellar porphyrin/surfactant aggregates. However, the results represent the electrostatic interaction of TMPyP with SDS anion below the cmc.
Keywords
meso-tetrakis (N-methylpyridinium-4-yl) porphyrin; surfactant; aggregation; resonance light scattering;
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1 Pasternack, R. F.; Bustamante, C.; Collings, P.J.; Giannetto, A.; Gibbs, E. J. J. Am. Chem. Soc. 1993, 115, 5393.   DOI
2 Pasternack, R. F.; Collings, P. J. Science 1995, 269, 935.   DOI
3 Barber, D. C.; Freitag-Beeston, R. A.; Whitten, D. G. J. Phys. Chem. B. 1991, 95, 4047.
4 Kadish, K. M.; Maiya, G. B.; Araullo-McAdams, C. J. Phys. Chem. 1991, 95, 427.   DOI
5 Maiti, N. C.; Mazumdar, S.; Periasamy, N. J. Phys. Chem. B. 1998, 102, 1528.   DOI
6 M.Gandini, S. C.; Yushmanov, V. E.; Borissevith, I. E.; Tabak, M. Langmuir 1999, 15, 6233.   DOI
7 Monsu Scolaro, L.; Donato, C.; Castriciano, M.; Romeo, A.; Romeo, R. Inorg Chim. Acta. 2000, 978, 302.
8 Gandini, S. C. M.; Yushmanov, V. E.; Tabak, M. J. Inorg. Biochem. 2001, 85, 263.   DOI
9 Li, X.; Li, D.; Han, M.; Chen, Z.; Zou, G. Colloids and Surfaces A: Physicochem. Eng. Aspects 2005, 256, 151.   DOI
10 Doan, S. C.; Shanmugham, S.; Aston, E.; McHale, J. L. J. Am. Chem. Soc. 2005, 127, 5885.   DOI
11 Koji, K.; Hideo, M.; Takashi, K.; Shigeru, N. J. Phys. Chem. A. 1997, 101, 6118.   DOI
12 Kano, K.; Fukuda, K.; Wakami, H.; Nishiyabu, R.; Pasternack, R. F. J. Am. Chem. Soc. 2000, 122, 7494.   DOI
13 Yushmanov, V. E.; Imasato, H.; Tominaga, T.; Tabak, M. J. Inorg. Biochem. 1996, 61, 233.   DOI
14 Ribo, J. M.; Crusocts, J.; Farrera, J. A.; Valero, M. L. J. Chem. Soc. Chem. Commun. 1994, 681.
15 Vermathen, M.; Louie, E.A.; Chodosh, A. B.; Ried, S.; Simonis, U. Langmuir 2000, 16, 210.   DOI
16 Gandini, S. C. M.; Yushmanov, V. E.; Borissevitch, I. E.; Tabak, M. Langmuir 1999, 15, 6233.   DOI
17 Schenning, A. P. H. J.; Hubert, D. H. W.; Feiters, M. C.; Nolte, R. J. M. Langmuir 1996, 12, 1572.   DOI
18 Maiti, N. C.; Mazumdar, S.; Perisamy, N. J. Phys. Chem. B. 1998, 102, 1528.   DOI
19 Causgrove, T. P.; Cheng, P.; Brune, D. C.; Blankenship, R. E. J. Phys. Chem. 1993, 97, 5519.   DOI
20 Paschenko, V. Z.; Knox, P. P.; Chamorovsky, S. K.; Krasilnikov, P. M.; Mamedov, M. D.; Semenov, A. Y.; Zakharova, N. I.; Renger, G.; Rubin, A. B. Bioelectrochem. Bioenerg. 2001, 53, 233.   DOI   ScienceOn
21 Li, G. R.; Wu, J. J.; Jin, W. J.; Spectrochimica. Acta A. 2004, 60, 265.   DOI
22 Fleischer, E. B.; Palmer, J. M.; Srivastava, T. S.; Chatterjee, A. J. Am. Chem. Soc. 1971, 93, 3162.   DOI
23 Pasternack, R. F.; Huber, P. R.; Boyd, P.; Engasser, G.; Francesconi, L.; Gibbs, E.; Fasella, P.; Venturo, G. C.; Hinds, L. D. J. Am. Chem. Soc. 1972, 94, 4511.   DOI
24 Chio, M. Y.; Pollard, J. A.; Webb, M. A.; McHale, J. L. J. Am. Chem. Soc. 2003, 125, 810.   DOI
25 Minch, M. J.; Mar, G. L. J. Phys. Chem. 1982, 86, 1400.   DOI
26 Gaplovsky, A.; Galovsky, M.; Toma, S.; Luche, J.-L. J. Org. Chem. 2000, 65, 8444.   DOI
27 Mazumdar, S. J. Phys. Chem. 1990, 94, 5947.   DOI
28 Maiti, N. C.; Mazumdar, S.; Perisamy, N. Curr. Sci. 1996, 70, 997.
29 Kadish, K. M.; Maiya, G. B.; Araullo, C.; Guilard, R. Inorg. Chem. 1989, 28, 2725.   DOI
30 Kadish, K. M.; Maiya, G. B.; Araullo, C. J. Phys. Chem. 1991, 95, 427.   DOI