• 한국표면공학회지
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• 제42권1호
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• pp.47-52
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• 2009

Cu-Ag powder having Core-Shell structure was prepared from by electroless plating method using agents such as $AgNO_3$, $NH_{4}OH$, Hydroquinone. Ag coated copper powders were analyzed using scanning electron microscopy(SEM) and energy dispersive X-ray spectrometer(EDX). The silver coating layer of copper powder was affected from various reaction conditions such as molar ratio of $NH_{4}OH$, $AgNO_3$, and pulp density. Free silver was generated below 0.1M or 0.3M and above of $NH_{4}OH$ mole ratio. Silver coating layer thickened as addition of $AgNO_3$. When the pulp density reached 12% with 0.2M $NH_{4}OH$, and 0.15M $AgNO_3$ at $4^{\circ}C$, silver was homogeneously distributed around the copper particles and free silver particles were not generated.

• 마이크로전자및패키징학회지
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• 제23권4호
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• pp.93-99
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• 2016

본 논문에서는 AgNW 필름의 기계적 전기적 신뢰성을 연구하였다. 특히 전류가 흐르는 상태에서 굽힘 변형이 발생하였을 때의 AgNW 필름의 내구성 및 신뢰성을 연구하였다. AgNW 필름의 전압 및 전류 시험을 수행하여, AgNW에서 발생하는 발열과 전류 밀도의 변화를 관찰함으로써 AgNW의 전기적 내구성을 평가하였다. AgNW는 곡률반경 2 mm까지 굽힐 수 있었으며, 200,000회의 굽힘 반복시험에도 높은 신뢰성 및 유연성을 보여주었다. 또한 over-coating 막은 AgNW 필름의 내구성을 향상시키는 효과가 있음을 확인하였다. Over-coating이 없는 AgNW 필름의 경우, AgNW 표면에서 국부적인 발열을 보인 반면에 over-coating이 된 AgNW 필름의 경우 균일하게 발열되어 over-coating막이 AgNW 필름의 내구성을 향상시킴을 알 수 있었다. 전류를 인가한 상태에서의 굽힘 시험을 수행한 결과 굽힘 반복시험에서는 전류밀도가 지속적으로 감소하여 시험 후, 52.4%의 전류밀도 감소를 보였다. 전류가 인가된 상태에서 AgNW의 굽힘 변형이 지속되면 AgNW들의 인장, 굽힘 및 sliding 등의 기계적인 변형에 의하여 AgNW network 구조의 변형이 발생하거나, 혹은 개별 AgNW의 접촉 접합부들이 떨어지면서 접촉저항이 증가하여 주울 열에 의하여 파괴가 발생한다. 또한 over-coating막의 적용은 AgNW 필름의 전기적 신뢰성을 향상시킬 수 있음을 알 수 있었다.

• 한국표면공학회지
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• 제53권4호
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• pp.182-189
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• 2020

Indium tin oxide (ITO) used a transparent electrode of a photoelectric device has a low sheet resistance and a high transmittance. However, ITO is disadvantageous in that the process cost is expensive, and the process time is long. Silver nanowires (AgNWs) transparent electrodes are based on a low cost solution process. In addition, it has attracted attention as a next-generation transparent electrode material that replaces ITO because it has similar electrical and optical characteristic to ITO, it is noted as a. AgNW thin films are mainly produced by spin-coating. However, the spin-coating process has a disadvantage of high material loss. In this study, the material loss was reduced by using about 2~10 ㎕ of AgNW solution on a (25 × 25) ㎟ substrate using the shear-coating method. It was also possible to align AgNWs in the drag direction by dragging the meniscus of the solution. The electro-optical properties of the AgNW thin film were adjusted by changing the experimental parameters that the amount of AgNWs suspension, the gap between the substrate and the blade, and the coating speed. As a result, AgNW thin films with a transmittance of 90.7 % at a wavelength of 550 nm and a sheet resistance of 15 Ω/□ was deposited and exhibited similar properties to similar AgNW transparent electrodes studied by other researchers.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1998년도 제27회 춘계학술대회
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• pp.47-54
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• 1998

An experimental study was performed to discover the effect of environmental conditions on the rolling resistance behavior of pure silver and lead coated 52100 bearing steel. Pure silver and lead coating were produced by a thermal evaporation coating method. Experiments using a thrust ball bearing-typed rolling test-rig were performed under vacuum, dry air and controlled humidity conditions. Results showed that agglomeration of particles were prevented in vacuum environment and as it showed low and stable rolling resistance by shakedown phenomena. Also, humidity relates closely to the agglomeration of particles and increased the rolling resistance after the failure of coated layer.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2009년 추계학술발표대회
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• pp.217-220
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• 2009

Conductive adhesives have been investigated for use in microelectronics packaging as a lead-free solder substitute due to their advantages, such as low bonding temperature. However, high resistivity and poor mechanical behavior may be the limiting factors for the development of conductive adhesives. The metal fillers and the polymer resins provide electrical and mechanical interconnections between surface mount device components and a substrate. As metal fillers used in conductive adhesives, silver is the most commonly used due to its high conductivity and the stability. However the cost of conductive adhesives with silver fillers is much higher than usual lead-free solders and silver has poor electro-migration performance. So, copper can be a promising candidate for conductive filler metal due to its low resistivity and low cost, but oxidation causes this metal to lose its conductivity. In this study, electrically conductive adhesives (ECAs) using surface modified copper fillers were developed. Especially, in order to overcome the problem associated with the oxidation of copper, copper particles were coated with silver, and the silver-coated copper was tested as a filler metal. Especially the effect of silver coating on the electrical resistance just after curing and after aging was investigated. As a result, it was found that the electrical resistance of ECA with silver-coated copper filler was clearly lower and more stable than that of ECA with pure copper filler after curing process. And, during high temperature storage test, the degradation rate of electrical resistance for ECA with silver coated copper filler was quite slower than that for ECA with pure copper filler.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2009년도 Korea Superconductivity Society Meeting 2009
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• pp.94-94
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• 2009

• Molecular & Cellular Toxicology
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• 제5권1호
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• pp.23-31
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• 2009

To compare the effects of nanometer-sized silver ions and support materials (nano-silver coating material, NM-silver) and silver ions, we exposed zebrafish embryos to both types of nano-silver ions and compared the acute responses during embryogenesis. The amount of silver in the NM-silver (17.16%) was greater than that in the silver ion (4.56%). Both of these materials have different atomic compositions. The silver ion-exposed groups (10 and 20 ppt) showed lower survival rates than the NM-silver-exposed groups (10 and 20 ppt). NM-silver penetrated the skin and blood tube of zebrafish larvae as aggregated particles, whereas, silver ions penetrated the organelles, nucleus and yolk in a spread-out pattern. Micro-array analysis of RNA from zebrafish larvae (72 hours post-fertilization) that were treated with either NM-silver or silver ions, showed alteration in expression of the BMP, activin, TGF-$\beta$, and $GSK3{\beta}$ genes pathway. Additionally, $GSK3{\beta}$ gene pathway for apoptosis that was related with left-right asymmetry. Gene expression changes in the NM-silver or silver ions-treated zebrafish embryo led to phenotypic changes in the hatched larvae, reflecting increased apoptosis and incomplete formation of an axis.

• Tribology and Lubricants
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• 제18권1호
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• pp.1-8
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• 2002

Nano adhesion and friction between a $Si_{3}N_{4}$ AFM(atomic force microscope) tip and thin silver films were experimentally studied. Tests were performed to measure the nano adhesion and friction in both AFM and LFM(lateral force microscope) modes in various range of normal loads. Thin silver films deposited by IBAD (ion beam assisted deposition) on Si-wafer (100) and other Si-wafers of different surface roughness were used. Results showed that nano adhesion and friction decreased with the surface roughness. When the Si surfaces were coated by pure silver, the adhesion and friction decreased. But the adhesion and friction were not affected by the thickness of IBAD silver coating. As the normal force increased, the adhesion forces of bare Si-wafer and IBAD silver coating film remained constant, but the friction forces increased linearly. Test results suggested that the friction was mainly governed by the adhesion as long as the load was low.

• 대한치과보철학회지
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• 제29권3호
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• pp.111-119
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• 1991

This study was performed to investigate the effect of gold electrodepositoin on porcelain color of palladium-silver alloy. The specimens were made by firing porcelain on the metal plates cast respectively in Au-Pt alloy, and Pd-Ag alloy. In the case of Pd-Ag alloy specimens, porcelain were fired under three different conditions of the metal plate: 1) without gold coating, 2) firing opaque beforehand on one side, gold coating on the other side, 3) gold coating on both sides of the metal plate. Color change was measured with fiber-optic colorimeter(Model TC-6FX, Tokyo Denshoku Co., Japan). The obtained results were as follows: 1. In the group of firing opaque beforehand on one side and gold coating on the other side, there was no significant differences in their color in comparison to the color of the control group of the Au-Pt alloys. 2. In the group of gold coating on both sides on metal plate, there were no significant differences except their value to the group of firing poaque beforehand on one side and gold coating on the other side.

• 한국인터넷방송통신학회논문지
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• 제18권4호
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• pp.79-83
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• 2018

EMI 스프레이 코팅막의 차폐효과(Shield Effectiveness, SE)를 측정하기 위한 정확한 방법을 제안하였다. 고주파 시뮬레이션을 한 후에 원형 동축 표준 측정기를 제작하였다. 원형 동축 표준 측정기에 삽입하기 위하여 EMI 스프레이 코팅막의 시료를 가공하였다. 차폐효과 측정을 위한 측정기는 에이질런트 8722ES 벡터 네트워크 분석기를 이용하였다. 이러한 측정기와 측정시료의 구성으로 구리와 은의 혼합 스프레이 코팅 시료의 정확한 차폐효과를 측정하였다. 동박 시료의 차폐효과는 70 dB로 측정되었고, 구리와 은의 혼합 스프레이 코팅 시료의 차폐효과는 60 dB로 측정되었다. 이와 같은 측정 결과로 원형 동축 표준 측정기의 신뢰성을 확인하였다.