• Journal of the Korean Society of Safety
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• v.29 no.6
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• pp.137-143
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• 2014

Asbestos is given to a variety of six naturally occurring silicate minerals. These minerals possess high tensile strength, flexibility, resistance to chemical and thermal degradation, and electrical resistance. These minerals have been used for decades in thousands of commercial products, such as insulation and fireproofing materials, automotive brakes, textile products, cement and wallboard materials. When handled, asbestos can separate into microscopic-size particles that remain in the air and are easily inhaled. It is now known that prolonged inhalation of asbestos fibers can cause serious and fatal illnesses including malignant lung cancer, mesothelioma, and asbestosis. Therefore the use of asbestos and asbestos products has dramatically decreased in recent years. Also all constructions including asbestos should be removed under strictly controlled conditions and very tightly implemented health & safety management systems. In this study, the process of the removal work of the asbestos cement slate was analyzed by IDEF-0 modeling and evaluated by 4M risk assessment method. The results show that removal work of the asbestos cement slate was classified five process and eighteen detail process. The risk of safety side the higher than the risk of health side in 4M risk assessment.

• Computers and Concrete
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• v.11 no.1
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• pp.39-49
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• 2013

The use of ground fly ash in concrete can increase the risk of slump loss due to the drastic surface change of the particles after the grinding treatment and the accelerated reaction compared to the untreated ash. This study is aimed at the early age hydration and time-dependent rheology changes of cement paste containing ground fly ash. An original fly ash is ground into different fineness and the hydration of cement paste containing the ground fly ash is monitored with the ultrasound propagation method. The zeta potentials of the solid particles are measured and the changes of rheological parameters of the cement pastes with time are analyzed with a rheometer. A particle packing model is used to probe packing of the solid particles. The results show that the early age hydration of the paste is strongly promoted by replacing Portland cement with fly ash up to 30 percent (by mass), causing increase of the yield stress of the paste. The viscosity of a paste containing ground fly ash is lower than that containing the untreated ash, which is explained by the denser packing of the solid particles.

• Environmental Engineering Research
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• v.12 no.3
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• pp.101-108
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• 2007

Fixation of lead contaminants in the solidification/stabilization using Portland cement has been investigated by X-ray diffraction, scanning electron microscopy and compressive strength. The presence of lead was observed to produce lead carbonate sulfate hydroxide ($Pb_4SO_4(CO_3)_2(OH)_2$), lead carbonate hydroxide hydrate ($3PbCO_3{\cdot}2Pb(OH)_2{\cdot}H_2O$) and two other unidentified lead salts in cavity areas and was observed to significantly retard the hydration of cement. By 28 days, howevere, the XRD peaks of most of the lead precipitates have essentially disappeared with only residual traces of lead carbonate sulfate hydroxide and lead carbonate hydroxide hydrate evident. After 28 days of curing, hydration appears well advanced with a strong portlandite peak present though C-S-H gel peaks are not particularly evident. Lead species produced with the dissolution of lead precipitates are fixed into the cement matrix to be calcium lead silicate hydrate (C-Pb-S-H) during cement-based solidification.

• Journal of the Korean Institute of Rural Architecture
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• v.21 no.2
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• pp.35-42
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• 2019

There are 17,427 reservoirs in Korea, of which about 96% were built before the mid 1980s. Therefore, aging is severe and reinforcement are necessary. In addition, aged reservoirs, which are more than 50 years old, account for 70% of the total. Therefore, there is a problem such as the collapse of the reservoir and the decrease of the storage capacity due to progress of aging with time. The grouting method using cement is mainly used as maintenance and reinforcement method of old reservoir. However, the grouting method using cement has engineering and environmental problems. In order to solve the engineering and environmental problems of cement grouting method, an eco-friendly grouting material was developed that mixes circular resource grouting binder, high molar ratio sodium silicate and colloidal silica. The engineering and environmental properties of the developed injection materials were evaluated by conducting gel time, homo-gel strength, sea water resistance test and environmental stability evaluation. Also, examined the possibility of replacing OPC existing aged reservoir reinforcement methods. As a result, it was found out that it was better than the conventional cement method in terms of engineering and environment. However, since this study is the result of laboratory test, it is necessary of verify the application at field of aged reservoir.

• Computers and Concrete
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• v.29 no.4
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• pp.237-246
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• 2022

The concrete quality relies on general factors like preparation technique, uniformity of the compaction, amount and appropriateness of the additives. The current article investigates the impact of a well knows amino acid, L-arginine as an additive on water requirements, setting durations and characterization of various cement samples. Compressive strength tests of reference and L-arginine added cements at age of 2, 7 and 28 days were carried out according to TS-EN 196-1. Samples were blended by incorporating various amounts of L-arginine (25 ppm, 50 ppm and 75 ppm) in the cement water mixture which were tested with Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermo-gravimetric analysis (TG), scanning electron microscopy (SEM) and the energy-dispersive X-ray spectroscopy (EDS) on the 28th day. Results revealed that L-arginine does not affect the setting time, volume expansion of cement and water demands negatively; rather it imparts enhanced sustainability to the samples. It was determined that the highest value belonged to the 75L mortar with an increase of 2.6% compared to the reference sample when the compressive strengths of all mortars were compared on the 28th day. Besides, it has been observed that the development of calcium silicate hydrate or C-S-H gel, calcium hydroxide or CH and other hydrated products are associated with each other. L-arginine definitely has a contribution in the consumption of CH formed in the hydration process.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.7
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• pp.810-819
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• 2007

Investigation of alkali activation of fly ash and blast furnace slag was carried out using waterglass and sodium hydroxide. XRD, FTIR, $^{29}Si$ and $^{27}Al$ NMR, TGA and SEM were used to observed the reaction products and microstructure of the fly ash/slag cement (FSC) pastes. The reaction products were amorphous or low-ordered calcium silicate hydrate and aluminosilicate gel produced from alkali activation of blast furnace slag and fly ash, respectively. On the basis of this investigation, waterglass solution with a modulus(Ms) of 1.0 and 1.2 is recommended for alkali activation of fly ash and blast furnace slag. Morphology of FSC pastes alkali-activated with Ms of 1.0 and 1.2 shows a more solid and continuous matrix due to restructuring of gel-like reaction products from alkali-activated fly ash and blast furnace slag together with another hydrolysis product(i.e., silica gel) from water glass.

• Journal of The Korean Society of Clinical Toxicology
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• v.16 no.2
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• pp.157-160
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• 2018

Chronic silica nephropathy has been associated with tubulointerstitial disease, immune-mediated multisystem disease, chronic kidney disease, and end-stage renal disease. On the other hand, acute intentional exposure is extremely rare. The authors' experienced a 44-year-old man who took rapid cement hardener (sodium silicate) in a suicide attempt whilst in a drunken state. He visited the emergency department approximately 1 hour after ingestion. Information on the material was obtained after 3 L gastric lavage. The patient complained of a sore throat, epigastric pain, and swollen to blood tinged vomitus. Proton pump inhibitors, hemostats, steroid, and fluids were administered. Nine hours after ingestion, he was administered 200 mL hematochezia. Immediately after, a gas-troenterologist performed an endoscopic procedure that revealed diffuse hyperemic mucosa with a color change and variable sized ulceration in the esophagus, whole stomach, and duodenal $2^{nd}$ portion. Approximately 35 hours later, persistent oligouria and progressive worsening of the renal function parameters (BUN/Cr from 12.2/1.2 to 67.5/6.6 mg/dL) occurred requiring hemodialysis. The patient underwent 8 sessions of hemodialysis for 1 month and the BUN/Cr level increased to 143.2/11.2 mg/dL and decreased to 7.6/1.5 mg/dL. He was discharged safely from the hospital. Follow up endoscopy revealed a severe esophageal stricture and he underwent endoscopic bougie dilatation. Acute cement hardener (sodium silicate) intoxication can cause renal failure and strong caustic mucosal injury. Therefore, it is important to consider early hemodialysis and treatment to prevent gastrointestinal injury and remote esophageal stricture.

• Earthquakes and Structures
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• v.20 no.4
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• pp.365-375
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• 2021

Rammed earth (RE) buildings have existed all over the world for thousands of years, and have gained increasing attention because of its sustainable advantages, however, the shrinkage cracks reduce its bearing capacity and seriously affect its durability and applicability. In this study, the shrinkage cracks test was carried out to investigate the effects of initial water content, proportion of sand and gravel, compaction degree, thickness and the additives (polypropylene fiber, cement and sodium silicate) of shrinkage cracks in RE buildings, ten groups of RE samples were prepared and dried outdoors to crack. Four quantitative parameters of geometrical structure of crack patterns were used to evaluate the development of cracks. The results show that the specimens cracking behavior and the geometrical structure of crack patterns are significantly influenced by these considered factors. The formation of crack can be accelerated with the increase of initial water content and thickness of specimen, while restricted with the increase of the compaction degree and the proportion of sand and gravel. Moreover, the addition of 1% polypropylene fiber, 10% cement and 0.5 volume ratio sodium silicate can significantly restrain the form and development of cracks. In RE construction, these factors should be considered comprehensively to prevent the harm caused by shrinkage cracks. Further works should be carried out to obtain the optimum dosage of the additives, which can benefit the construction of RE buildings in future.

• Journal of Animal Environmental Science
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• v.7 no.1
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• pp.29-32
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• 2001

In this experiment porous calcium silicate (PCS) powder prepared by using a 50 mesh sieve was spread on top of chick droppings to investigate the odor from the manure. Zeolite was used as a comparative purpose. Reduction in ammonia production from chick droppings shortly after the PCS and zeolite application was evident (P<0.05), but there were no difference among treatments afterwards. hydrogen sulfide level was significantly lowered by both PCS and zeolite treatment(P<0.05).

• Proceedings of the Korea Concrete Institute Conference
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• 1995.04a
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• pp.111-117
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• 1995

The alkali-aggregate reaction is a reaction between the alkali metals in the pore water of a concrete and an unstable mineral of the aggregate. There are three types of alkali-aggregate reation which causes deterioration of concrete, such as alkali-silicate reation, alkali-carbonate reaction and alkali-silica reation. Deterioration due to alkali-silica reation is more comon than that due to either the alkali-silicate or alkali-carbonate reaction. The alkali-silica reation is a reaction between the hydroxyl ions in the pore water of a concrete and silica which exists in signigicant quantities in the aggregate. In this PAPER, Alkali-aggregate reactions of mortar made with various abroad aggregate were investigated using XRD, microscope, chemical and physical tests. In additions, the effects of the texture of aggregate, Na, K, CI ion concentrations added to the mortar, on these reactions were studied.