• Journal of Korean Society of Water and Wastewater
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• v.22 no.5
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• pp.571-580
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• 2008

The influence of bacterial stress on anaerobic hydrogen-producing microorganisms was investigated in batch tests using serum bottles. Several physical and chemical stresses (i.e., heating, adding methane producing inhibitor and chemical acidification) were adapted as a pretreament of the seed sludge. In this experiment, the cultivation temperature were set at mesophilic ($35^{\circ}C$) and thermophilic conditions ($55^{\circ}C$) with adjusting pH at 5, 6, and 7 when using the mixture of food waste and activated sludge as a substrate. In conjunction with the pretreatment, hydrogen production was significantly enhanced as compared with that from untreated sludge. However, less biogas (hydrogen and methane) was produced without the pH control, resulted from the decrease of pH to below 4, mainly due to the formation of VFAs. Hydrogen and carbon dioxide gas were analyzed as main components of the biogas while methane not detected. With an application of chemical acidification, the highest hydrogen production value of 248 ml/l/day achieved at pH 7 and $35^{\circ}C$. In addition, more hydrogen gas produced when the ratio of butyric/acetic acid ratio increased. The optimum pH and temperature for hydrogen production were found to be 7 and $35^{\circ}C$, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.6
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• pp.627-632
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• 2008

It is necessary to investigate methods for improvement by diagnosing sludge settling characteristics on inflow of slurry to thickener. The results of the settling tests are correlated to determine zone settling velocities at the various sludge solids concentrations. Conditioning of WTP residuals is generally done by either chemical or physical treatment. The settling test was conducted with 1m columns dosing polymer to WTP residuals at various solids concentration. The estimated results for dosing to WTP residuals for a sludge of 2,100 ~ 16,012 mg/L solids concentration were the zone settling velocities of 48.38 ~ 6.8 m/day, supernatant solid concentration of 3.2 ~ 19 mg/L and solid flux of $101.6{\sim}317.61kg/m^3{\cdot}day$. The values for non-polymer treatment were the zone settling velocities of 28.37 ~ 0.12 m/day, supernatent solid concentration of 8.5 ~ 108 mg/L and solid flux of $59.58{\sim}1.92kg/m^2{\cdot}day$. The limiting solid flux value by Yoshioka methods was $4.0kg\;TS/m^3{\cdot}day$ for Non-polymer and $228.0kg\;TS/m^3{\cdot}day$ for dosing polymer. These results are to indicate a possibility of improvement on the thickening characteristics and the quality of supernatant as increasing the settling velocities by dosing polymer to WTP residuals.

• Resources Recycling
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• v.6 no.1
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• pp.40-46
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• 1997

Sludgc d~sposal has been a major challenge in the wastewater treatment. Drying is operation which is separated fromsewage sludge to solid and liquid by heating. Drying needs to pretreatment process for effective "thation, incinerationand dispaal The objective of this work was to the drying dewatered sewage sludge by microwave heating, and tocompare the experimental rcsults with thcorctical rcsults. Microwave drylng is fast and has a high efficiency. In thepresent \ark, an unsteady state analysis of one dunensional drying, with microwave heating, is carried out. In drying ratecurve, moisture movement at falling rate period occured by dfision. A good agreement was abtamed between the modcland the experimental results using the slab sample of 0.2cm thickness. 0.2cm thickness.

• Journal of the Korea Organic Resources Recycling Association
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• v.11 no.4
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• pp.66-78
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• 2003

The effects of several factors such as heavy metals, living microorganims, high molecular conglomerator in sewage sludge were analysed. And the effects of the sewage sludges which were mixed with other organic waste such as paper mill sludge or night soil sludge upon the feeding rate and biomass of earthworm population were also estimated. The earthworm populations could not survive when newly produced sewage sludges were fed without any pretreatment. The contents of heavy metals were under the levels that could inhibit earthworm's growth. The living microorganisms and the high molecular conglomerator in the sewage sludge had no relations with ecotoxicological effects of sewage sludge upon the earthworm population. Sewage sludge which had been mixed with paper mill sludge and aged for more than 21 days showed no ecotoxicological effects on tiger worm(Eisenia fetida) population. And the feeding rate of earthworm population and the turnover rate of earthworm biomass were higher in those sewage sludges than in the sewage sludges pretreated by other ways.

• Journal of Korean Society of Water and Wastewater
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• v.32 no.6
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• pp.559-572
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• 2018

The aim of this study was to evaluate pretreatment methods for 27 pharmaceuticals and personal care products (PPCPs) in various sewage samples using a modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) and online solid-phase extraction with LC-MS/MS. Extraction efficiencies of PPCPs in the solid phase under different experimental conditions were evaluated, showing that the highest recoveries were obtained with the addition of sodium sulfate and ethylenediaminetetraacetic acid disodium salt dehydrate in acidified conditions. The recoveries of target compounds ranged from 91 to 117.2% for liquid samples and from 61.3 to 137.2% for solid samples, with a good precision. The methods under development were applied to sewage samples collected in two sewage treatment plants (STPs) to determine PPCPs in liquid and solid phases. Out of 27 PPCPs, more than 19 compounds were detected in liquid samples (i.e., influent and effluent) of two STPs, with concentration ranges of LOQ-33,152 ng/L in influents and LOQ-4,523 ng/L in effluents, respectively. In addition, some PPCPs such as acetylsalicylic acid, ibuprofen, and ofloxacin were detected at high concentrations in activated sludge as well as in excess sludge. This methodology was successfully applied to sewage samples for the determination of the target compounds in STPs.

• Journal of Korean Society of Water and Wastewater
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• v.7 no.1
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• pp.20-28
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• 1993

The Wastewater from the weight reduction process of polyester is more difficult to be treated biologically than the general wastewater from dyeing and finishing processes in textile industries. Above wastewater shows high pH, high organic strength and wide variation of organic loading. These characteristics are due to TPA and EG resulting from alkaline weight-reduction process and make trouble in the operation of activated sludge process. Therefore, the objective of this study is to develop the pretreatment method for the successful operation of treatment process. For the successful pretreatment process, the wastewater from weight-reduction process should be segregated from other wastewater stream and then acidified with concentrated sulfuric acid to precipitate out TPA from DST solution. At the optimum pH of 2. 2, the initial $COD_{cr}$ 60,000mg/l is reduced to 11,500mg/l and the removal efficiency of $COD_{cr}$ is 81.1%. The required amount of sulfuric acid for pretreatment is not greater than the amount for the the existing neutralization process. Moreover, the supernatant of pretreatment process can be reused in acidification of wastewater.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.1
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• pp.23-30
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• 2013

The sludge disposal is a major economic factor in the sewage treatment facility operation. Moreover, since the ocean dumping will be prohibited by Korean environmental law from 2013, sludge should be eliminated or sludge volumetric reduction should be performed urgently. In this study, improvement of the sewage sludge dewaterability was investigated by ultrasound and electric field treatment. Sludge was treated by a single or in combination of either the electric field or ultrasound on a pilot pretreatment facility, then it was dewatered by lab-scale filter press. The operating input energy of ultrasound device was varied from 225~1,200 kJ/L and electric field device was varied from 4.5~24 kJ/L. The water contents of dewatered sludge cake treated with ultrasound (1,200 kJ/L) and combination of ultrasound/electric field (1,224 kJ/L) were decreased 10~12% by comparing non-treated sludge. At that time, water contents were 65~66%. The combination treatment of ultrasound/electric field was effective to reduce water content of dewatered sludge cake, however, water content was not changed by a single treatment of electric field because of low energy density.

• Journal of Korean Society on Water Environment
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• v.23 no.5
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• pp.781-788
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• 2007

The Carbon source to enhance the denitrification is essential matter in the advanced sewage treatment. For the high level of nutrient removal, external carbons such as ethanol, methanol, volatile fatty acids and so on should be needed. In this study, the methods to increase the sludge solubilization and acidification rate were compared with waste activated sludges and food waste leachate. Ultrasonication and acids were used for the pretreatment of organic particles in sludges. As a results, the optimal temperature and HRT were $60^{\circ}C$ and 5 days, respectively. HAc, HPr, HBr, and other VFAs for acid fermentations reduced up to 22, 16, 14, and 48% with HRT reduction. For the increase of solubilization, 28% of solids destruction rate was shown at 0.3 watts/mL.

• New & Renewable Energy
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• v.1 no.2 s.2
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• pp.60-72
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• 2005

The effect of alkaline pre-treatment on the solubilization of waste activated sludge(WAS) was investigated, and the biodegradability of WAS, pretreated WAS, [PWAS], food waste and two types of mixture were estimated by biochemical methane potential [BMP] test at $35^{\circ}C$. The biodegradability of PWAS and mixture waste were significantly improved due to the effect of alkaline hydrolysis of WAS. An alkaline pre-treatment was identified to be one of the useful pre-treatment for improving biodegradability of WAS and mixture waste. In high-rate anaerobic co-digestion system coordinate with an alkaline pre-treatment in process, the digesters were operated at the HRT of 5, 7, 10 and 13 days with a mixture of FW $50\%\;and\;PWAS\;50\%,\;$In term of $CH_4$ content, VS removal and specific methane production [SMP] which are the parameters in the performance of digester, the optimum operating condition was found to be a HRT of 7 days and a OLR of 4.20g/L-day with the highest SMP of 0.340 L $CH_4/g$ VS.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.5
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• pp.551-558
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• 2007

From the view point of biological wastewater treatment, C/N ratio is one of the most important factor in biological nutrient removal process. However, municipal sewage in Korea is characterized by extremely low content of carbon source and relatively higher portion of N source. Accordingly, it is necessary to dose external carbon source in order to obtain higher degree of carbon source within the process. In this study, the effects of pH pretreatment as an alternative plan for increasing carbon source on the cell disruption and COD solubility of waste activated sludge were conducted under well defined experimental conditions. During 5 hours, the value of COD solubilization rate ($S_R$) at pH 11.5 is approximately 4.4 times higher than the value of $S_R$ at pH 9.5. It is expected that the level of SCOD increased due to the result from cell disruption. However, VSS/TSS ratio was not significantly changed after 5 hours. As Alkalinity changes gradually from less than 15, 30 and 60 meq NaOH/L, average RBCOD/SCOD fraction showed 34, 36 and 45%,respectively.