• Title/Summary/Keyword: Slurries

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In-situ Characterization of Electrochemical and Frictional Behaviors During Copper CMP

  • Eom, Dae-Hong;Kang, Young-Jae;Park, Jin-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.227-230
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    • 2004
  • As the organic acids were added in the slurry, zeta potential of alumina was changed to negative value and IEP value was shifted from alkaline to acidic pH. In citric acid based slurry, Cu surface continuously dissolved and etching depth linearly increased. On the contrary, passivation layer was grown on Cu surface in oxalic acid based slurry. As the platen rotation speed increased, Preston coefficient decreased in both slurries. With oxalic acid based slurry, at low velocity, removal rate is high value because of high friction force compared to citric acid based slurry. As platen velocity increased, removal of Cu in citric acid based slurry became higher value than oxalic acid based slurry. Typical lubrication behaviors were observed in both slurries. As Sommerfeld number increased, COF values gradually decreased and then re-increased. It indicated that lubrication was changed to direct contact or semi-direct contact mode to hydro-lubrication mode.

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Effects of Dietary Amino Acid Additives to Weaned Piglet Diets on pH and Volatile Fatty Acids of Pig Slurry (이유자돈 사료에 아미노산 첨가제가 돈분 슬러리의 pH와 휘발성지방산에 미치는 영향)

  • Chang-Man, Kim
    • Journal of Environmental Science International
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    • v.32 no.3
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    • pp.191-195
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    • 2023
  • This study aimed to investigate the effect of amino acid additives to weaned piglet diets on the pH and volatile fatty acids of pig slurries. A total of 135 weaned 22 -day-old piglets (Yorkshire x Landrace x Duroc) were used in this 56-d study. The three dietary treatments were as follows: (1) Control as a basal diet, (2) 1% amino acid additive and (3) 2% amino acid additive. Both pH and acetic acid values at 71 and 78 days were significantly different in all treatment groups (p<0.05). In addition, significant differences in propionic acid values were observed among treatment groups at 64 and 78 days (p<0.05). However, pH, acetic acid, and propionic acid values did not differ between 1% and 2% amino acid treatment groups. In conclusion, adding 1% and 2% amino acid to weaned piglet diets reduced the pH, acetic acid and propionic acid contents of pig slurries by acting as a probiotic. This may help formulate increase management strategies for improving the pig housing environment.

Fermentation Characteristics of Cheese Slurry prepared from Caseinates (카세인을 이용한 치즈곤죽의 발효특성)

  • Jang, Hae-Dong;Lee, Hyong-Joo
    • Korean Journal of Food Science and Technology
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    • v.17 no.5
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    • pp.389-398
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    • 1985
  • To shorten the processing of cheese slurry, four different slurries, ie, Control, Cheddar 1 and 2, and Italian-type that were made of Na-caseinates, cream, trace elements, lactic culture, and enzymes were fermented at $30^{\circ}C$ for 7days with daily stirring. PH, titratable acidity, soluble nitrogen, viable cell count, active SH groups, total volatile fatty acid, free fatty acid, electrophoretic patterns of degraded caseins, and viscosity were analyzed to investigate physicochemical properties of fermented slurries. Acid production was accelerated in the cheese slurries with protease than that without the enzyme and PH of the former was decreased after three days of fermentation to 4.90. The Change of titratable acidity agreed to PH patterns. Soluble nitrogen of the Control slurry was increased slowly for four days and then rapidly to 40% of total nitrogen while those containing protease to 70%. The protease of lactic cultures used (Streptococcus lactis and Streptococcus cremoris) broke down as-casein more rapidly than $\beta$-casein and most proteins were degraded to peptides and amino acids after three days of fermentation. Total volatile fatty acids were increased by added lipase and free fatty acids composition analyzed by GLC in cheddar slurry with 0.00001% lipase was similar to that of commercial cheddar cheese, while that in Italian-type slurry was a half of that in commercial Italian cheese. Active SH groups were increased in the cheese slurries with glutathione from fourth day of fermentation. The viscosity of slurries decreased very rapidly by addition of protease.

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Changes of Methanogenic Pathway with Incubation Temperatures in the Littoral Sediment of Reservoir Paldang, Korea (팔당호 연안대 저질토에서 배양온도에 따른 메탄발생 경로의 변화)

  • Kim, Mi-Kyeong;Cho, Kang-Hyun
    • Korean Journal of Ecology and Environment
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    • v.34 no.1 s.93
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    • pp.54-61
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    • 2001
  • Changes in methanogenic pathway at low temperature were studied by incubation experiments of sediment slurries from the littoral zone of Reservoir Paldang. Methane production rates in sediment slurries increased exponentially between $5^{\circ}C$and $45^{\circ}C$, reached a maximum rate of $7.4\;nmol\;{\cdot}\;g^{-1}\;{\cdot}\;h^{-1}$ at $45^{\circ}C$, and then declined to low rate. The shift of incubation temperature from high temperature ($30^{\circ}C$) to lowtemperature ($15^{\circ}C$) resulted in a decrease of methane production rate and of hydrogen accumulation rate, and the transient accumulation of acetate concentration. Chlorofarm inhibited perfectly methanogenesis and resulted in the accumulation of hydrogen and acetate as immediate precursors for metltane formation at both incubation temperatures of $15^{\circ}C$ and $30^{\circ}C$. In terms of equivalent methane which was calculated from the two intermediary metabolites accumulated in absence of methanogenesis, methane production from acetate was accounted for 14% of total methanogenesis at $30^{\circ}C$ and 75% at $15^{\circ}C$, respectively. When the high acetate concentrations above 19 mM were added to sediment slurries, methane production was inhibited at the low temperature ($15^{\circ}C$) . Our results demonstrate that contribution of acetate on methanogenesis increases at low temperature, but this pathway is inhibited by high concentration of acetate. Therefore acetate-utilizing methanogensis appears to be a key reaction at low temperature, and seems to be one of bottlenecks of the low temperature anaerobic degradation of organic matter in littoral sediments of the reservoir.

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Quartz Dissolution by Irradiated Bacillus Subtilis (방사선을 조사(照射)한 Bacillus Subtilis에 의한 석영 용해)

  • Lee, Jong-Un
    • Economic and Environmental Geology
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    • v.42 no.4
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    • pp.335-342
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    • 2009
  • The effects of bacterial lysis on the rate of quartz dissolution were investigated under pH 7 condition using Bacillus subtilis cells which were either irradiated or non-irradiated with gamma ray. The amount of dissolved organic carbon (DOC) which resulted from bacterial lysis increased in slurries of quartz and bacteria mixture over experimental period. Lysis of non-irradiated bacteria led to the elevated concentration of dissolved silicon when compared with abiotic control. Concomitant increase in the amounts of DOC and dissolved silicon over time indicated that lixiviation of silicon from quartz was due to bacterial lysis. Higher amounts of DOC and dissolved silicon were present in the irradiated bacterial slurries than those of non-irradiated bacteria. The enhancement of quartz dissolution in the irradiated bacterial slurries was likely attributed to disruption of organic molecules in the bacterial cells by gamma ray and formation of effective ligands for quartz dissolution. The results suggest that the effects of bacterial lysis on mineral weathering rate should be considered for prediction of time for released radionuclides to migrate to surface biosphere in high level radioactive waste disposal site.

An Image Processing System to Estimate Pollutant Concentration of Animal Wastes (가축 분뇨의 오염물질 농도 추정을 위한 영상처리 시스템)

  • 이대원;김현태
    • Journal of Animal Environmental Science
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    • v.7 no.3
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    • pp.177-182
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    • 2001
  • This study was conducted to find out the coefficient relationships between intensity values image processing and pollution density of slurries. Slurry images were obtained from the image processing system using personnel computer and CCD-camera. Software, written in Visual $c^{++}$, combined the functions of the image capture, image processing and image analysis. The data of image processing for slurries were analyzed by the method of regression analysis. The results are as follows. 1. Red(R)-values among image processing data were obtained the highest correlation coefficient 0.9213 for detecting COD. Also, green(G)-value were obtained the highest correlation coefficient 0.9019 fur detecting BOD. Blue(B)-value could not find significant values to detect the pollution resources density. 2. Hue(H)-values among image processing data were obtained the highest correlation coefficient 0.9466 for detecting BOD. This fact could be used in detecting BOD 3. Green(G)-value, GRAY-value, Hue(H)-value, Saturation(5)-value and Intensity(I)-value were the correlation coefficient more than 0.8 for BOD. Hue(H)-value was higher correlation coefficient than any other value. It was possible to detect pollution density of slurries by using the image processing system. 4. Red(R)-value, GRAY-value and Saturation(5)-value were obtained the correlation coefficient more than 0.8 for detecting COD. a-value had the highest correlation coefficient Among these values. It was possible to detect density indirectly by using the image processing system. 5. SS-density were obtained the correlation coefficient less than 0.8 by using the image processing system. The density of $NH_4$-N and $NO_3$-N were obtained correlation coefficient less than 0.2.

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Evaluation of SO2 Absorption Efficiency for Calcined Oyster Shell Slurry Using a Simulated Spray Type-flue Gas Desulfurization (FGD) System: A Comparative Study with Limestone Slurry (모사 Spray Type 배연탈황설비를 이용한 소성패각 슬러리의 SO2 흡수능 평가: 석회석과의 비교연구)

  • Kim, Seok-Hwi;Hong, Bum-Uh;Lee, Jin-Won;Cha, Wang-Seok;Kim, Kangjoo;Moon, Bo-Kyung
    • Economic and Environmental Geology
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    • v.52 no.2
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    • pp.119-128
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    • 2019
  • About 300,000 tones of oyster shell are annually produced in Korea and, thus, a massive recycling plan is required. Many desulfurizing studies using oyster shells with chemical composition of $CaCO_3$ have been performed so far; however, most of them have focused on dry desulfurization. This study investigates the possibility of using oyster shells for wet desulfurization after calcination. For this, a simulated wet desulfurization facility of spray type was devised and compared the SOx-stripping characteristics of calcined oyster shell with those of limestone. The calcined oyster shell slurry indicate a better desulfurizability than the slurries of raw shell or limestone because the oyster shell transformed to a more reactive phase ($Ca(OH)_2$) by the calcination and hydration. Because of this reason, when the calcined oyster shell slurries were used, the reaction residue showed the higher gypsum ($CaSO_4{\cdot}2H_2O$) contents than any other cases. In the continuous desulfurization experiments, calcined oyster shell slurry showed a wider pH variation than limestone or raw oyster shell slurries, another clear indication of high reactivity of calcined oyster shells for $SO_2$ absorption. Our study also shows that the efficiency of wet desulfurization can be improved by the use of calcined oyster shells.

Hardened Properties of Ultra Fine Cement with Superplasticizer (유동화제 변화에 따른 초미립자 시멘트의 경화특성)

  • 채재홍;이종열;이웅종;박경상;김진춘;이세웅
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.10a
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    • pp.69-72
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    • 1999
  • In this study, we blended 2 grades of ultra fine cement using the results of previous stud. And the cement slurry was produced by water each water/cement ratio. The slurries were observed hydration phenomena during 28 days with SEM, XRD and DSC. The specimen made by slurry were evaluated with the hardened properties such as compressive strength, flexural strength length change and water absorption. And were tested the adhesive strength of specimen made by injecting the slurry between mortar bars.

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Morphology Development of HAp Crystallites in GEL Matrix

  • Chang, Myung-Chul
    • Journal of the Korean Ceramic Society
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    • v.44 no.3 s.298
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    • pp.133-136
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    • 2007
  • The crystal morphology of hydroxyapatite [HAp] phase in gelatin [GEL] matrices was investigated with the condition of a GEL precursor treatment in an aqueous solution of $H_{3}PO_{4}$ at $37-80^{\circ}C$. Needle-shaped nanocomposite particles were prepared through a dynamic reaction during a coprecipitation process using a phosphoric GEL solution. Various types of mineralized morphology appeared with a phosphorylated condition of the GEL solution. HAp/GEL nanocomposite slurries showed the existence of an octacalcium phosphate [OCP] phase during the process.