• Journal of the Korean GEO-environmental Society
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• v.15 no.11
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• pp.61-66
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• 2014

The various recycling methods of mixed coal ash have been developed considerably and it's recycling quantity has been increased. However, the more relatively finer grain content of coal ash in ash pond is increased the more it's quantity is increased in recycling as products for drainage in soft ground etc. Accordingly, the geotechnical properties of mixed coal ash in ash pond would be inferior and it's recycling rate should reach the limitations in increase. In this study, to recycle mixed coal ash contained fine grain in considerably amount as products for strength, etc. By adding binder to it and manifesting, it's compressive strength is stronger than the criteria, these are suggested; 1) the variety of compressive strength test performed on mixed coal ash of various grain distributions as main material, 2) the kind of binder, it's mixing quantity and the optimum content rate range of fine grain coal ash that the compressive strength stronger than a certain compressive strength is manifested. Cement is more excellent than quicklime as binder in manifesting stronger compressive strength and the sieve type to sort it is #40 sieve in order to recycle all mixed coal ash in ash pond efficiently as products for drainage as well as products for strength, etc. And, it could increase insufficient compressive strength remarkably that content of pure sand is more in the rate as pure sand and the part of mixed coal ash in ash pond to pass through #40 sieve is mixed in the ratio of 2 to 8.

• Journal of Korean Society of Forest Science
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• v.84 no.2
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• pp.166-177
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• 1995

This study was carried out to discuss how soils in the area planned for a forest road construction can be mechanically tested and practically applied. For this, 16 soil test samples from 8 plots(2 samples per plot) were used. The major tests are focused on unit weight before and after cut, water content, liquid and plastic limits, sieve and hydrometer analysis etc. The total unit weight(${\rho}_t$) before and after cut are $1.69g/cm^3$ and $1.19g/cm^3$, respectively. Their water contents are 21.0% and 20.5%. The coefficient of uniformity U and coefficient of curvature C obtained from sieve and hydrometer analysis are 125 and 0.42, which mean generally not well graded. On the soil classification by USCS, SM(silty sand or silt-sand mixed soil)is a Key soil, but it seems to be not good for fill material. From the standard proctor test are resulted $1.40{\pm}0.065g/cm^3$ for the unit weight(${\rho}$) in the nature and $1.88{\pm}0.049g/cm^3$ for the optimum proctor unit weight(${\rho}pr$) each. With this to say, it is necessary more powerful compaction work at earth filling, with which this soil reachs enough the ${\rho}pr$, and more earth.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.8 no.1
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• pp.115-123
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• 1998

Vinyl chloride monomer exists as gas phase at normal temperature and reacts with oxygen and strong oxidant in the air to form oxidized materials. Because of being easily synthesized, it is used as a main source at the synthetic reaction process of PVC synthesis factories. Ministry of Labor regulates its usage as a carcinogen and its exposure level as 1 ppm. But the amount of VCM production in PVC and VCM production process hasn't been exactly estimated. In addition, facilities of this factory are located in outdoor. Therefore, this study was designed to investigate effects of temperature on breakthrough of charcoal tube at a fixed concentration and temperature during VCM sampling based on NIOSH and OSHA methods which were used as methods of occupational environment measuring and analysis. During the sampling of VCM, methods of OSHA and NIOSH require flow rate of 0.05 lpm and sampling volume of $3{\ell}$, $5{\ell}$ respectively, at this time carbon molecular sieve tube and coconut shell charcoal tube are used to observe the breakthrough along with concentration and temperature. As a result, significant difference between average adsorbed amounts of OSHA methods but that of NIOSH methods cannot be found. NIOSH method is likely to be effected by high temperature and normal temperature in high concentration. Breakthrough is not found in the method of OSHA at different conditions of temperature and concentration. As the result of this study we could verify that breakthrough occurred in the process of sampling VCM with NIOSH methods. Therefor in summer time, breakthrough should be considered and research on the breakthrough volume should be done. It is considered the research about the specificity of the coconut shell charcoal and carbon molecular sieve sorbent should be done when sampling VCM in comming days.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.3
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• pp.535-543
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• 2016

This study has been carried out to evaluate the CBR characteristics and the correlations among every soil properties of National road in Yeongnam region. Total of 480 soil samples were collected from 41 administrative districts for more than 30 years. Their physical and mechanical properties such as natural water content, the Atterberg limit, No. 200 sieve passing, the compaction test and the CBR test results were involved. The soils in Yeongnam region, SM, SC, SP and CL by USCS have predominated approximately 79%. The test results show that average CBR values of gravel and sand range from 12.7% to 20.3% and those of silt and clay range from 4.8% to 7.1%. It means that average CBR values of fine grained soils are less than a half of coarse grained one. Natural water content, No. 200 sieve passing, optimum moisture content and maximum dry density of soils are well correlated with CBR values. Especially, it presents that No. 200 sieve passing is the best correlation factor with CBR value. If consider the partition off this region into 6 zones of classified by mother rock, the correlation between CBR value and every soil properties tends to increase. It is suggested that tables, figures and the regressions described in this paper may be available for designers and engineers to understand the characteristics of an embankment materials in Yeongnam region.

• Journal of Korean Society of Environmental Engineers
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• v.39 no.6
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• pp.325-331
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• 2017

Adsorption experiments of carbon dioxide were performed on ZSM5 and Molecular Sieve 13X (MS13X) impregnated with Monoethanol Amine (MEA). Adsorption efficiency of $CO_2$ was investigated in a U type packed column with GC/TCD. The adsorption capacities of adsorbents are estimated in the temperature range of $30-80^{\circ}C$. The modified adsorbents was characterized by BET surface area, $N_2$ adsorption/desorption isotherms, X-ray diffraction and FT-IR. Surface analysis results showed that the impregnation method did not affect the crystallinity of any adsorbents. BET surface area of the MS13X impregnated amine decreased to $19.945m^2/g$ from $718.335m^2/g$. These reults showed that amine molecules were filled with the pore volume in MS13X, as a results restricting access of nitrogen into the pores. The MEA modified MS13X showed improvement in $CO_2$ adsorption capacity over the ZSM5 impregnated with MEA. The MS13X-MEA showed the highest adsorption capacity due to physical adsorption and chemical adsorption by amino-group content. This results also showed that adsorption capacity of MS13X-MEA increases with the temperature range of $60-80^{\circ}C$ compared with pristine MS13X.

• Membrane Journal
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• v.23 no.5
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• pp.332-342
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• 2013

In the present study, carbon molecular sieve (CMS) hollow fiber membranes were prepared by carbonizing a methyl imide hollow fiber precursor, which was spun by non-solvent induced phase separation process. And effects of carbonization parameters such as pre-oxidation, pyrolysis, and post-oxidation on the gas permeation were systematically investigated. CMS membrane having the highest gas flux was obtained by carbonizing the precursor through a combined process of air pre-oxidation at $250^{\circ}C$ for 2h, nitrogen pyrolysis at $550^{\circ}C$ for 2h, and oxygen post-oxidation at $250^{\circ}C$ for 2h. The optimized membrane showed a considerable gas permeance : the $H_2$, He, $CO_2$ permeances were 69.72, 35.61, 31.01 GPU, respectively, and the $O_2$ and $N_2$ permeances were ignorable. Therefore, it was clear that the prepared CMS hollow fiber membrane was a promising membrane for recovering small gases such as hydrogen and hellium and carbon dioxide.

• Membrane Journal
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• v.26 no.3
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• pp.220-228
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• 2016

Carbon molecular sieve (CMS) hollow fiber membranes were prepared by carbonizing a polyimide precursor manufactured by non-solvent induced phase separation process. Gas separation performance of CMS hollow fiber membrane was investigated on the effect of three carbonization conditions. CMS membrane with the highest gas separation performance was obtained at the pyrolysis temperature of $250-450^{\circ}C$: $N_2$, $SF_6$, and $CF_4$ permeance were 20, 0.32, 0.48 GPU, respectively, and $N_2/SF_6$ and $N_2/CF_4$ selectivities were 62 and 42, respectively. In the $SF_6/CF_4/N_2$ mixture gas test, when the stage cut was 0.2, the recovery ratio of $SF_6$ and $CF_4$ was over 99% and 98%. $SF_6$ concentration ratio was 4.5 times higher than the $SF_6$ concentration at the feed side. From the results, it was concluded that CMS membrane was one of the promising membranes for recovery Perfluorocompound gases process.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.527-534
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• 2012

The adsorption dynamics of activated carbon (AC) and carbon molecular sieve (CMS) beds were studied to recover ethylene from FCC fuel gas. In this study, the FCC fuel gas used consisted of six-component mixture ($CH_4/C_2H_4/C_2H_6/C_3H_6/N_2/H_2$,32:15:14:2:12:25 vol.%). And the breakthrough experiments of adsorption and desorption were carried out. The breakthrough sequence in the AC bed was $H_2$ < $N_2$ < $CH_4$ < $C_2H_4$ < $C_2H_6$ while the sequence in the CMS bed was $H_2$ < $CH_4$ < $N_2$ < $C_2H_6$ < $C_2H_4$. The separation performance of the CMS bed during the adsorption step was lower than that of the AC bed. However, due to the characteristics of kinetic separation, the CMS bed could remove $CH_4/N_2$ as well asthe molecules that are larger than $C_2H_6$, which was not easy to be done by the AC bed. Since it was hard to regenerate the adsorption bed by simple depressurization, vacuum regeneration should be adopted. As a result, the pressure vacuum swing adsorption (PVSA) process, consisting of CMS pretreatment process and AC main process, was suggested to recover ethylene efficiently.

• Journal of the Korean Institute of Gas
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• v.13 no.6
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• pp.34-38
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• 2009

Nitrous oxide, which is used as an anesthetic gas, has been shown to be a chronic health hazard. It is necessary to monitor and control the nitrous oxide exposure of the operating theaters staff. In this study, N2O exposure level of the operating nurses is assessed with a GC-ECD. The nitrous oxide gas is collected on a molecular sieve 5A contained in a glass tube and desorbed for 12 hours at $100^{\circ}C$ in heating block. As a result of the test using GC-ECD, calibration curve's $R^2$ of $N_2O$ is 0.9992, LOD is $0.96{\mu}g$/injection, LOQ is $3.21{\mu}g$/injection, desorption efficiency is 94.78 4.50% in average and break through is within 10% compared with the concentration. The average concentration before operation is 5.12ppm and it is 42.3ppm during operation. There are a significant difference showing that the P value is lower than 0.05. Assessing exposure level to nitrous oxide based on nurses' working positions, the exposure levels do not show significant difference( P>0.005). And $N_2O$ in active sampling method is higher than passive sampling method(P<0.05).

• Membrane Journal
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• v.13 no.3
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• pp.182-190
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• 2003

Carbon molecular sieve (CMS) membranes were prepared by the pyrolysis of polyvinylpyrrolidone containing polyimide precursors. We have prepared the polymer precursors, pyrolyzed polymer and investigated the effect of pyrolyzing polymer on the characteristics of carbon structures and gas separation properties of the CMS membranes. Thermogravimetric analysis (TGA) showed the two-step decomposition of polymer precursor. First decomposition of the pyrolyzing polymer began around $400^{\circ}C$ while carbonizing polymer showed the decomposition around $550^{\circ}C$. The gas permeabilities through the CMS membranes were enhanced by the introduction of the pyrolyzing polymer and decreased with increased final pyrolysis temperature. The CMS membrane pyrolyzed at $550^{\circ}C$. derived from precursor containing 5wt% PVP as a pyrolyzing polymer showed gas permeability for $O_2$ of 808 Barrers [$10^{-10}cm^3 (STP)cm/cm^2scmHg]$ and $O_2/N_2$ selectivity of 7.