• 한국세라믹학회지
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• 제52권6호
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• pp.473-478
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• 2015

Green bodies of earthenware tile were prepared from a mixture of earthenware tile powder and SiC as forming agents by applying a conventional process. Granule powder for tile samples was prepared using the spray drying method with commercial earthenware raw material with a quantity of SiC of 0.3 wt%. The applied pressure was $250kg{\cdot}f/m^2$ and the firing temperature was $1050-1200^{\circ}C$. The effects of the SiC particle size and sintering temperature on the open porosity and total porosity were investigated and the correlative mechanism was also discussed. While total porosity was not significantly changed by decreasing the SiC particle size, the open porosity showed a gradual decrease, which represents an increase of the closed porosity. As the sintering temperature increased, coarsening was made among the pores due to excessive oxidation. The volume shrinkage and bending strength were demonstrated for the sintered tile samples. The sintered bulk density was also measured to determine the weight reduction value.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.589-590
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• 2006

Based on the comparison of structures and properties of the HS6-5-2 high speed steels made with the powder injection moulding method, pressureless forming, compacting and sintering, and commercial steels made with the ASEA-STORA method, fine carbides spread evenly in the steel matrix were found in the structure of all tested high-speed steels in the sintered state. The steels made with the pressureless forming method are characteristic of the lowest sintering temperature and the highest density, resulting from the high carbon concentration coming from the binding agent degradation.

• 대한금속재료학회지
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• 제56권12호
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• pp.854-860
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• 2018

In spite of the many attractive properties of (W,Ti)C, its low fracture toughness limits its wide application. To improve the fracture toughness generally a second phase is added to fabricate a nanostructured composite. In this regard, graphene was considered as the reinforcing agent of (W,Ti)C. (W,Ti)C-graphene composites that were sintered within 2 min using pulsed current activated heating under a pressure of 80 MPa. The rapid consolidation method allowed retention of the nano-scale microstructure by blocking the grain growth. The effect of graphene on the hardness and microstructure of the (W,Ti)C-graphene composite was studied using a Vickers hardness tester and FE-SEM. The grain size of (W,Ti)C was reduced remarkably by the addition of graphene. Furthermore, the hardness decreased and the fracture toughness improved with the addition of graphene.

• 한국세라믹학회지
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• 제43권2호
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• pp.92-97
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• 2006

Dolomite type $BaSn(BO_3)_2$ ceramics with rhombohedral crystal structure has been synthesized via solid state reaction route. Dielectric properties were measured for the samples sintered at $1050\~1200^{\circ}C$ for 2 h in air. Dielectric constant, loss tangent, and temperature coefficient were increased with sintering temperature due to the evolution of $BaSnO_3$, secondary, phase. Optimum dielectric properties were obtained at the $BaSn(BO_3)_2$ ceramics sintered at $1100^{\circ}C.\;CuO/Bi_2O_3$ was added to $BaSn(BO_3)_2$ ceramics to lower the sintering temperature for LTCC application, then Co and Fe-based coloring agents were added for colorizing the LTCC tape. Typical dielectric properties of $BaSn(BO_3)_2$ ceramics with $5 wt\%\;CuO/Bi_2O_3\;and\;3wt\%$ Co-coloring agent that sintered at $900^{\circ}C$ were $\varepsilon_r=9.89,\;tan{\delta}=0.92\times10^{-3},\;and\;TCC=112ppm/^{\circ}C$. Thus obtained LTCC tape was co-fired with Ag paste for compatibility test and revealed no sign of Ag reaction with the ceramics.

• 한국재료학회지
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• 제24권2호
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• pp.111-115
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• 2014

Titanium and its alloys are useful for implant materials. In this study, porous Ti-Nb-Zr biomaterials were successfully synthesized by powder metallurgy using a $NH_4HCO_3$ as space holder and $TiH_2$ as foaming agent. Consolidation of powder was accomplished by spark plasma sintering process(SPS) at $850^{\circ}C$ under 30 MPa condition. The effect of high energy milling time on pore size and distribution in Ti-Nb-Zr alloys with space holder($NH_4HCO_3$) was investigated by optical microscope(OM), scanning electron microscope(SEM) & energy dispersive spectroscopy(EDS) and X-ray diffraction(XRD). Microstructure observation revealed that, a lot of pores were uniformly distributed in the Ti-Nb-Zr alloys as size of about $30-100{\mu}m$ using mixed powder and milled powders. In addition, the pore ratio was found to be about 5-20% by image analysis, using an image analyzer(Image Pro Plus). Furthermore, the physical properties of specimens were improved with increasing milling time as results of hardness, relative density, compressive strength and Young's modulus. Particularly Young's modulus of the sintered alloy using 4h milled powder reached 52 GPa which is similar to bone elastic modulus.

• 한국세라믹학회지
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• 제41권2호
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• pp.165-169
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• 2004

$Zn_{1-x}(Li_{1/2}La_{1/2})_xTiO_3$ ($0.01{\leq}x{\leq}0.05$)세라믹스에 $H_3BO_3$를 4 wt% 첨가 후 $(Li_{1/2}La_{1/2})^{2+}$ 치환량 변화에 따른 저온 소결 거동 및 마이크로파 유전특성을 고찰하였다. 저온 소결첨가제인 H$_3$BO$_3$를 4 wt% 첨가하여 소결온도를 $1150^{\circ}C$에서 $875^{\circ}C$로 낮출 수 있었으며, 치환량 변화에 따른 유전상수와 공진주파수 온도계수(TCF)의 변화는 존재상의 유전체 혼합 법칙(dielectric mixing rule)에 의존하였고, 품질계수(Qf)는 소결 시편의 밀도와 미세구조에 의존하여 변화되었다 $875^{\circ}C$에서 3시간 소결한 경우 x=0.03에서 K=26.5, Qf=19,030 GHz, TCF=7.5 ppm$/^{\circ}C$를 얻을 수 있었다.

• 한국산학기술학회논문지
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• 제19권8호
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• pp.176-182
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• 2018

심미 치과보철물의 가장 중요한 요인 중의 하나는 치아의 색상이다. 지르코니아는 디자인, 밀링, 착색, 건조, 소결과정을 거치는데, 이때의 지르코니아 착색제의 건조 정도가 색조에 어떠한 영향을 미치는지 알아보고자 한다. 실험을 위해 캐드캠을 이용하여 지르코니아 블록별(L block(LAZOR), Z block(Zircos-E block posterior), A block(AlphaZ))로 각 15개씩 총 45개의 원형 시편을 제작하였다. 그다음 지르코니아 시편을 화학적 착색제를 이용하여 미건조(0sec), 중간건조(10sec), 완전건조(10min)의 온도유지시간(Temperature dwelling time)을 부여하여 오븐에서 건조한 후 제조회사 지시대로 지르코니아 시편을 소결하였다. 분광광도계를 이용하여 색조를 측정하였다. 치과용 지르코니아 시편의 건조유지시간에 따라 색조의 변화를 비교 분석하기 위해 One-way ANOVA를 시행하고, 사후검정으로 Tukey test를 실시하였다. 지르코니아 $L^*$값은 L, A 시편과 $a^*$값은 A 시편, $b^*$값은 Z 시편의 건조 정도에 따라 통계적으로 차이가 없으나 (p>0.05), $L^*$값은 Z 시편과 $a^*$값은 L, Z 시편, $b^*$값은 L, A 시편이 건조 정도에 따라 통계적으로 차이가 있었다(p<0.05). 결론적으로 착색제의 건조유지시간이 길수록 지르코니아 명도를 밝게 하고, 법랑질의 광학적 특성을 증가시킨다.

• 한국분말재료학회지
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• 제25권2호
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• pp.126-131
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• 2018

In the present study, we investigate the effects of milling time and the addition of a process control agent (PCA) on the austenite stability of a nanocrystalline Fe-7%Mn alloy by XRD analysis and micrograph observation. Nanocrystalline Fe-7%Mn alloys samples are successfully fabricated by spark plasma sintering. The crystallite size of ball-milled powder and the volume fraction of austenite in the sintered sample are calculated using XRD analysis. Changes in the shape and structure of alloyed powder according to milling conditions are observed through FE-SEM. It is found that the crystallite size is reduced with increasing milling time and amount of PCA addition due to the variation in the balance between the cold-welding and fracturing processes. As a result, the austenite stability increased, resulting in an exceptionally high volume fraction of austenite retained at room temperature.

• 한국세라믹학회지
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• 제43권5호
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• pp.277-283
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• 2006

A porous material with a surface layer was fabricated from glass abrasive sludge and expanding agents. The glass abrasive sludges were mixed with expanding agents and compacted into precursors. These precursors were sintered in the range of $700-900^{\circ}C$ for 20 min. The sintered porous materials had a surface layer with smaller pores and inner parts with larger pores. The surface layer and closed pores controlled water absorption. As the expanding agent fraction and the sintering temperature increased, the porosity and pore size increased. The porous materials with $Fe_2O_3$ and graphite as the expanding agents had a low absorption ratio of about 3% or lower while the porous material with $CaCO_3$ as the expanding agent had a higher absorption ratio and more open pores.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1165-1166
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• 2006

An experiment was carried out to investigate the effect of Ba Stearate as a reducing agent on the magnetic and physical properties of anisotropic $BaFe_2-W$ type ferrite magnets. It was found that the magnetic properties of $BaO{\cdot}8.5Fe_2O_3$ were improved by adding 0.3 wt% of Ba Stearate, 0.5 wt% of $SiO_2$, and 0.5 wt% of CaO together. The optimum conditions for making magnets were as follows; semisintering condition: $1350^{\circ}C{\times}4.0$ h in nitrogen gas atmosphere, drying condition: $180^{\circ}C{\times}2.0$ h in air, sintering condition: $1160^{\circ}C{\times}1.5$ h in nitrogen gas atmosphere. Magnetic and physical properties of a typical sample were $J_m$ = 0.46 T, $J_r$ = 0.43 T, $H_{cJ}$ = 182.3 kA/m, $H_{cB}$ = 177.2 kA/m, $(BH)_{max}$ = 33.8 kJ/$m^3$, $T_C$ = $495^{\circ}C$ and $K_A$ = $2.65{\times}10^5\;J/m^3$ and $H_A$ = 1332 kA/m.