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Enhanced Electrogenerated Chemiluminescence of Tris (2,2'-bipyridyl) Ruthenium (II)-$S_2O_8^{2-}$ System by Sodium Dodecyl Sulfate

  • Published : 1990.12.20

Abstract

The electrochemical reduction and electrogenerated chemiluminescence (ECL) of $Ru(bpy)_3^{2+}-S_2O_8^{2-}\;in\;CH_3CN-H_2O$ solution were studied in the presence of sodium dodecyl sulfate (SDS) as an anionic surfactant. SDS enhanced the ECL and the fluorescence intensities and lengthened the duration of ECL due to the solubilization of reactants and possibly to the stabilization of ECL intermediates in the SDS micellar environment.

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Cited by

  1. Enhanced Electrochemifluorescence and Reduction Mechanism of Acetoxy Coumarin Derivatives in Acetonitrile Solution vol.27, pp.9, 1990, https://doi.org/10.5012/bkcs.2006.27.9.1329
  2. Synthesis and electrochemiluminescence studies of tricarbonylrhenium(I) complexes with a cationic 2,2′-bipyridyl ligand vol.56, pp.25, 1990, https://doi.org/10.1016/j.electacta.2011.08.016