• Title/Summary/Keyword: Silica particle

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A Numerical Analysis of Growth of Non-spherical Silica Particles in a Premixed Flat Flame (예혼합 평면화염에서 비구형 실리카 입자의 성장에 관한 수치해석적 연구)

  • Oh, Se-Baek;Lee, Bang-Weon;Choi, Man-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.10
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    • pp.1351-1358
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    • 2000
  • Two dimensional aerosol dynamics considering the effects of particle generation, coagulation, thermophoresis, sintering and convection has been studied to obtain the growth of non-spherical silica particles in conjunction with determining flame temperature by performing combustion analysis of premixed flat flame. Heat and mass transfer analysis includes 16 species, 29 chemical reaction steps together with oxidation and hydrolysis of SiCl4. The effect of radiation heat loss has also been included. The predictions of flame temperatures and the evolution of particle size distributions were in a reasonable agreement with the existing experimental data.

Performance Improvement of Epoxy Resin System by the Filler Reformation (충진제 개질을 통한 에폭시복합체의 성능개선)

  • Yi, Dong-Young
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.1
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    • pp.130-135
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    • 2010
  • In this study, the performance improvement of epoxy resin system had been tried by the improvement of particle size distribution and globularization of filler using polymerization method. From the results of particle size distribution measurement, the polydispersity value of reformed filler was 1.04 and that of silica flour before reformation was 2.6, it could be confirmed that the particle size uniformity of reformed filler had been improved greatly and the shape of particle was globular. Compatibility between monomer and silica was improved remarkably with the silanization pretreatment of silica flour. From the results of degree of crosslinking test, it could be confirmed that the binding structure of reformed filler was 3-dimensional net structure. And it could be also confirmed that the fluidness was improved at the casting of epoxy resin with reformed filler. From the above results, it could be concluded that the reformation of filler with the improvement of particle size distribution and globularization was very successful method to improve the performance of cast epoxy resin system.

Effect of Alumina Addition tn the Silica Slurry on the Chemical Mechanical Polishing of Laugasite (실리카 슬러리에 첨가된 알루미나가 Langasite의 기계.화학적 연마에 미치는 영향)

  • 장영일;윤인호;임대순
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1999.11a
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    • pp.263-268
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    • 1999
  • Langasite, a new piezoelectric material was polished by CMP(chemical mechanical polishing). To enhance the polishing rate, alumina abrasives were added to commercial ILD1300 slurry which contains silica abrasive. The effect of added alumina 0 the silica slurry on the polishing rate and damage of langasite was investigated, Experimental results show that the polishing rate and roughness increases with increasing added alumina particle size, Crystallinity of the langasite is also lowered by alumina addition.

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Preparation of electro-catalysts supported on the bimodal porous carbon for polymer electrolyte fuel cell (Bimodal 다공성 탄소지지체에 담지된 고분자전해질연료전지용 전극촉매 제조)

  • Hwang, So-hee;Park, Gu-Gon;Yim, Sung-Dae;Park, Seok-Hee;Kim, Han-Sung;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.652-655
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    • 2009
  • The bimodal porous carbons were synthesized by using imprinting method with templates of SBA-15 particle and silica sphere and applied as supporting materials for the electro-catalyst of polymer electrolyte fuel cell (PEFC). The silica spheres with diameter size of 100 nm and SBA-15 particle having 200 nm -250 nm diameter and 700 nm -900 nm length were synthesized in this work. The bimodal porous carbons (S100) were prepared by using the silica spheres and SBA-15 as templates and mesophase pitch as a carbon source. The PtRu nanoparticle of ca. 1.9 nm were supported on the bimodal porous carbon support and the resulting PtRu/S100 catalysts was tested by the cyclic voltammetry. The use of bimodal porous carbon showed in comparable electro-catalytic activities with commercial catalyst. Though unclear effects of bimodal porosity of supports could be obtained in the scope of this study, morphological advantage in electrical conductivity can be considered on the electro-catalytic activity.

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Impact behavior on temperature effect of nano composite materials (온도변화에 따른 나노 복합재료의 충격거동)

  • KIM, Hyung-Jin;LEE, Jung-Kyu;KOH, Sung Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.51 no.4
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    • pp.561-566
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    • 2015
  • In this study, the effect of temperature effect of the rubber matrix filled with nano sized silica particles composites with silica volume fraction of 19-25% was investigated by the Charpy impact test. The Charpy impact test was conducted in the temperature range from $-40^{\circ}C$ to $0^{\circ}C$. The critical energy release rate GIC of the rubber matrix composites filled with nano sized silica particles was considerably affected by temperature and it was shown that the maximum value was appeared at higher temperature between temperature tested and it was shown that the value of GIC increases as temperature tested increases. The major fracture mechanisms were matrix deformation, silica particle debonding and delamination, microcrack between particles and matrix, and/or pull out between particles and matrix which is ascertained by SEM photographs of Charpy impact surfaces fracture.

Syntheses of Mesoporous Silica Hollow Spheres Using Polystyrene Template (폴리스티렌 주형 중공형 중간세공 나노 입자의 합성)

  • Chu, Sang-Wook;Sung, A-Reum;Park, Sung Soo;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.13 no.4
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    • pp.151-155
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    • 2012
  • In the present study, we synthesized mesoporous silica hollow spheres with different wall thickness using polystyrene (PS) spheres as a structure template, tetraethoxysilane (TEOS) as a silica source, cetyltrimethylammonium bromide (CTAB) as a template. Particle size and dispersion of PS spheres were strongly depended on the concentration of surfactant in the aqueous solutions. The size of PS spheres was increased with decreasing concentration of surfactants. Dispersion of PS particle was improved when the surfactant concentration was lower than 0.5 g of surfactant.

A Study on the ZnO Supported Silica Gel (ZnO가 담지된 실리카 겔 연구)

  • Kim, S.Y.;Kim, M.Y.;Ju, C.S.
    • Journal of Power System Engineering
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    • v.15 no.4
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    • pp.75-78
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    • 2011
  • There are various types of materials used in electronic industry, such as electrode material, conductor, insulator, anode, cathode and semiconductor. Electrode material type is Cu, Ti, ZnO and so on. Especially if we use mixed ZnO in soil cement or silica gel, we can have advantages in ice road to prevent freezing. We have great impact if we use supported in inorganic substances like silica gel. In this paper we have studied that ZnO supported silica gel and its properties. Zinc acetate dissolved in distilled water were loaded on the silica gel by the reaction with ammonia at $80^{\circ}C$. And we investigated particle structures of ZnO by scanning electron microscopy(SEM) and X-ray diffraction(XRD).

An Experimental Studyon the Durability of Steel Field Reinforced Concrete Using Silica Fume (실리카흄을 혼입한 강섬유보강 콘크리트의 내구성에 관한 실험적연구)

  • 박승범;홍석주;조청휘;김부일
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.285-291
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    • 1998
  • During recent years, the durability of concrete structures has been considered in concret practice and material research. To preserve the brittleness of concrete as well as energy absorption and impact resistance, amount of fiber usage has greatly increased in the field of public works. Ultra fine powder, silica fume, mixed into concrete, it reduce void of concrete structure. Especially, there's a great effect for strength improvement of concrete by initial pozzolanic reactions. For these reasons, if silica fume mixed into concrete, it decrease the total void by microfilter effect . Pozzolan reaction, between cement particle and silica powder, can elaborate the micro structure of matrix. And so, in this paper, we deal SFRC for the purpose of efficiently using of industrial by-products(silica fume). Also we performed the test for durability such as freeze-thaw resistance and accelerated carbonation of SFRC using silica fume.

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Effect of Mixing Ratio of Spherical Silica on the Electrical Insulation Breakdown Strength in Epoxy Composites

  • Park, Jae-Jun
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.2
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    • pp.101-104
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    • 2013
  • The effect of the mixing ratio of spherical silica on the electrical insulation breakdown strength in an epoxy/silica composite was studied. Spherical silicas with two average particle sizes of $5{\mu}m$ and $20{\mu}m$ were mixed in different mixing ratios, and their total filling content was fixed at 60 wt%. In order to observe the dispersion of the silicas and the interfacial morphology between silica and epoxy matrix, scanning electron microscopy (SEM) was used. The electrical insulation breakdown strength was estimated in sphere-sphere electrodes with different insulation thicknesses of 1, 2, and 3 mm. Electrical insulation breakdown strength decreased with increasing mixing ratio of $5/20{\mu}m$ and the thickness dependence of the breakdown strength was also observed.

Preparation and Characterization of Spherical Silica-coated Ceria Nanoparticles by Sol-Gel Method

  • Ahn, Yang-Kyu;Jeoung, Hae-Chan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.96-96
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    • 2010
  • Monodispersed spherical silica-coated ceria nanoparticles were prepared through a sol-gel process using tetraethylorthosilicate (TEOS) and ceria fine particles. In this process, ceria fine particles were also prepared from cerium nitrate. The mean size of ceria particles was 300nm. Silica nanoparticles with narrow particle size distribution were prepared by controlled hydrolysis of TEOS solution. The silica sols were obtained by peptization, the process of redispersing a coagulated colloid, and were coated on ceria particles by the control of the weight ratio of silica/ceria and the pH of the mixture in aqueous solution. The morphologies of particles were characterized with scaning electron microscopy(SEM), transmission electron microscopy(TEM) and atomic force microscopy(AFM). The coating thickness of silica particles obtained by using this method was controlled in the range of 30 - 70nm.

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