• 제목/요약/키워드: Single walled carbon nanotube (SWNT)

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탄소나노튜브와 바인더의 상호작용이 탄소나노튜브/바인더 박막의 정전기적 특성에 미치는 영향 (Effect of intermolecular interactions between CNTs and silane binders on the opto-electrical properties of SWNT/silane binder films)

  • 한중탁;김선영;정희진;정승열;이건웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.97-98
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    • 2009
  • Here, we describe a versatile strategy for precise control of the optoelectrical properties of the single walled carbon nanotube (SWNT)/silane binder hybrid films by noncovalent hybridization. Stable SWNT/silane binder solutions were prepared by direct mixing of high concentration CNT solutions and silane sol solutions. The critical binder content was determined by varying the amount of binder in the SWNT/binder solutions. A binder content of 50 wt% was used to prepare the other SWNT/binder solutions. This study demonstrates how the intermolecular interactions between the SWNTs and the silanes can affect the conductivity of the CNT/binder network films by characterizing the optoelectrical and Raman spectroscopic properties of the SWNT/silane films containing silane binders with various functional groups. The use of the PTMS binder with phenyl groups was found to be most effective in the fabrication of transparent and conductive films on glass substrates. Such a precise control of the optoelectrical properties of SWNT/binder films can be useful to fabricate the high performance conductive thin films, with ramifications for understanding the fundamental intermolecular interaction in carbon materials science.

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PEDOT:PSS/Single Wall Carbon Nanotube Composite Nanoparticles as an Additive for Electric-double Layer Capacitor

  • Park, Jong Hyeok;Lee, Sang Young;Kim, Jong Hun;Ahn, Sunho
    • Journal of Electrochemical Science and Technology
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    • 제3권3호
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    • pp.143-148
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    • 2012
  • The unique effects of highly conductive conducting polymer/SWNT (single walled carbon nanotube) composite nanoparticles in electric double layer capacitors are studied for the enhancement of the adhesive properties, specific capacitance and power characteristics of the electrode. Because the conducting polymer/SWNT composite material, which is believed to act as a polymer binder, an active material for charge storage and a conducting agent, is well distributed on the activated carbon, greatly enhanced adhesion properties, cell capacitance and power characteristics were obtained.

SWCNTs 용액 속의 바인더로 인한 가스센서의 가스 선택성의 효과 (The Effect on the Gas Selectivity of Gas Sensors by Binder in SWNTs Solution)

  • 이호중;감병민;김성진;한중탁;이건웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.103-105
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    • 2009
  • 본 연구에서 우리는 single walled carbon nanotube(SWNT) 용액 속의 TEOS와 VTMS 바인더가 나노튜브 센서의 감도의 증가와 선택성을 가지는 것에 대해서 조사하였다. 일반적으로 혼합된 SWNT 용액 속의 유기 화합물인 바인더는 기판에 잘 부착된다. 그리고 가수분해 된 바인더의 표면에는 바인더가 경화 되었을 때 기능화 된 하나의 그룹이 형성된다. 그것은 SWNT의 표면에 가수분해 된 TEOS와 VTMS의 -OH와 $-CH=CH_2$ 같이 기능화된 그룹이다. 그러므로 전하는 carbon nanotube와 흡착된 분자 사이에서 이동되고 그에 대한 영향으로 전기적인 전도성이 변화한다. 이 실험에서 증가되어지는 알콜 농도에 따라 TEOS 바인더를 사용한 센서의 저항은 감소하는 반면 VTMS 바인더를 사용한 센서의 저항은 증가한다.

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탄소나노튜브 작동기의 이론적 해석 (Theoretical Analysis of Carbon Nanotube Actuators)

  • 박철휴;박현철;소현기;정봉부
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.927-931
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    • 2005
  • Carbon nanotube actuator, working under physical conditions (in aqueous solution) and converting electrical energy into mechanical energy directly, can be a good substitute for artificial muscle. The carbon nanotube actuator simulated in this paper is an isotropic cantilever type with an adhesive tape which is sandwiched between two single-walled carbon nanotubes. For predicting the static and dynamic characteristic parameters, the analytical model for a 3 layer bimorph carbon nanotube actuator is developed by using Euler-Bernoulli beam theory. The governing equation and boundary conditions are derived from energy principles. The induced displacements of the theoretical model are presented in order to investigate the performance of the carbon nanotube actuator with different control voltages. The developed model presents invaluable means for designing and predicting the performance of carbon nanotube actuator that can be used in artificial muscle applications.

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Analysis of Sensing Mechanisms in a Gold-Decorated SWNT Network DNA Biosensor

  • Ahn, Jinhong;Kim, Seok Hyang;Lim, Jaeheung;Ko, Jung Woo;Park, Chan Hyeong;Park, Young June
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제14권2호
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    • pp.153-162
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    • 2014
  • We show that carbon nanotube sensors with gold particles on the single-walled carbon nanotube (SWNT) network operate as Schottky barrier transistors, in which transistor action occurs primarily by varying the resistance of Au-SWNT junction rather than the channel conductance modulation. Transistor characteristics are calculated for the statistically simplified geometries, and the sensing mechanisms are analyzed by comparing the simulation results of the MOSFET model and Schottky junction model with the experimental data. We demonstrated that the semiconductor MOSFET effect cannot explain the experimental phenomena such as the very low limit of detection (LOD) and the logarithmic dependence of sensitivity to the DNA concentration. By building an asymmetric concentric-electrode model which consists of serially-connected segments of CNTFETs and Schottky diodes, we found that for a proper explanation of the experimental data, the work function shifts should be ~ 0.1 eV for 100 pM DNA concentration and ~ 0.4 eV for $100{\mu}M$.

가스절연기기의 부분방전검출을 위한 SWNT-UHF 융합센서 (SWNT-UHF Fusion Sensor for GIS Partial Discharge Detection)

  • 이상욱;장용무;백승현;이종철
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.120-120
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    • 2010
  • To detect the PD events, we have studied a fusion sensor, the UHF sensor and the single-walled carbon nanotube(SWNT) gas sensor. We are accustomed to the UHF sensor which have employed to detect the partial discharges in apparatus GIS-like. But the SWNT gas sense is a newly way proposed to detect the partial discharges. In this study, we monitored not only the changes of the electrical conductance of the SWNT sensors in responding to the PD events but also the signal of the UHF sensor at the same time with IEC 60270 standard method for reference on the partial discharge events.

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열처리를 통한 금 나노입자의 크기 제어와 일벽 탄소나노튜브의 합성 촉매로의 이용 (Size Control of Gold Nanoparticles by Heat Treatment and Its Use as a Catalyst for Single-Walled Carbon Nanotube Growth)

  • 이승환;정구환
    • 한국재료학회지
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    • 제23권12호
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    • pp.737-744
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    • 2013
  • We demonstrated size control of Au nanoparticles by heat treatment and their use as a catalyst for single-walled carbon nanotube (SWNTs) growth with narrow size distribution. We used uniformly sized Au nanoparticles from commercial Au colloid, and intentionally decreased their size through heat treatment at 800 oC under atmospheric Ar ambient. ST-cut quartz wafers were used as growth substrates to achieve parallel alignment of the SWNTs and to investigate the size relationship between Au nanoparticles and SWNTs. After the SWNTs were grown via chemical vapor deposition using methane gas, it was found that a high degree of horizontal alignment can be obtained when the particle density is low enough to produce individual SWNTs. The diameter of the Au nanoparticles gradually decreased from 3.8 to 2.9 nm, and the mean diameter of the SWNTs also changed from 1.6 to 1.2 nm for without and 60 min heat treatment, respectively. Raman results reconfirmed that the prolonged heat treatment of nanoparticles yields thinner tubes with narrower size distribution. This work demonstrated that heat treatment can be a straightforward and reliable method to control the size of catalytic nanoparticles and SWNT diameter.

외부 자기장내의 반도체 CNT의 온도의존 조사 (Investigation of Temperature Dependence for CNT Semiconductor in External Magnetic Field)

  • 박정일;이행기
    • 한국자기학회지
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    • 제22권3호
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    • pp.73-78
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    • 2012
  • 본 연구에서는 Argyres-Sigel의 투영 연산자 방법을 단일 벽 탄소 나노튜브(SWNT)의 zigzag(10,0)에 직접 적용하여 이를 운동방정식의 형태로 만들어 선모양 함수를 구하는 방법을 사용하였다. 선모양 함수의 실수 부분인 선 너비는 저온 영역(T < 200K)에서 온도의 영향에 거의 무관한 것으로 조사되었다. 이는 온도에 관여하는 페르미-디랙 분포함수가 선모양 함수에 거의 영향을 작용하지 않기 때문인 것으로 생각된다. 고온 영역(T > 200K)에서는 선 너비가 다소 단조롭게 증가하는 것으로 나타났으며, 이는 음향 포논의 영향에 기인하는 것으로 보인다. 그리고 SWNT의 전자스핀이완 시간은 $1.4{\times}10^{-6}\;s$으로 계산되었다.

Nonlinear dynamics of SWNT reinforced Aluminium alloy beam

  • Abdellatif Selmi;Samy Antit
    • Steel and Composite Structures
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    • 제51권4호
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    • pp.407-416
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    • 2024
  • The main objective of the present paper is to investigate the nonlinear vibration of buckled beams fixed at both ends and made of Aluminium allay (Al-alloy) reinforced with randomly dispersed Single Walled Carbon Nanotube (SWNT). The Mori-Tanak (M-T) micromechanical approach is selected to predict the homogenized material properties of the beams. The differential equation of motion governing the nonlinear behavior of the Euler-Bernoulli homogeneous beam is solved using an analytical method. The influences of diverse parameters including axial load, vibration amplitude, SWNT volume fraction, SWNT aspect ratio and beam slenderness ratio on the nonlinear frequency are studied.