• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.216-219
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• 2002

Much quantity of anti-tracking agent, ATH is added to the silicone rubber for the protection of silicone rubber against surface discharge. Hydrophobicity recovery properties of silicone rubber could be different by the content, surface treatment state and particle size of ATH. Because hydrophobicity of silicone rubber is depend much on the surface state of ATH. In this paper, the properties of silicone rubber is investigated according to the addition of different particle size of ATH to the silicone rubber. Hydrophobicity recovery properties and arc resistance of silicone rubber were investigated according to the addition of different particle size of ATH. Hydrophobicity recovery properties of silicone rubber were evaluated by the measurement of contact angle.

• Elastomers and Composites
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• 제44권3호
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• pp.260-268
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• 2009

Clay의 표면을 bis[(3-triethoxysilylpropyl)tetra sulfide (TSS)으로 처리하면 clay 표면의 소수성이 증가 될 뿐만 아니라 high temperature vulcanization 형 silicone rubber(HTV)와 화학적 반응이 가능하기 때문에 clay와 silicone rubber 사이의 상용성이 향상될 수 있을 것으로 예상되어 TSS를 이용하여 Na-MMT와 Fe-MMT의 silicate 층 표면에 tetra sulfide 그룹을 도입시킨 Na-$MMTS_4$와 Fe-$MMTS_4$를 각각 제작하였다. 이들 clay를 HTV silicone rubber와 compounding하여 silicone rubber/clay composites를 제작하였으며, clay의 종류 및 표면개질에 따른 silicone rubber 복합체의 열적안정성 및 기계적 물성을 평가하였다.

• Elastomers and Composites
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• 제32권5호
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• pp.309-317
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• 1997

Estimation of the dielectric properties of insulating silicone rubbers added reinforcing fillers $(SiO_2,\;0{\sim}140phr)$ are very important to investigate the polymer structure. The characteristies of the dielectric absorption in insulating silicone rubbers were studied in the frequency range from 30Hz to 1MHz at the temperature range from $0{\sim}170^{\circ}C$. In the case of non-filled specimen, the dielectric loss is due to the syloxane which is the main chain of silicone rubber at the low temperature below $50^{\circ}C$ and the frequency at 330Hz, and is due to methyl and vinyl radical over the frequency of 1MHz. It is confirmed that the methyl radical or the vinyl radical becomes thermal oxidation at the high temperature over $100^{\circ}C$ and then the dielectric disperssing owing to the carboxyl radical Is appeared. In the case of filled specimen, the dielectric constant is in creased with the additives of reinforcing fillers due to the effect of interfacial polarization explained by MWS(Maxwell-Wagner-Sillars)'s law. The dielectric loss is decreased by the disturbance of reinforcing fillers that is permeated between networks.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권5호
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• pp.302-309
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• 2000

The tracking characteristics of silicone rubber degraded by accelerated outdoor exposure employing a weather-o-meter were investigated. The tracking test was performed according to ICE Publ.587 method but the concentration of conductive solution was two times higher than IEC standard in order to accelerate the tracking failure. The number of large effective scintillation and the current of high voltage circuit were measured simultaneously. It was shown that the number of effective scintillation had valuable information of the tracking degradation state of silicone rubber, while the average current between electrodes could not provide information enough for diagnosis. Based upon the experimental results, it could be said that the key factor accelerating tracking failure was not Joule heating by current but pyrolysis by burning of silicone rubber, and that reduction of contact angle was due to chain scission which resulted in the free radicals of low molecules.

• Elastomers and Composites
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• 제22권1호
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• pp.20-28
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• 1987

The characteristic of the dielectric relaxation in silicone rubbers were studied in the frequency range of $1{\times}10^2{\sim}3{\times}10^6Hz$ at the temperature range of $30^{\circ}{\sim}170^{\circ}C$. As the results of the study, it has been confirmed that the silicone rubber containing the cross-linking agants of 2,5-bis(tert-butylperoxy)-2, 5-dimethyl hexane exhibit the dissipation spectra of two kind(${\alpha},\;{\beta}$ dissipation) due to the siloxane and methyl groups. Particularly, the maximum value of dielectric loss spectra of silicone rubber combinning the cross-linking agents of 0.7phr to 1.0phr are on the increasing in high frequency region, but the specimen of above 1.0phr become smaller again. The energy and the entropy of activation on the molicular motion obtained 18.32 kcal/mole and $1.48ca1/mole{\cdot}deg$ in measuring condition respectively.

• 대한안전경영과학회:학술대회논문집
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• 대한안전경영과학회 2012년 추계학술대회
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• pp.355-368
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• 2012

This paper, the hardness of the silicone rubber wire for 50, 60 degrees, 70 degrees High Temperature Vulcanizing (HTV) method using specimens were fabricated. In this paper, in order to investigate the dielectric properties of silicone rubber for wire specimens, the temperature range of $30^{\circ}C{\sim}170^{\circ}C$, the frequency range from 100Hz~4.5MHz report surveyed about the frequency and temperature dependent properties.

• Elastomers and Composites
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• 제50권3호
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• pp.210-216
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• 2015

Polyurethane modified silicone (PUMS) was synthesized from various molecular weights of polydimethylsiloxane (PDMS 2000, PDMS 6000, PDMS 20000), polypropyleneglycol with molecular weight of 3000 g/mol (PPG 3000) and 2,4-toluenediisocyanate (TDI) under tin catalyst. Their structures were confirmed by the measurement of FT-IR and $^1H-NMR$, and the thermal properties were studied from DSC and TGA. Glass transition temperature of PUMS exhibited exothermic peak at $-63{\sim}-69^{\circ}C$, and residual weight was 19~35% at $800^{\circ}C$.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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• pp.227-230
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• 2003

Silicone rubber has very excellent chemical stability and hydrophobicity. A hydrophobic surface can prevent the formation of continuous water films on the surface in wet and heavily contaminated conditions. This phenomenon contributes to the suppression of leakage current and partial discharges on insulator surfaces. Silicone rubber has been used much for housing materials of polymer insulators. ATH is added to the silicone rubber for improvement of its resistance against surface discharge. In this paper, ATH with different particle size and content was added to the silicone rubber during compounding. Silicone rubber was deteriorated by a corona treatment. Hydrophobicity recovery rate after corona treatment and arc resistance of silicone rubber were investigated. Hydrophobicity recovery rate of silicone rubber was evaluated by the measurement of contact angle. Arc resistance was evaluated by measuring weight loss of silicone rubber after arc resistance test. It was observed that the hydrophobicity recovery rate and arc resistance of silicone rubber were different when different particle size and content of ATH were added.

• 한국전기전자재료학회논문지
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• 제19권1호
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• pp.46-51
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• 2006

This paper reports on the effects of silicone oils, used as processing agents, on the recovery of hydrophobicity of silicone rubber. The recovery of hydrophobicity was evaluated by the measuring the contact angle, the surface electrical resistance and SEM. Here, we formed artificial contamination on the surface of samples, which scratched by sand papers and alumina powders. There was small recovery of hydrophobicity on the surface of SIR-A that silicone oil was not added. In both oil-added samples, SIR-B and SIR-C, recovery of hydrophobicity was achieved greatly. The surface of SIR-C showed that a lot of silicone oil was observed due to migration of oil, relatively in comparison with SIR-B. The tendency of recovery of hydrophobicity expressed by contact angle was in a good agreement with electrical property as determined by surface resistivity.

• 한국전기전자재료학회논문지
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• 제24권11호
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• pp.890-894
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• 2011

In this thesis, the silicone filler with a sample size of 0~75 phr and void size of 2~4.5 mm is prepared in order to diagnose the defect of void which exists in widely used insulation material, silicone rubber. In this silicone rubber sample, electrodes are connected and whilst the voltage changes, applied voltage 7 kV~9 kV is increased constantly over time and discharge quantity, discharge frequency and applied voltage (T-QNV) were measured. The discharge quantity of the applied voltage (VQ) is measured to estimate inception voltage and extinction voltage. In addition, under the condition of maintaining constant applied voltage, discharge quantity and discharge frequency (QN) are measured, and its characteristics are analyzed.