• Title/Summary/Keyword: Silicon powder

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A study on the Polymer surface treatment of GF-filter bag for collection of fine Particle like carbon black (카본블랙류 미세입자 포집을 위한 유리섬유 필터백의 고분자 표면처리에 관한 연구)

  • Lee, B.;Choi, H.L.;Moon, C.K.
    • Journal of Power System Engineering
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    • v.12 no.3
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    • pp.55-59
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    • 2008
  • In this paper, we have investigated on collection efficiency of fine particle of glass fiber-filter bag according to the surface treatment. The solution consisted of polytetrafluoroethylene(teflon), graphite powder, silicon resin and water was used as a basic surface treatment agent. Tensile strength of glass filter-bag increased with up to 3hrs and then decreased with surface treatment time. Tensile strength and initial modulus of the glass fiber-filter bag treated by iodine after basic surface treatment for 3hrs were lower than those of basic surface treatment for 3hrs, however collection efficiency and fracture strain were higher than those of basic surface treatment for 3hrs. Glass fiber-filter bag with lower initial modulus and more strain will be extend the durable period and the one treated by iodine after basic surface treatment 3or 3hrs is expected high collection efficiency of fine particle. This method makes it possible to manufacture glass fiber-filter bag of the optimum condition.

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A Study on the Diamond Synthesis by MPECVD using $CO-H_2$ Mixture ($CO-H_2$ 혼합 기체의 MPECVD 에 의한 다이아몬드 합성에 관한 연구)

  • Ku, Ja-Chun;Oh, Jeong-Seob;Hwang, Ki-Woong
    • Proceedings of the KIEE Conference
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    • 1989.07a
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    • pp.390-393
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    • 1989
  • Diamond is synthesized from the gaseous mixture of carbon monoxide and hydrogen by microwave PECVD. $10{\times}10mm^2$ silicon wafers are used as the substrate,and it can be raised more than $900^{\circ}C$ by microwave absorption, radiation by plasma and bombardment of ions. The changes of the morphology and the growth rates of the deposits with the experimental conditions are examined by Scanning Electron Microscopy. The d values of all the deposited films concide with those of powder diffraction data in XRD. In Raman spectra, the peak of the deposit coincides with that of the natural diamond which has a value of 1332.5 $cm^{-1}$, and the broad peak from 1360 $cm^{-1}$to 1600 $cm^{-1}$which represents the amorphous graphite was observed in the higher concentration of carbon monoxide.

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Prevention of Grain Growth during the Liquid-Phase Assisted Sintering of β-SiC (액상소결 시의 β-SiC의 입자성장 방지)

  • Gil, Gun-Young;Noviyanto, Alfian;Han, Young-Hwan;Yoon, Dang-Hyok
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.485-490
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    • 2010
  • In our previous studies, continuous SiC fiber-reinforced SiC-matrix composites ($SiC_f$/SiC) had been fabricated by two different slurry infiltration methods: vacuum infiltration and electrophoretic deposition (EPD). 12 wt% of $Al_2O_3-Y_2O_3$-MgO with respect to SiC powder was used as additives for liquid-phase assisted sintering. After hot pressing at $1750^{\circ}C$ under 20 MPa for 2 h in Ar atmosphere, a high composite density could be achieved for both cases, whereas the problems such as large grain size and non-uniform distribution of liquid phase were observed, which was resulted in the relatively poor mechanical properties of composites. Therefore, efforts have been made to reduce the grain growth during the sintering, including the optimization for hot pressing condition and utilization of spark plasma sintering using a SiC monolith. Based on the results, spark plasma sintering was found to be effective method in decreasing the amount of sintering additive, time and grain growth, which will be explained in comparison to the results of hot pressing in this paper.

Effect of $Al_2O_3$ and $Fe_2O_3$ Tribological Properties of Reaction Bonded SiC (반응 소결 SiC 소결체의 마찰마모특성에 미치는 첨가제 $Al_2O_3$$Fe_2O_3$ 의 영향)

  • 백용혁;박홍균
    • Journal of the Korean Ceramic Society
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    • v.31 no.9
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    • pp.1069-1075
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    • 1994
  • When ceramics are used as the parts of an engine and a machine, the tribological properties are very important. For the preparation of the resistance material for wear applications by the method of Reaction-Bonded Sintering, metal silicon and carbon black are mixed up into SiC powder, and Al2O3 and Fe2O3 are put as an additive. As the general properties, the bending strength and water absortion are measured in the normal temperature and the phase changies are investigated with XRD. The property of the resistance for wear applications is measured with the amount of friction and wear, friction coefficient and maximum asperties. And, the surface of wear is observed with SEM. With the results of this study, the optimal mol ratio of Si : C and the suitable quantity of the mixture of SiC are 7 : 3 and 40 wt%, respectively. In the case of the addition of Al2O3 (2 wt%), the resistance for friction and wear applications is prominent. The bending strength showed the highest peak when Al2O3 (4 wt%) and Fe2O3 (4 wt%) were added. The properties of friction and wear were related with the propagation velocity of crack rather than the bending strength.

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Effects of Debinding Atmosphere on Properties of Sintered Reaction-bonded Si3N4 Prepared by Tape Casting Method

  • Park, Ji-Sook;Lee, Sung-Min;Han, Yoon-Soo;Hwang, Hae-Jin;Ryu, Sung-Soo
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.622-627
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    • 2016
  • The effects of the debinding atmosphere on the properties of sintered reaction-bonded $Si_3N_4$ (SRBSN) ceramics prepared by tape casting method were investigated. Si green tape was produced from Si slurry of Si powder, using 11.5 wt% polyvinyl butyral as the organic binder and 35 wt% dioctyl phthalate as the plasticizer. The debinding process was conducted in air and $N_2$ atmospheres at $400^{\circ}C$ for 4 h. The nitridation process of the debinded Si specimens was performed at $1450^{\circ}C$, followed by sintering at $1850^{\circ}C$ and 20 MPa. The results revealed that the debinding atmosphere had a significant effect on $Si_3N_4$ densification and thermal conductivity. Owing to the higher sintered density and larger grain size, the thermal conductivity of $Si_3N_4$ specimens debinded in air was higher than that of the samples debinded in $N_2$. Thus, debinding in air could be suitable for the manufacture of high-performance SRBSN substrates by tape casting.

COMPARATIVE ANALYSIS OF STRUCTURAL CHANGES IN U-MO DISPERSED FUEL OF FULL-SIZE FUEL ELEMENTS AND MINI-RODS IRRADIATED IN THE MIR REACTOR

  • Izhutov, Aleksey.L.;Iakovlev, Valeriy.V.;Novoselov, Andrey.E.;Starkov, Vladimir.A.;Sheldyakov, Aleksey.A.;Shishin, Valeriy.Yu.;Kosenkov, Vladimir.M.;Vatulin, Aleksandr.V.;Dobrikova, Irina.V.;Suprun, Vladimir.B.;Kulakov, Gennadiy.V.
    • Nuclear Engineering and Technology
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    • v.45 no.7
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    • pp.859-870
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    • 2013
  • The paper summarizes the irradiation test and post-irradiation examination (PIE) data for the U-Mo low-enriched fuel that was irradiated in the MIR reactor under the RERTR Program. The PIE data were analyzed for both full-size fuel rods and mini-rods with atomized powder dispersed in Al matrix as well as with additions of 2%, 5% and 13% of silicon in the matrix and ZrN protective coating on the fuel particles. The full-size fuel rods were irradiated up to an average burnup of ${\sim}60%^{235}U$; the mini-rods were irradiated to an average burnup of ${\sim}85%^{235}U$. The presented data show a significant increase of the void fraction in the U-Mo alloy as the U-235 burnup rises from ~ 40% up to ~ 85%. The effect of irradiation test conditions and U-235 burnup were analyzed with regard to the formation of an interaction layer between the matrix and fuel particles as well as generation of porosity in the U-Mo alloy. Shown here are changes in distribution of U fission products as the U-235 burnup increases from ~ 40% up to ~ 85%.

A Study on Magnetic Abrasive Using Sr-Ferrite (Sr-Ferrite를 이용한 자기 연마재에 관한 연구)

  • Kim, Hee-Nam;Kim, Dong-Wook
    • Journal of the Speleological Society of Korea
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    • no.79
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    • pp.77-81
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    • 2007
  • In this paper deals with behavior of the magnetic abrasive using Sr-Ferrite on polishing charateristiccs in a internal finishing of staninless steel pipe a tying magnetic abrasive polishing. The magnetic polishing is the useful method to finish some machinery fabrications by using magnetic power. This method is one of the precision techniques and has in aim for clean technology in the transportation of the pure gas in the clean pipes. The magnetic abrasive polishing method is not so common in the field of machine that it is not known to widely. There are rarely researcher in this field because of non-effectiveness of magnetic abrasive. Therefore, in this paper we deals with the development of the magnetic abrasive with the use of Sr-Ferrite. In this development, abrasive grain SiC has been made by using the resin bond fabricated at low temperature. And magnetic abrasive powder was fabricated from the Sr-Ferrite which was crushed into 200 mesh. The XRD analysis result shows that only SiC abrasive and Sr-Ferrite crystal peaks were detected, explaining that resin bond was not any more to contribute chemical reaction. From MACRO analysis, we found that SiC abrasive and Sr-Ferrite were strongly bonding with each other.

Separation and Recovery of Silicon Powder from Waste Silcon Sludge (폐실리콘 슬러지로부터 실리콘 분말의 분리 회수)

  • Jang, Hee-Dong;Chang, Han-Kwon;Suh, Yong-Jae;Kim, Byoung-Gyu;Hong, Seung-Hui;Chang, Won-Chul
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2005.05a
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    • pp.147-151
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    • 2005
  • 실리콘 잉곳의 절단공정에서 발생하는 폐실리콘 슬러지는 실리콘과 실리콘카바이드 등의 유가자원이 함유되어 있는데, 본 연구에서는 폐실리콘 슬러지 중의 실리콘 분말을 효과적으로 분리, 회수하는 방법에 대해 검토하였다. 폐실리콘 슬러지는 상당량의 절삭유와 소량의 철분말이 포함되어 있는데 절삭유는 유기 용매에 용해시켜 효과적으로 분리하였고, 철분말은 자력선별에 의해 제거하였다. 절삭유와 철성분이 제거된 잔사인 실리콘과 실리콘 카바이드의 혼합 분말로부터 초음파 분산 선별법을 사용하여 실리콘 분말을 효율적으로 분리회수 하였다.

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Fabrication and High-temerature Mechanical Property of Liquid-Phase-Sintered SiC (액상소결 탄화규소 세라믹스의 제조 및 고온기계적 특성)

  • Lee, Moonhee;Kim, Sungwon;Lee, Jongho;Hwang, SeungKuk;Gwak, Jaehwan;Lee, Jinkyung;Lee, Sangpill
    • Journal of the Korean Society of Industry Convergence
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    • v.23 no.4_2
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    • pp.669-674
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    • 2020
  • Liquid-phase-sintered (LPS) SiC materials were briefly examined with their microstructure and mechanical property. Especially, effect of high-temperature exposure on the tendency of fracture toughness of LPS-SiC were introduced. The LPS-SiC was fabricated in hot-press by sintering powder mixture of sub-micron SiC and sintering additives of Al2O3-Y2O3. LPS-SiC represented dense morphology and SiC grain-growth with some amount of micro-pores and clustered additives as pore-filling. The strength of LPS-SiC might affected by distribution of micro-pores. LPS-SiC tended to decrease fracture toughness depending on increasing exposure temperature and time.

Photocatalytic Degradation of Organic Compounds over $xTiO_2$-$ySiO_2$ Powders Prepared by Sol-Gel Method (졸-겔법으로 제조된 $xTiO_2$-$ySiO_2$ 분말에 의한 유기물의 광분해)

  • Yang, Chun-Hoe;Lee, Bong-Cheol
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.130-136
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    • 2008
  • $xTiO_2$-$ySiO_2$ system photocatalysts were developed by sol-gel method based on the change of production parameters, and their structure of crystallization and the specific surface area were measured. Considering the efficiency of the ethanol and phenol degradation using the catalyst, the conclusions were obtained as follows: By means of X-ray analysis of $xTiO_2$-$ySiO_2$ powder that is obtained from Titanium and Silicon alkoxide by sol-gel process, it is shown that crystal structure of anatase type is a dominating structure and, on the other hand, the structure of rutile also partly exists. The increase of $SiO_2$ contents causes the decrease of the degree of crystallization of the gel, whereas the specific surface area preferentially increases. It is shown that more than 90% of ethanol and phenol are degraded when reaction time is about three and an hours, and the maximum degradation rate of ethanol and phenol is shown in $60TiO_2$-$40SiO_2$ catalyst.