• 한국결정성장학회지
• /
• 제29권2호
• /
• pp.45-49
• /
• 2019

본 연구에서는, 탄소성분으로서 탄화왕겨, 제지슬러지, 커피찌꺼기와 실리카 분말로부터, 비교적 미세한 탄화규소 결정질 응집체를 합성하였다. 탄소성분들과 실리카의 혼합물로부터 탄화규소 응집체를 얻기 위한 주요 반응물질은 열탄화환원 반응에 의해 생성된 일산화규소 기체로 추정되었다. 탄화왕겨, 제지슬러지, 커피찌꺼기와 실리카 분말의 혼합물로부터 열탄화환원반응법을 거쳐 생성된 탄화규소 결정질 응집체들에 대한 XRD 회절패턴으로부터 결정상을 분석하였고, FE-SEM과 FE-TEM을 통한 미세구조, 결정구조 분석이 이루어졌다. 탄화왕겨, 제지슬러지, 그리고 실리카 분말의 시료의 경우, XRD 분석에서는 $35^{\circ}$ 부근의 (111) peak은 비교적 높은 강도를 나타내었다. 탄화왕겨, 제지슬러지, 커피찌꺼기와 실리카 분말의 혼합물로부터 합성된 시료들에 대해 FE-SEM 관찰을 통하여 $1{\mu}m$ 이하의 미세입자들을 관찰하였으며, TEM 측정 결과에서는 탄화규소 결정질상의 (110) 회절패턴들을 확인하였다.

• 전기화학회지
• /
• 제17권1호
• /
• pp.49-56
• /
• 2014

탄소가 코팅된 일산화규소(C-coated SiO) 전극에서 전해질 첨가제로서 lithium bis(oxalato)borate(LiBOB)의 영향을 조사하였다. 전해질 조성은 1.3M $LiPF_6$/ethylene carbonate (EC), fluoroethylene carbonate (FEC), diethyl carbonate (DEC) (5:25:70 v/v/v)이며, 여기에 LiBOB을 0.5 wt.% 첨가한 것과 첨가하지 않은 2가지 전해질을 사용하였다. LiBOB을 첨가하지 않은 전해질에서 C-coated SiO 전극은 초기에 저항이 작은 피막이 형성되어 결정질의 $Li_{15}Si_4$를 형성할 때까지 합금화가 진행되며 동시에 큰 부피 변화를 보였다. 따라서 입자의 균열이 발생하고, 전극의 저항이 증가하여 충방전이 진행됨에 따라 용량이 빠르게 감소하였다. 반면에 LiBOB이 첨가된 전해질에서는 초기에 LiBOB의 환원분해에 의해 저항이 큰 피막이 형성되어, 합금화 반응이 원활히 진행되지 못하였다. 따라서 결정질 $Li_{15}Si_4$도 생성되지 못하였고, 결과적으로 부피변화도 적게 발생하므로 입자의 균열과 전극 저항의 증가도 적게 나타났다. 이러한 효과로 싸이클 후반부에서 용량감소가 적었고, 싸이클 성능도 좋은 결과를 보였다. 반면 피막 저항에 의한 영향이 줄어드는 $45^{\circ}C$ 에서는 LiBOB 첨가에 관계없이 합금화 반응이 유사하게 진행되며 비슷한 싸이클 성능을 나타내었다.

• 한국화재소방학회논문지
• /
• 제33권4호
• /
• pp.16-27
• /
• 2019

실리콘 화합물인 Sodium silicate, 3-aminopropyltrimethoxysilane 졸, 3-(2-aminoethylamino) propylmethyl-dimethoxysilane 졸, 3-(2-aminoethylamino) propyltrimethoxysilane 졸로 표면 처리한 편백목재 시편의 연기 및 연소가스 발생에 대한 시험을 하였다. 실리콘 화합물 졸로 각각 편백목재 시험편에 붓으로 3회 칠하였다. 콘칼로리미터(ISO 5660-1)를 사용하여 연기 및 연소가스를 분석하였고 연기는 새로운 연기위험성 평가 방법을 적용하여 평가하였다. 실리콘 화합물로 처리한 목재시험편의 연기성능지수(SPI)는 편백목재보다 1.66~8.42배 증가하였고, 연기성장지수(SGI)는 11.8~88.2% 감소하였다. 연기강도(SI)는 편백목재보다 1.0~50.5% 감소되었고, 연기 및 화재 위험성이 낮아짐을 예측할 수 있었다. 실리콘화합물로 처리한 시험편의 세 번째 최대일산화탄소(CO_peak)농도는 공시편보다 22.5~33.3% 감소되었다. 그러나 미국직업안전위생관리국(OSHA) 허용기준(PEL)인 50 ppm보다 1.48~1.72배 높은 치명적인 독성을 발생시키는 것으로 측정되었다. 편백목재 자체는 일산화탄소 생성 농도가 높았지만 실리콘 화합물은 일산화탄소를 감소시키는 역할을 하였다.

• 한국전기전자재료학회논문지
• /
• 제18권10호
• /
• pp.936-940
• /
• 2005

IMML(Inorganic metal multi-layer) was used as cathode in the OLED devices to reduce the reflectance or ITO and increase the contrast ratio. Device structure was $ITO/{\alpha}-NPD/Alq_3:DCJTB/Alq_3/IMML/Al$. $Alq_3$ and DCJTB (4 - (dicyanomethylene) - 2 - ( 1 - propyls) 6 - methy 4H - pyrans) as host material lot red emission and red emitting guest material. IMML made three different layer: thin aluminum layer, aluminum layer doped with silicon monoxide, thick aluminum layer. The red OLED device with IMML showed the average reflectance of $4.97\%$, and then normal OLED with or without polarizer showed the average reflectance of $4.55\%$, $46\%$ at visible range from 380 nm to 780 nm. The brightness of OLED with IMML at 13 V was 5557 $cd/m^2$, and that of normal OLED with polarizer was 4872 $cd/m^2$. IMML could be the substitution for polarizer with same reflection, low cost, easy process in flat panel display market.

• 한국세라믹학회지
• /
• 제43권9호
• /
• pp.582-587
• /
• 2006

Decomposition behavior of $ferro-Si_3N_4$was investigated with varying temperature and holding time in mud components for high temperature refractory applications. Porosities gradually increased with increasing temperature and holding time due to the carbothermal reduction of $Si_3N_4\;and\;SiO_2$. Silicon monoxide (SiO) as a intermediate resulted from evaporation of $Si_3N_4\;and\;SiO_2$ reacted with C sources to generate needle-like ${\beta}-SiC$ and Fe in $Si_3N_4$ acted as a catalyst in order to enhance growth of SiC grain with the preferred orientation. SiC generation yield increased with increasing holding time, all of the $Si_3N_4\;and\;SiO_2$ affected on SiC formation up to 2h. However, SiC generation was only dependent on residual $SiO_2$ over 2h, because the carbothermal reduction reaction of $Si_3N_4$ was no longer possible at that time.

• 전기학회논문지
• /
• 제56권9호
• /
• pp.1561-1565
• /
• 2007

According to thermal degradation on power transformers, it is known that electrical, mechanical and chemical characteristics for power transformer's oil-paper are changed. In the chemical property, especially, when the kraft paper is aged, the cellulose polymer chains break down into shorter lengths. It causes decrease in both tensile strength and degree of polymerization of paper insulation. Also the paper breakdown is accompanied by an increase in the content of various furanic compounds within the dielectric liquid. It is known that furanic components in transformer oil come only from the decomposition of insulating paper rather than from the oil itself. Therefore the analysis of furanic degradation products provides a complementary technique to dissolved gas analysis for monitoring transformers when we evaluate the aging of insulating paper by the total concentration of carbon monoxide and carbon dioxide dissolved in oil only. Recently, the analysis of furanic compounds by high performance liquid chromatography(HPLC) using IEC 61198 method for estimating degradation of paper insulation in power transformers has been used more conveniently for assessment of oil-paper. It is know that the main products which is produced by aging are 2-furfuryl alcohol, 2-furaldehyde(furfural), 2-furoic acid, 2-acetylfuran, 5-methyl-2-furaldehyde, and 5-hydroxymethyl-2-furaldehyde. For investigating the accelerated aging process of oil-paper samples we manufactured accelerating aging equipment and we estimated variation of insulations at $140^{\circ}C$ temp. during 500 hours. Typical transformer proportions of copper, silicon steel and iron have been added to oil-paper insulation during the aging process. The oil-paper insulation samples have been measured at intervals of 100 hours. Finally we have analyzed that 2-furoic acid and 2-acetylfuran products of furanic compounds were detected by HPLC, and their concentrations were increased with accelerated aging time.

• 천문학회보
• /
• 제41권2호
• /
• pp.46.3-46.3
• /
• 2016

We present the ALMA Cycle 2 results "Two New SiO Maser Sources in High-Mass Star-Forming Regions" which was published in the Astrophysical Journal (Vol. 826, P157, 2016). Silicon monoxide (SiO) masers are rare in star forming regions, with the exception of five known SiO maser sources. However, we detected two new SiO maser sources from infrared loud clumps of the high-mass star forming regions G19.61-0.23 and G75.78+0.34 using the KVN single dish. High angular resolution observations with ALMA and JVLA toward G19.61-0.23 suggest that the deeply embedded young stellar object (YSO) of SMA 1 is powering the SiO masers. In addition, the SiO v=1, J=1-0 line shows four spike features while the v=2 maser shows combined features of one spike and broad wing components, implying energetic activities of the YSO of SMA 1 in the G19.61-0.23 hot molecular core. The SiO v=0, J=2-1 emission shows bipolar outflows in NE-SW direction with respect to the center of the SiO maser source. A high angular resolution map of the SiO v=1, J=2-1 maser in G75.78+0.34 shows that the SiO maser is associated with the CORE source at the earliest stage of high-mass star formation. Therefore, the newly detected SiO masers and their associated outflows will provide good probes for investigating this early high-mass star formation.

• Journal of Electrochemical Science and Technology
• /
• 제2권3호
• /
• pp.146-151
• /
• 2011

The formation of Li-Si-O phases, $Li_4SiO_4$ and $Li_2SiO_3$ from the starting materials SiO and $Li_2O$ are analyzed using Vienna Ab-initio Simulation (VASP) package and the total energies of Li-Si-O compounds are evaluated using Projector Augmented Wave (PAW) method and correlated the structural characteristics of the binary system SiO-$Li_2O$ with experimental data from electrochemical method. Despite $Li_2SiO_3$ becomes stable phase by virtue of lowest formation energy calculated through VASP, the experimental method shows presence of $Li_4SiO_4$ as the only product formed when SiO and $Li_2O$ reacts during slow heating to reach $550^{\circ}C$ and found no evidence for the formation of $Li_2SiO_3$. Also, higher density of $Li_4SiO_4$(2.42 g $ml^{-1}$) compared to the compositional mixture $1SiO_2-2Li_2O$ (2.226 g $ml^{-1}$) and better cycle capacity observed through experiment proves that $Li_4SiO_4$ as the most stable anode supported by better cycleabilityfor lithium ion battery remains as paradox from the point of view of VASP calculations.

• 대한전자공학회논문지SD
• /
• 제40권1호
• /
• pp.11-19
• /
• 2003

폭발성 가스의 증류 및 그 양을 검지하기 위한 4 개의 개별 센서가 한 마이크로 열판 위에 집적된 센서어레이를 개발했다. 이 센서어레이는 각종 가스에 대해 다양한 감도 패턴을 가지며, SnO2를 모물질로 하는 4 개의 산화물 반도체 마이크로 가스센서로 구성하였다. 다공질에 큰 비표면적을 가진 모물질에 서로 다른 촉매를 첨가하여 감지물질을 제작함으로써 저농도에 대한 감도 및 재현성을 높였고, 센서어레이 전반에서 균일한 온도 분포가 되도록 설계하였다. 마이크로 열판은 N/O/N 박막을 가진 실리콘 기관을 이용하여, 열적 고립을 위해 Al 본딩 와이어로 공기중에 부유되어 있고, CMP 공정으로 두께를 제어하여 소모 전력을 조절하였다. 400℃에서 동작하는 센서어레이로부터 얻은 감도를 이용하여 주성분 분석 기법을 통해 폭발 하한값의 범위에서 부탄, 프로판, LPG, 그리고 일산화탄소 등과 같은 폭발성 빛 유독성 가스의 증류 및 양을 신뢰성 있게 식별할 수 있었다.

• Nuclear Engineering and Technology
• /
• 제54권8호
• /
• pp.2792-2800
• /
• 2022

In the core of the WWR-K reactor, a long-term irradiation of tristructural isotopic (TRISO)-coated fuel particles (CFPs) with a UO₂ kernel was carried out under high-temperature gas-cooled reactor (HTGR)-like operating conditions. The temperature of this TRISO fuel during irradiation varied in the range of 950-1100 ℃. A fission per initial metal atom (FIMA) of uranium burnup of 9.9% was reached. The release of gaseous fission products was measured in-pile. The release-to-birth ratio (R/B) for the fission product isotopes was calculated. Aspects of fuel safety while achieving deep fuel burnup are important and relevant, including maintaining the integrity of the fuel coatings. The main mechanisms of fuel failure are kernel migration, silicon carbide corrosion by palladium, and gas pressure increase inside the CFP. The formation of gaseous fission products and carbon monoxide leads to an increase in the internal pressure in the CFP, which is a dominant failure mechanism of the coatings under this level of burnup. Irradiated fuel compacts were subjected to electric dissociation to isolate the CFPs from the fuel compacts. In addition, nondestructive methods, such as X-ray radiography and gamma spectrometry, were used. The predicted R/B ratio was evaluated using the fission gas release model developed in the high-temperature test reactor (HTTR) project. In the model, both the through-coatings of failed CFPs and as-fabricated uranium contamination were assumed to be sources of the fission gas. The obtained R/B ratio for gaseous fission products allows the finalization and validation of the model for the release of fission products from the CFPs and fuel compacts. The success of the integrity of TRISO fuel irradiated at approximately 9.9% FIMA was demonstrated. A low fuel failure fraction and R/B ratios indicated good performance and reliability of the studied TRISO fuel.