• Title/Summary/Keyword: Silicon-Based

Search Result 1,458, Processing Time 0.027 seconds

Preparation of $TiO_2-SiO_2$ by Sol-Gel Method and Their Photocatalytic Activities (졸-겔법에 의한 $TiO_2-SiO_2$합성 및 광촉매활성)

  • 류완호;양천희
    • Journal of the Korean Society of Safety
    • /
    • v.14 no.1
    • /
    • pp.101-107
    • /
    • 1999
  • $TiO_2$ and $xTiO_2-ySiO_2$ system photocatalysts were developed by sol-gel method based on the change of production parameters, and their structure of crystallization and the specific surface area was measured. Considering the efficiency of the ethanol decomposition using the catalyst, the conclusion was made as follows: 1) By means of X-ray analysis of $TiO_2$ powder that is obtained from water and Titanium alkoxide with various molar ratios, it is shown that structure of crystallization is a dominating structure and, on the other hand, the crystallization of rutile also partly exists. The specific surface area is at its maximum value at R=6, which is the molar ratio of water vs. alkoxide, whereas its value goes down as the molar ratio increases. In the reaction of using $TiO_2$ catalyst, the ethanol is decomposed into the extent of 15 ~30% in an hour and three hours are necessitated for 70% decomposition. 2) $TiO_2/SiO_2$ powder is developed from Titanium and Silicon alkoxide by a hetero-condensation process. The increase of SiO$_2$ contents causes the decrease of the degree of crystallization of the gel, whereas the specific surface area preferentially increases. In the decomposition reaction of the ethanol, the decomposition efficiency represents 25~60% in an hour. It is, however, examined that the efficiency inactively increases corresponding to the duration of reaction time. It is shown that more than 90% of ethanol is decomposed when reaction time is about three hours and the efficiency illustrates the maximum value for 60-$TiO_2/4O-SiO_2$ catalyst.

  • PDF

A Study on the Resin Flow through Fibrous Preforms in the Resin Transfer Molding Process (수지이동 성형공정에서 섬유직조망내의 수지유동에 관한 연구)

  • 김성우;이종훈;이미혜;남재도;이기준
    • Composites Research
    • /
    • v.12 no.2
    • /
    • pp.70-81
    • /
    • 1999
  • Resin transfer molding(RTM) as a composite manufacturing process is currently of great interest in the aerospace industry requiring high performance composite parts. In this study, an analysis of mold filling in the RTM process was carried out by numerical simulation using finite element/control volume technique. Experimental work for the visualization of resin flow through fibrous preform was also conducted in order to quantitatively measure the permeabilities of the fiber mats and to evaluate the validity of the developed numerical code. The different types of fiber mats and silicon oils were selected as reinforcements and resin materials, respectively. The effects of fibrous preform structure, mold geometry, and preplaced insert on the flow front patterns during mold filling were examined by integrating the model predictions and experimental results. The flow fronts predicted by numerical simulation were in good agreement with those observed experimentally. However, according to the regions of the mold, some deviations between predicted and observed flow fronts could be found because of non-uniform fiber volume fraction. Weldline locations for the resin flow through round insert preplaced in the mold could be qualitatively deduced based on predicted flow fronts.

  • PDF

Review of Injection-Locked Oscillators

  • Choo, Min-Seong;Jeong, Deog-Kyoon
    • Journal of Semiconductor Engineering
    • /
    • v.1 no.1
    • /
    • pp.1-12
    • /
    • 2020
  • Handling precise timing in high-speed transceivers has always been a primary design target to achieve better performance. Many different approaches have been tried, and one of those is utilizing the beneficial nature of injection locking. Though the phenomenon was not intended for building integrated circuits at first, its coupling effect between neighboring oscillators has been utilized deliberately. Consequently, the dynamics of the injection-locked oscillator (ILO) have been explored, starting from R. Adler. As many aspects of the ILO were revealed, further studies followed to utilize the technique in practice, suggesting alternatives to the conventional frequency syntheses, which tend to be complicated and expensive. In this review, the historical analysis techniques from R. Adler are studied for better comprehension with proper notation of the variables, resulting in numerical results. In addition, how the timing jitter or phase noise in the ILO is attenuated from noise sources is presented in contrast to the clock generators based on the phase-locked loop (PLL). Although the ILO is very promising with higher cost effectiveness and better noise immunity than other schemes, unless correctly controlled or tuned, the promises above might not be realized. In order to present the favorable conditions, several strategies have been explored in diverse applications like frequency multiplication, data recovery, frequency division, clock distribution, etc. This paper reviews those research results for clock multiplication and data recovery in detail with their advantages and disadvantages they are referring to. Through this review, the readers will hopefully grasp the overall insight of the ILO, as well as its practical issues, in order to incorporate it on silicon successfully.

Micro Sensor Away and its Application to Recognizing Explosive Gases (마이크로 센서 어레이 제작 및 폭발성 가스 인식으로의 응용)

  • 이대식;이덕동
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.40 no.1
    • /
    • pp.11-19
    • /
    • 2003
  • A micro sensor array with 4 discrete sensors integrated on a microhotplate was developed for identifying the kinds and quantities of explosive gases. The sensor array consisited of four tin oxide-based thin films with the high and broad sensitivity to the tested explosive gases and uniform thermal distribution on the plate. The microhotplate, using silicon substrate with N/O/N membrane, dangling in air by Al bonding wires, and controlling the thickness by chemical mechanical process (CMP), has been designed and fabricated. By employing the sensitivity signal of the sensor array at 40$0^{\circ}C$, we could reliably classily the kinds and quantities of the explosive gases like butan, propane, LPG, and carbon monoxide within the range of threshold limit values (TLVs), employing principal component analysis (PCA).

Analysis of Random Variations and Variation-Robust Advanced Device Structures

  • Nam, Hyohyun;Lee, Gyo Sub;Lee, Hyunjae;Park, In Jun;Shin, Changhwan
    • JSTS:Journal of Semiconductor Technology and Science
    • /
    • v.14 no.1
    • /
    • pp.8-22
    • /
    • 2014
  • In the past few decades, CMOS logic technologies and devices have been successfully developed with the steady miniaturization of the feature size. At the sub-30-nm CMOS technology nodes, one of the main hurdles for continuously and successfully scaling down CMOS devices is the parametric failure caused by random variations such as line edge roughness (LER), random dopant fluctuation (RDF), and work-function variation (WFV). The characteristics of each random variation source and its effect on advanced device structures such as multigate and ultra-thin-body devices (vs. conventional planar bulk MOSFET) are discussed in detail. Further, suggested are suppression methods for the LER-, RDF-, and WFV-induced threshold voltage (VTH) variations in advanced CMOS logic technologies including the double-patterning and double-etching (2P2E) technique and in advanced device structures including the fully depleted silicon-on-insulator (FD-SOI) MOSFET and FinFET/tri-gate MOSFET at the sub-30-nm nodes. The segmented-channel MOSFET (SegFET) and junctionless transistor (JLT) that can suppress the random variations and the SegFET-/JLT-based static random access memory (SRAM) cell that enhance the read and write margins at a time, though generally with a trade-off between the read and the write margins, are introduced.

Inversion Barriers of Methylsilole and Methylgermole Monoanions

  • Pak, Youngshang;Ko, Young Chun;Sohn, Honglae
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.12
    • /
    • pp.4161-4164
    • /
    • 2012
  • Density functional MO calculations for the methylsilole anion of $[C_4H_4SiMe]^-$ and methylgermole anion of $[C_4H_4SiMe]^-$ at the B3LYP (full)/6-311+$G^*$ level (GAUSSIAN 94) were carried out and characterized by frequency analysis. The ground state structure for the methylsilole anion and methylgermole anion is that the methyl group is pyramidalized with highly localized structure. The difference between the calculated $C_{\alpha}-C_{\beta}$ and $C_{\beta}-C_{\beta}$ distances are 9.4 and 11.5 pm, respectively. The E-Me vector forms an angle of $67.9^{\circ}$ and $78.2^{\circ}$ with the $C_4E$ plane, respectively. The optimized structures of the saddle point state for the methylsilole anion and methylgermole anion have been also found as a planar with highly delocalized structure. The optimized $C_{\alpha}-C_{\beta}$ and $C_{\beta}-C_{\beta}$ distances are nearly equal for both cases. The methyl group is located in the plane of $C_4E$ ring and the angle between the E-Me vector and the $C_4E$ plane for the methylsilole anion and methylgermole anion is $2.0^{\circ}$ and $2.3^{\circ}$, respectively. The energy difference between the ground state structure and the transition state structure is only 5.1 kcal $mol^{-1}$ for the methylsilole anion. However, the energy difference of the methylgermole anion is 14.9 kcal $mol^{-1}$, which is much higher than that for the corresponding methylsilole monoanion by 9.8 kcal $mol^{-1}$. Based on MO calculations, we suggest that the head-to-tail dimer compound, 4, result from [2+2] cycloaddition of silicon-carbon double bond character in the highly delocalized transition state of 1. However, the inversion barrier for the methylgermole anion is too high to dimerize.

Effect of Sintering Additives and Sintering Temperature on Mechanical Properties of the $Si_3N_4$ Composites Containing Aligned $\beta-Si_3N_4$ Whisker (배향된 $\beta-Si_3N_4$ Whisker를 함유하는 $Si_3N_4$ 복합체의 기계적 특성에 미치는 소결조제와 소결온도의 영향)

  • Kim, Chang-Won;Choi, Myoung-Jae;Park, Chan;Park, Dong-Soo
    • Journal of the Korean Ceramic Society
    • /
    • v.37 no.1
    • /
    • pp.21-25
    • /
    • 2000
  • Gas pressure sintered silicon nitride based composites with 5 wt% $\beta$-Si3N4 whiskers were prepared, and the variations depending on sintering additives and sintering temperature were studied. Sintering additives were 6 wt% Y2O3-1 wt% MgO(6Y1M), 6 wt%Y2O3-1 wt% Al2O3(6Y1A), 6 wt% Y2O3-1 wt% SiO2(6Y1S), and whiskers were unidirectionally oriented by a modified tape casting technique. Samples were fully densified by gas pressure sintering at 2148 K and 2273 K. As the sintering temperature increased, the size of large elongated grains was increased. Three point flexural strength of 6Y1M and 6Y1M samples was higher than that of 6Y1S sample, and the strength decreased as the sintering temperature increased. The indentation crack length became shorter for the sample sintered at higher temperature, and the difference between the cracks length parallel to and normal to the direction of whisker alignment was decreased. In case of cracks 45$^{\circ}$off the whisker alignment direction, the crack length anisotropy disappeared.

  • PDF

Evaluation of a FPGA controlled distributed PV system under partial shading condition

  • Chao, Ru-Min;Ko, Shih-Hung;Chen, Po-Lung
    • Advances in Energy Research
    • /
    • v.1 no.2
    • /
    • pp.97-106
    • /
    • 2013
  • This study designs and tests a photovoltaic system with distributed maximum power point tracking (DMPPT) methodology using a field programmable gate array (FPGA) controller. Each solar panel in the distributed PV system is equipped with a newly designed DC/DC converter and the panel's voltage output is regulated by a FPGA controller using PI control. Power from each solar panel on the system is optimized by another controller where the quadratic maximization MPPT algorithm is used to ensure the panel's output power is always maximized. Experiments are carried out at atmospheric insolation with partial shading conditions using 4 amorphous silicon thin film solar panels of 2 different grades fabricated by Chi-Mei Energy. It is found that distributed MPPT requires only 100ms to find the maximum power point of the system. Compared with the traditional centralized PV (CPV) system, the distributed PV (DPV) system harvests more than 4% of solar energy in atmospheric weather condition, and 22% in average under 19% partial shading of one solar panel in the system. Test results for a 1.84 kW rated system composed by 8 poly-Si PV panels using another DC/DC converter design also confirm that the proposed system can be easily implemented into a larger PV power system. Additionally, the use of NI sbRIO-9642 FPGA-based controller is capable of controlling over 16 sets of PV modules, and a number of controllers can cooperate via the network if needed.

A Study on Energy Savings in a Network Interface Card Based on Optimization of Interrupt Coalescing (인터럽트 병합 최적화를 통한 네트워크 장치 에너지 절감 방법 연구)

  • Lee, Jaeyoul;Han, Jaeil;Kim, Young Man
    • Journal of Information Technology Services
    • /
    • v.14 no.3
    • /
    • pp.183-196
    • /
    • 2015
  • The concept of energy-efficient networking has begun to spread in the past few years, gaining increasing popularity. A common opinion among networking researchers is that the sole introduction of low consumption silicon technologies may not be enough to effectively curb energy requirements. Thus, for disruptively boosting the network energy efficiency, these hardware enhancements must be integrated with ad-hoc mechanisms that explicitly manage energy saving, by exploiting network-specific features. The IEEE 802.3az Energy Efficient Ethernet (EEE) standard is one of such efforts. EEE introduces a low power mode for the most common Ethernet physical layer standards and is expected to provide large energy savings. However, it has been shown that EEE may not achieve good energy efficiency because mode transition overheads can be significant, leading to almost full energy consumption even at low utilization levels. Coalescing techniques such as packet coalescing and interrupt coalescing were proposed to improve energy efficiency of EEE, but their implementations typically adopt a simple policy that employs a few fixed values for coalescing parameters, thus it is difficult to achieve optimal energy efficiency. The paper proposes adaptive interrupt coalescing (AIC) that adopts an optimal policy that could not only improve energy efficiency but support performance. AIC has been implemented at the sender side with the Intel 82579 network interface card (NIC) and e1000e Linux device driver. The experiments were performed at 100 M bps transfer rate and show that energy efficiency of AIC is improved in most cases despite performance consideration and in the best case can be improved up to 37% compared to that of conventional interrupt coalescing techniques.

A new cleaning concept for display process with electrolyzed anode water (전해 양극수를 이용한 디스플레이 신 세정 공정)

  • Choi Minki;Cha Jiyung;Kim Younggeun;Ryoo Kunkul
    • Proceedings of the KAIS Fall Conference
    • /
    • 2004.11a
    • /
    • pp.99-102
    • /
    • 2004
  • Display process has adopted RCA clean, being applied to large area and coped with environmental issue for last ten years. However, the approaching concept of ozonized, hydrogenised, or electrolyzed water cleaning technologies is within RCA clean paradigm. In this work, only electrolyzed anode water was applied to clean particles and organics as well as metals based on Pourbaix concept, and as a test vehicle, MgO particles were introduced to prove the new concept. The electrolyzed anode water is very oxidative with high oxidation reduction potential(ORP) and low in pH of more than 900mV and 3.1, respectively. MgO particles were immerged in the anode water and its weight losses due to dissolution were measured with time. Weight losses were in the ranges of 100 to 500 micrograms in 250m1 anode waters depending on their ORP and pH. Therefore it was concluded that the cleaning radicals in the anode water was at least in the range of 1 to 5E20 ea per 250 ml anode water equivalent to IE18 ea/cm3. Hence it can be assumed that the anode water be applied to display cleaning since 1E10 to IE15 ea/cm3 ranges of contaminants are being treated. In addition, it was observed that anode water does not develop micro-roughness on hydrophobic surface while it does on the native silicon oxide.

  • PDF