• 제목/요약/키워드: Sintering aids

검색결과 104건 처리시간 0.029초

저온소결 PMN-PZT 압전세라믹의 소성시간에 따른 미세구조 및 압전특성 (Microstructural and Piezoelectric Properties of Low Temperature Sintering PMN-PZT Ceramics with the Variations of Sintering Times)

  • 류주현;이창배;이상호;백동수;정영호;임인호
    • 한국전기전자재료학회논문지
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    • 제18권3호
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    • pp.237-242
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    • 2005
  • In this paper, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, PMN-PZT ceramics were manufactured with the variations of sintering times, and their microstructural, piezoelectric and dielectric properties were investigated. Li$_2$CO$_3$ and Bi$_2$O$_3$ were used as sintering aids and the specimens were sintered during 30, 60, 90, 120, 150, and 180 minutes, respectively. At the specimen sintered during 90 minute, mechanical quality factor(Qm), electro-mechanical coupling factor(kp) and dielectric constant were showed the optimum values of 2,356, 0.504 and 1,266, respectively.

MnO2 첨가에 따른 저온소결 PCW-PMN-PZT세라믹스의 유전 및 압전특성 (Dielectric and Piezoelectric Properties of Low Temperature Sintering PCW-PMN-PZT Ceramics according to MnO2 Addition)

  • 정광현;이덕출;이창배;이상호;류주현;이형규;강형원
    • 한국전기전자재료학회논문지
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    • 제18권2호
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    • pp.136-141
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    • 2005
  • In this study, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, PCW-PMN-PZT ceramics using Li$_2$CO$_3$, Bi$_2$O$_3$, and CuO as sintering aids were manufactured according to the amount of MnO$_2$ addition. Their microstructural, dielectric and piezoelectric properties were investigated. When the sintering aids were added, specimens could be sintered below 95$0^{\circ}C$, but mechanical qualify factor decreased. Therefore, MnO$_2$ was added excessively to the PCW-PMN-PZT ceramics to increase mechanical quality factor. At the sintering temperature of 95$0^{\circ}C$, the density, dielectric constant($\varepsilon$$_{r}$), electromechanical coupling factor(k$_{p}$), mechanical quality factor(Q$_{m}$) and Curie temperature(T$_{c}$) of 0.1 wt% MnO$_2$ added specimen showed the optimal values of 7.75 g/㎤, 1503, 0.57, 1502, and 337, respectively, for multilayer piezoelectric transformer application.ation.n.

소결조제 ZnO 첨가에 따른 저온소결 0.20Pb(Zn1/3Nb2/3)O3-0.80Pb(Zr0.48Ti0.52)O3 세라믹스의 유전 및 압전특성 (Dielectric and Piezoelectric Characteristics of Low Temperature Sintering 0.20Pb(Zn1/3Nb2/3)O3-0.80Pb(Zr0.48Ti0.52)O3 Ceramics with the Addition of Sintering Aid ZnO)

  • 류주현;이유형;김도형;이일하;권준식;백동수
    • 한국전기전자재료학회논문지
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    • 제21권2호
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    • pp.126-130
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    • 2008
  • In this study, in order to develop low loss multilayer piezoelectric actuator, PZN-PZT ceramics were fabricated using $Li_2CO_3,\;Bi_2O_3$, CuO and ZnO as sintering aids, their structural, piezoelectric and dielectric characteristics were investigated according to the amount of ZnO addition, At the sintering temperature of $870^{\circ}C$, the density, electromechanical coupling factor(kp), mechanical quality factor(Qm), dielectric constant(${\epsilon}_r$) and piezoelectric constant($d_{33}$) of 0.4 wt% ZnO added specimen (sintered at $870^{\circ}C$) showed the optimum value of $7.812g/cm^3$, 0.535, 916, 1399, 335 pC/N respectively. Taking into consideration above piezoelectric properties of the specimen sintered at low temperature, it was concluded that PZN-PZT ceramics using 0.4 wt% ZnO as additive showed the optimum characteristics as the composition ceramics for low loss multilayer piezoelectric actuator application.

PMW-PNN-PZT 세라믹스의 Bismuth 치환에 따른 미세구조 및 압전 특성 (Microstructure and Piezoelectric Properties of PMW-PNN-PZT Ceramics with Bismuth Substitution)

  • 김용진;류주현;신동찬
    • 한국전기전자재료학회논문지
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    • 제29권6호
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    • pp.332-336
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    • 2016
  • In this study, in order to develop the composition ceramics for ultrasonic sensor with high $d_{33}*g_{33}$, $Pb_{1-3x/2}Bix(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3$(PMW-PNN-PZT) system ceramics were prepared using CuO as sintering aids. And then, their microstructure, piezoelectric and dielectric characteristics were systemetically investigated with bismuth substitution. The PMW-PNN-PZT ceramic specimens could be sintered at sintering temperature of $940^{\circ}C$ by adding sintering aids. At x=0.015 specimen, the density, electromechanical coupling factor($k_p$), dielectric constant, piezoelectric constant($d_{33}$) and piezoelectric figure of merit($d_{33}*g_{33}$) indicated the optimal properties of $7.90g/cm^3$, 0.67, 2,511, 628 pC/N, and $17.7pm^2/N$, respectively, for duplex ultrasonic sensor application.

적층 압전 변압기용 변성 $PbTiO_3$ 세라믹스의 압전 및 유전 특성 (Piezoelectric and dielectric Properties for Multilayer Piezoelectric Transformer Of Modified $PbTiO_3$ system ceramics)

  • 유경진;류주현;정영호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.344-345
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    • 2006
  • In this study, in order to develop low temperature sintering piezoelectric transformer, $(Pb_{0.99-x}Ca_xSr_{0.01})Ti_{0.96}(Mn_{1/3}Sb_{2/3})_{0.04}O_3$ ceramic systems were fabricated using $Na_2CO_3-Li_2CO_3$ as sintering aids and investigated with the amount of Ca substitution. The piezoelectric transformer requires high electromechanical coupling factor $k_t$ and high mechanical quality factor $Q_{mt}$ for generating high output power At the ($PbCaSr)Ti(MnSb)O_3$ ceramics with 24mol% Ca substitution sintered at $900^{\circ}C$, electromechanical coupling factor $k_t$ and mechanical quality factor $Q_{mt}$ showed the optimal values of 0.504 and 1655 respectively, for thickness vibration mode multilayer piezoelectric transformer application.

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저온소결 PMgN-PMnN-PZT 세라믹스의 압전 및 유전 특성 (Piezoelectric and Dielectric Characteristics of Low Temperature Sintering PMgN-PMnN-PZT Ceramics)

  • 이상호;류주현;홍재일;정광현;정영호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 제37회 하계학술대회 논문집 C
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    • pp.1400-1401
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    • 2006
  • In this study, in order to develop low temperature sintering piezoelectric ceramics for multilayer piezoelectric actuator, $PbSr(Mn_{1/3}Nb_{2/3})O_3-(Mg_{1/3}Nb_{2/3})O_3-(ZrTi)O_3$ ceramics were fabricated using $Na_{2}CO_{3}-Li_{2}CO_{3}$ as sintering aids and their piezoelectric and dielectric characteristics were investigated according to the sintering tempo rature. At the sintering temperature of $900^{\circ}C$, the density, electrom echanical coupling factor(kp), mechanical quality factor(Qm) and dielectric constant(${\varepsilon}r$) of specimen showed the optimum value of $7.730[g/cm^2]$, 0.552, 1134, 1492 and 330[pC/N], respectively.

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승온속도에 따른 저온소결 PMN-PNN-PZT 세라믹스의 유전 및 압전특성 (Dielectric and Piezoelectric Characteristic of Low Temperature Sintering PMN-PNN-PZT Ceramics according to the Heating Rate)

  • 김국진;류주현;홍재일
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
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    • pp.253-254
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    • 2007
  • In this study, in order to develop low temperature sintering multilayer piezoelectric actuator, PMN-PNN-PZT system ceramics were fabricated using $Li_2CO_3-Bi_2O_3$-CuO as sintering aids and their piezoelectric and dielectric characteristics were investigated as a function of heating rate. At sintering temperature of $900^{\circ}C$, with increasing heating rate, electromechanical coupling factor(kp), mechanical quality factor(Qm) and dielectric constant $({\varepsilon}_r)$ were increased.

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적층 압전변압기용 저온소결 PMN-PZT 압전세라믹의 소성시간에 따른 미세구조 및 압전특성 (Microstructural and piezoelectric properties of low temperature sintering PMN-PZT ceramics for multilayer piezoelectric transformer with the variations of sintering times)

  • 이창배;류주현;이상호;백동수;정영호;윤현상;임인호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.425-430
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    • 2004
  • In this paper, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, PMN-PZT ceramics were manufactured with the variations of sintering times, and their microstructural, piezoelectric and dielectric properties were investigated. To manufacture multilayer piezoelectric transformer, the low temperature sintering composition is need, hence, $Li_2CO_3$ and $Bi_2O_3$ were used as sintering aids and the specimens were sintered during 30, 60, 90, 120, 150 and 180 minutes, respectively. At the specimen sintered during 90 minute, mechanical quality factor(Qm), electromechanical coupling factor(kp) and dielectric constant were showed the optimum values of 2356, 0.504 and 1266, respectively. All the specimens showed tetragonality phase, and pyrochlore phase was not shown.

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저온 소결 조제에 따른 PMN-PZ-PT 후막 세라믹 특성 (Characteristics of PMN-PZ-PT Thick Film Ceramic by Low-Temperature Sintering Aids)

  • 정명원;전대우;김진호;이영진
    • 한국전기전자재료학회논문지
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    • 제29권8호
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    • pp.476-482
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    • 2016
  • Convectional PZT based piezoelectric ceramics have to sinter at high temperature about $1,200^{\circ}C$ for their suitable electrical properties. However, some issues: low temperature sintering piezoelectric ceramic composition and reliable internal electrode, have recently attracted a great deal of interest as a highly efficient multi-layered piezoelectric ceramics. In order to optimize low temperature sintering conditions of thick-film PMN-PZ-PT ceramic, it was investigated sintering and piezoelectric properties according to the change of $LiBiO_2$ contents. Thus, the superior piezoelectric properties were found at the pallet type PMN-PZ-PT optimized with low sintering processing at $925^{\circ}C$ including 7 wt% $LiBiO_2$ sintering aid. Consequentially, we successfully manufactured thick-film PMN-PZ-PT ceramics, which had superior piezoelectric and dielectric properties, with 5 wt% of $LiBiO_2$ sintering aid at temperature of $900^{\circ}C$.