• 한국분말재료학회지
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• 제29권2호
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• pp.110-117
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• 2022

The grain growth behavior in the (1-x)K_0.5Na_0.5NbO₃-xCaZrO₃ (KNNCZ-x) system is studied as a function of the amount of CZ and grain shape. The (1-x)K_0.5Na_0.5NbO₃-xCaZrO₃ (KNNCZ-x) powders are synthesized using a conventional solid-state reaction method. A single orthorhombic phase is observed at x = 0 - 0.03. However, rhombohedral and orthorhombic phases are observed at x = 0.05. The grain growth behavior changes from abnormal grain growth to the suppression of grain growth as the amount of CaZrO₃ (CZ) increases. With increasing CZ content, grains become more faceted, and the step-free energy increases. Therefore, the critical growth driving force increases. The grain size distribution broadens with increasing sintering time in KNNCZ-0.05. As a result, some large grains with a driving force larger than the critical driving force for growth exhibit abnormal grain growth behavior during sintering. Therefore, CZ changes the grain growth behavior and microstructure of KNN. Grain growth at the faceted interface of the KNNCZ system occurs via two-dimensional nucleation and growth.

• 대한통합의학회지
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• 제10권4호
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• pp.145-151
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• 2022

Purpose : Stroke patients exhibit abnormal walking patterns such as slow walking speed and asymmetrical walking values. The recovery of symmetrical walking in the stance phase using a treadmill means improvements in walking speed and asymmetrical walking. The purpose of this research was to investigate the effect of unilateral step treadmill training (USTT) on gait speed and the recovery of symmetrical walking in chronic stroke patients. Methods : Fifteen patients (11 men and 4 women) with chronic stroke participated in this study. The 10-meter walk test (10MWT) and GAITRite system were used to determine the intervention-related changes in gait speed and symmetrical walking values such as non-paretic step length (NSL), non-paretic step time (NST), paretic single-support time (PSST), step length asymmetry (SLA), and step time asymmetry (STA) after USTT. All participants completed USTT and underwent measurements at 3 different times: at pretest, posttest, and the follow-up test. Repeated-measures analysis of variance was used to compare walking speed and asymmetrical walking values. The statistical significance level was set at p<.05. Results : Walking speed by 10MWT (p<.05) showed significant improvements after USTT as follows: at pretest and posttest (p<.05), posttest and follow-up test (p<.05), and pretest and follow-up test (p<.05). Recovery of symmetrical walking patterns such as NSL (p<.05), NST (p<.05), and SLA (p<.05) were observed after USTT. However, no significant improvements were found in PSST (p>.05) and STA (p>.05) in symmetrical gait. Conclusion : This study suggests that USTT may have a positive effect on walking speed and symmetrical walking patterns in chronic stroke patients. Thus, this study contributes to the existing knowledge about the usefulness of USTT for the effective management of patients with chronic stroke. Further studies are needed to generalize these findings.

• 한국분말재료학회지
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• 제30권1호
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• pp.13-21
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• 2023

In additive manufacturing, the flowability of feedstock particles determines the quality of the parts that are affected by different parameters, including the chemistry and morphology of the powders and particle size distribution. In this study, the microstructures and flowabilities of gas-atomized heat-resistant alloys for additive manufacturing applications are investigated. A KHR45A alloy powder with a composition of Fe-30Cr-40Mn-1.8Nb (wt.%) is fabricated using gas atomization process. The microstructure and effect of powder chemistry and morphology on the flow behavior are investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and revolution powder analysis. The results reveal the formation of spherical particles composed of single-phase FCC dendritic structures after gas atomization. SEM observations show variations in the microstructures of the powder particles with different size distributions. Elemental distribution maps, line scans, and high-resolution XPS results indicate the presence of a Si-rich oxide accompanied by Fe, Cr, and Nb metal oxides in the outer layer of the powders. The flowability behavior is found to be induced by the particle size distribution, which can be attributed to the interparticle interactions and friction of particles with different sizes.

• Natural Product Sciences
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• 제28권4호
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• pp.168-180
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• 2022

Ephedra is a genus of the Ephedraceae family and is found in temperate regions, such as Central Asia and Europe. Among the various ephedra species, Ma Huang (Ephedra herb) is derived from the aerial parts of Ephedra sinica S tapf, Ephedra equisetina Bunge, and Ephedra intermedia Schrenk & C.A. Mey. Ma Huang contains various ephedra alkaloids, including (-)-ephedrine, (+)-pseudoephedrine, (-)-norephedrine, (+)-norpseudoephedrine, (-)-methylephedrine, and (+)-methylpseudoephedrine, which are found naturally as single enantiomers, although they can be prepared as racemates. Although the use of Ma Huang in foods is prohibited in Korea, products containing Ma Huang can be imported, and so it is necessary to develop a suitable analytical technique for the detection of Ma Huang in foods. Herein, we report the development of analytical methods for the detection of ephedra alkaloids in products containing Ma Huang. Following sample purification by solid phase extraction, quantitative analysis was performed using ultra-performance liquid chromatography-triple quadrupole mass spectrometry (UPLC-MS/MS). Additionally, the enantiomers were successfully separated using HPLC-DAD. We successfully analyzed various food samples, where the ephedra alkaloids were qualitatively and quantitatively determined, and the enantiomers were separated. It is expected that these methods may contribute toward preventing the distribution of illegal products containing Ma Huang.

• Clinics in Shoulder and Elbow
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• 제25권4호
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• pp.265-273
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• 2022

Background: Massive rotator cuff tears (MRCTs) with subscapularis (SSC) tears cause severe shoulder dysfunction. In the present study, the influence of SSC tears on three-dimensional (3D) shoulder kinematics during scapular plane abduction in patients with MRCTs was examined. Methods: This study included 15 patients who were divided into two groups: supraspinatus (SSP) and infraspinatus (ISP) tears with SSC tear (torn SSC group: 10 shoulders) or without SSC tear (intact SSC group: 5 shoulders). Single-plane fluoroscopic images during scapular plane elevation and computed tomography (CT)-derived 3D bone models were matched to the fluoroscopic images using two-dimensional (2D)/3D registration techniques. Changes in 3D kinematic results were compared. Results: The humeral head center at the beginning of arm elevation was significantly higher in the torn SSC group than in the intact SSC group (1.8±3.4 mm vs. -1.1±1.6 mm, p<0.05). In the torn SSC group, the center of the humeral head migrated superiorly, then significantly downward at 60° arm elevation (p<0.05). In the intact SSC group, significant difference was not observed in the superior-inferior translation of the humeral head between the elevation angles. Conclusions: In cases of MRCTs with a torn SSC, the center of the humeral head showed a superior translation at the initial phase of scapular plane abduction followed by inferior translation. These findings indicate the SSC muscle plays an important role in determining the dynamic stability of the glenohumeral joint in a superior-inferior direction in patients with MRCTs.

• 한국수소및신에너지학회논문집
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• 제33권6호
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• pp.808-818
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• 2022

In this research paper, we investigated the cryogenic line chill down characteristics of liquefied natural gas (LNG). A numerical analysis model was established and verified so that it can calculate the precise cooling characteristics of cryogenic fluid for the stable and safe utilization especially such as LNG and liquid hydrogen. The numerical modeling was programmed by C++ as an one-dimensional homogeneous model. The thermohydraulic cooling process was simulated using mass, momentum, energy conservation equations and appropriate heat transfer correlations. In this process, the relevant heat transfer correlations for nuclear boiling, transition boiling, film boiling, and single-phase heat transfer that can predict the experimental results were implemented. To verify the numerical modeling, several cryogenic line chill down experiments using LNG were conducted at the Korea Institute of Machinery & Materials (KIMM) LNG and Cryogenic Technology Center.

• Elastomers and Composites
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• 제58권1호
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• pp.32-43
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• 2023

The worldwide use of polyurethane foam products generates large amounts of waste, which in turn has detrimental effects on the surroundings. Hence, finding an economical and environmentally friendly way to dispose of or recycle foam waste is an utmost priority for researchers to overcome this problem. In that sense, the glycolysis of waste flexible polyurethane foam (WFPF) from automotive seat cushions using different industrial-grade glycols and potassium hydroxide as a catalyst to produce recovered polyol was investigated. The effect of different molecular weight polyols, catalyst concentration, and material ratio (PU foam: Glycols) on the reaction conversion and viscosity of the recovered polyols was determined. The obtained recovered polyols are obtained as single or split-phase reaction products. Besides, the foaming characteristics and physical properties such as cell morphology, thermal stability, and compressive stress-strain nature of the regenerated flexible foams based on the recovered polyols were discussed. It was observed that the regenerated flexible foams displayed good seating comfort properties as a function of hardness, sag factor, and hysteresis loss compared to the reference virgin foam. With the growing demand for a sustainable and circular economy, a global valorization of glycolysis products from polyurethane scraps can be realized by transforming them into profitable substances.

• Nuclear Engineering and Technology
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• 제21권4호
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• pp.259-266
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• 1989

LOFT L2-5 대형 냉각재상실사고 모사실험에 대해 RELAP5/MOD2/Cycle 36.04로부터 개선된 코드를 이용, 코드평가를 수행하였다. 강수관(Downcomer)모델 및 노심유로모델에 따른 코드 민감도분석을 위해 보충계산을 수행하였다. 계산결과는 1차계통의 압력, 파단부를 통과하는 질량유량, 노심 고온부의 피복재 온도등에 대해서 실험결과와 비교 분석되었다. 분석결과 RELAP5/MOD2 계산에 의해 1차계통의 수력학적 거동은 잘 묘사될 수 있으며, 단일 노심유로 모델을 이용한 계산에서는 사고발생이후 감압기간동안 노심이 과대 냉각되는 현상이 발견되었다. 노심의 고온유로에서의 수력학적 거동을 잘 묘사할 수 있는 이중 노심유로 모델계산을 이용하여 이 현상을 극복하고 실험치에 근사하는 결과를 얻을 수 있음을 알 수 있었다.

• Nuclear Engineering and Technology
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• 제54권11호
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• pp.4329-4337
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• 2022

Jet impinging device is designed for decay heat removal on horizontal fuel rods in a low temperature heating reactor. An experimental system with a fuel rod simulator is established and experiments are performed to evaluate water film covering capacity, within 0.0287-0.0444 kg/ms mass flow rate, 0-164.1 kW/m² heating flux and 13.8-91.4℃ feeding water temperature. An effective method to obtain the film coverage rate by infrared equipment is proposed. Water film flowing patterns are recoded and the film coverage rates at different circumference angles are measured. It is found the film coverage rate decreases with heating flux during single-phase convection, while increases after onset of nucleate boiling. Besides, film coverage rate is found affected by Marangoni effect and film accelerating effect, and surface wetting is significantly facilitated by bubble behavior. Based on the observed phenomenon and physical mechanism, dry-out depth and initial dry-out rate are proposed to evaluate film covering potential on a heating surface. A model to predict film coverage rate is proposed based on the data. The findings would have reliable guide and important implications for further evaluation and design of decay heat removal system of new reactors, and could be helpful for passive containment cooling research.

• 천문학회보
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• 제46권1호
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• pp.55.2-56
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• 2021

The progenitor of Type Ia supernovae (SNe Ia) is mainly believed to be a close binary system of acarbon-oxygen white dwarf (CO WD) and non-degenerate companion (single degenerate) or another WD (double degenerate). However, it is unclear which system is more prevalent. Here, we present a high cadence optical/Near-IR light curve of normal but slightly faint type Ia SN 2019ein from IMSNG project. We fit the early light curve (t <+8.3 days from the first detection) with various models to find the shock-heated cooling emission from SN ejecta-companion interaction. No significant shock-heated cooling emission is found, from which we constrain the progenitor star size as the following. The upper limit (R_upper,*) of the companion size in R-band is ~0.2R_⊙ when forcing the first light time (t_fl) to have one value and ~0.9R_⊙ when using the mean value of tfl from the fitting in each band. Assuming the source of the I-band curve is almost powered from the radioactive decay, we obtained R_upper,*~1.2R_⊙. The early B-V color curve is in agreement with the model color curve of the 2M_⊙ main sequence companion. These results allow us to at least rule out large stars like red giants as a companion star of the binary progenitor system of this supernova. B-R and V-R color do not show any significant signs of a red bump, which shows a thin helium shell (MHe<0.1M_⊙) for the sub-Mch WD (double detonation model). In addition, we estimated the distance to NGC 5353 as 37.098±0.028Mpc.