• Title/Summary/Keyword: SiCN

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Electrical Properties of MIM and MIS Structure using Carbon Nitride Films

  • Lee, Hyo-Ung;Lee, Sung-Pil
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.5
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    • pp.257-261
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    • 2006
  • Nano-structured carbon nitride $(CN_x)$ films were prepared by reactive RF magnetron sputtering with a DC bias at various deposition conditions, and the physical and electrical properties were investigated. FTIR spectrum indicated an ${alpha}C_3N_4$ peak in the films. The carbon nitride film deposited on Si substrate had a nano-structured surface morphology. The grain size was about 20 nm and the deposition rate was $1.7{\mu}m/hr$. When the $N_2/Ar$ ratio was 3/7, the level of nitrogen incorporation was 34.3 at%. The film had a low dielectric constant. The metal-insulator-semiconductor (MIS) capacitors that the carbon nitride was deposited as insulators, exhibited a typical C-V characteristics.

A Study on the Case of Quality Innovation with Building Evaluation Method for System Diagnosis (시스템 진단 평가 체계 구축을 통한 품질 혁신 사례 연구)

  • Ryou, In-Ho;Shin, Hyun-Jong;Yun, Kwang-Dong
    • 한국IT서비스학회:학술대회논문집
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    • 2007.05a
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    • pp.431-438
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    • 2007
  • SI 프로젝트에서 품질을 혁신하기 위해서는 시스템 생명 주기 각 단계에서 품질 관리 활동을 강화해야 할 뿐만 아니라 통합된 시스템 관점에서 각 계층(Layer)별, 요소(Component)별 특성을 고려하여 체계적인 시스템 진단 평가 활동을 수행할 필요성이 있다. 시스템 진단 평가 활동은 품질 이슈를 찾아내는 작업과 품질 이슈를 해결하는 작업이 톱니바퀴처럼 맞물려 수행되어야 한다. LG CNS는 프로젝트의 품질 이슈를 적기 진단하기 위해서 시스템 진단 평가 체계를 구축했으며, 프로젝트 현장에서 이를 적용하여 품질 혁신에 기여하고 있다.

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Using open source software to increase competency in overseas IT services (공개SW를 활용한 해외 IT서비스 경쟁력 강화)

  • Yang, Jae-Young;Kim, Kyung-Nam
    • 한국IT서비스학회:학술대회논문집
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    • 2006.11a
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    • pp.118-125
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    • 2006
  • 최근 공개SW를 활용한 IT서비스가 활성화되고 있으며, 대표적인 서비스 유형으로는 소프트웨어 개발, 소프트웨어 유지보수, SI 및 SM, 리포지토리 서비스가 있다. 공개SW의 대표적인 장점 및 기대효과로는 가격 경쟁력 향상과 개발 생산성 향상을 꼽을수 있다. 하지만 IT 서비스 업체에서 공개SW를 활용할 경우 라이센스, 유지보수, 품질 및 호환성 이슈에 대해 정확히 파악하고 사전에 준비해야 한다. LG CNS에서는 최근 해외시장에 공개SW를 적극적으로 활용하여 IT 서비스를 제공한 사례가 있으며, 해당 사례를 분석한 결과 공개SW를 IT 서비스에서 활용할 경우 실제로 소프트웨어 비용 절감을 통한 가격 경쟁력 제고 및 개발생산성 향상의 효과를 확인할 수 있다. 국내 IT서비스 업체가 상대적으로 공개SW에 대한 인식이 잘 형성되어 있는 해외 IT 서비스 시장에서 공개SW에 대한 이해를 바탕으로 주요 이슈에 대해 미리 준비하고 이를 적절히 활용한다면 경쟁력을 확보하는데 도움이 될 것이다.

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Fabrication of Ceramic Line Pattern by UV-Nanoimprint Lithography of Inorganic Polymers (무기고분자의 나노임프린트법에 의한 세라믹 선형 패턴의 제조)

  • Park Jun-Hong;Pham Tuan-Anh;Lee Jae-Jong;Kim Dong-Pyo
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.407-411
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    • 2006
  • The SiC-based ceramic nanopatterns were prepared by placing polydimethylsiloxane (PDMS) mold from DVD master on the spincoated polyvinylsilaeane (PVS) or allylhydridopolycaybosilane (AHPCS) as ceramic precursors to fabricate line pattern via UV-nanoimprint lithography (UV-NIL), and subsequent pyrolysis at $800^{\circ}C$ in nitrogen atmosphere. As the dimensional change of polymeric and ceramic patterns was comparatively investigated by AFM and SEM, the shrinkage in height was 38.5% for PVS derived pattern and 24.1% for AHPCS derived pattern while the shrinkage in width was 18.8% for PVS and 16.7% for AHPCS. It indicates that higher ceramic yield of the ceramic precursor resulted in less shrinkage, and the strong adhesion between the substrate and the pattern caused anisotropic shrinkage. This preliminary work suggests that NIL is a promissing route for fabricating ceramic MEMS devices, with the development on the shrinkage control.

Application Effects of Some Nitrogen Fertilizers Forms for the Growth and Yield of Rice Plant (몇가지 형태(形態)의 질소비료시비(窒素肥料施肥)가 수도(水稻)의 생육(生育) 및 수량(收量)에 미치는 영향(影響))

  • Park, Chang Keu;Yuk, Chang Su;Cho, Gwang Dong
    • Korean Journal of Soil Science and Fertilizer
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    • v.18 no.1
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    • pp.78-88
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    • 1985
  • Nitrogen fertilizer effectiveness on rice production was studied to evaluate the different forms and sources. Seven kind of nitrogen fertilizers were applied in two levels, 15 and 30 kg per 10a on Jinjubyeo (Japonica type) in silt loam paddy soil of pot cultivation. The results were summerized as follows; 1. pH in soils was decreased with enhancement of ammonium sulfate application in $NH_4-N$, but it was increased with times after nitric-acid application and PH change in soil was not remarkable when $NO_3-N$ with accessory component was applied. 2. $NH_4-N$ contents in soil were the lowest at 2 weeks after application in N 15kg/10a regardless of different sources of nitrogen fertilizer. $NO_3-N$, in N 30kg/10a, was decreased continuously until 4 weeks, while $NH_4-N$, Urea-N were at minimum during 2-3 weeks. 3. Growth of culm length and straw weight applied with AN (Ammonium Nitrate), AS (Ammonium Sulfate) and urea were superior to the form of nitrate. While NA (Nitric Acid), PN (Potassium Nitrate) and CN (Calcium Nitrate) plot of the $NO_3-N$ was the dominant fertilizers for root elongation. 4. Brown rice yields were increased dominantly by $NH_4-N$ application such as AS or AP than $NO_3-N$ pot. But the yields in case of $NO_3-N$ application CN, PN and NA were decreased. 5. N, P, Mg and Mn content of straw ranked the effectiveness of nitrogen forms as $NH_4-N$, Urea-N and $NH_4-N+NO_3-N$, while K, Ca and $SiO_2$ content of straw in $NO_3-N$ fertilizer plot were high while N, P, Mg, Mn, Fe and Mg were low. 6. Increament of nitrogen absorption in straw was stimulated by enhancement of phosphorous absorption and the growth and yield of rice plant were increased. Absorption of N, P, Ca and Mg was decreased by CN application. Absorption of N, P and Mg also was decreased by $NO_3-N$ application and N, P, Mg or Ca content were seemed to simulated the growth and yield of rice plant. 7. $SiO_2$, Zn and Fe contents of the root at harvest stage were higher than those of the straw. N, P, Mg, Mn, Zn and Fe contents were high in $NH_4-N$ and Urea treatment. While K, ca and $SiO_2$ contents, however, were high in $NO_3-N$ treatment.

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Consideration of Procurement System and Material Homogeneity for Lime and Clay using the Tombs within the King Muryeong and the Royal Tombs in Gongju, Korea (공주 무령왕릉과 왕릉원 내부에 사용한 석회 및 점토의 재료학적 동질성과 조달체계 검토)

  • Choi, Il Kyu;Yang, Hye Ri;Lee, Chan Hee
    • Economic and Environmental Geology
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    • v.55 no.5
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    • pp.447-463
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    • 2022
  • The lime and clay that used in the construction of the Tomb of King Muryeong and the Royal Tombs in Gongju are auxiliary materials, and are used joint and plaster materials for the wall to play a role of structural support. In this study, the homogeneity between the tombs and material characteristics were interpreted through quantitative analysis of lime and clay. As a result of microtexture and composition analysis, almost the same minerals were identified in each sample groups, and similar characteristics were shown in thermal analysis. Geochemically, it is confirmed that the behavior characteristics are very similar regardless of the tombs. The compositions is also confirmed high homogeneity in the diagrams of CaO-MgO-SiO2, RO2-(RO+R2O) correlations, A-CN-K and A-CNK-FM triangles. Therefore, it is interpreted that the clay used for the construction of the tomb complex was supplied from around area, and the raw materials of lime were produced using shell fragments of oyster family based on mainly composed of calcite. It is interpreted that the raw materials of lime were supplied from middens along the west coast of down the Geumgang river in Korean peninsula, but the consideration of the supply site, needs to be cross-validated through stable isotope analysis, use of carbonate rock and reproduction experiments.

The Analytic Gradient with a Reduced Molecular Orbital Space for the Equation-of-Motion Coupled-Cluster Theory: Systematic Study of the Magnitudes and Trends in Simple Molecules

  • Baek, Gyeong Gi;Jeon, Sang Il
    • Bulletin of the Korean Chemical Society
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    • v.21 no.7
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    • pp.720-726
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    • 2000
  • The analytic gradient method for the equation-of-motion coupled-cluster singles and doubles (EOM-CCSD) energy has been extended to employ a reduced molecular orbital (MO) space. Not only the innermost core MOs but also some of the outermost virtua l MOs can be dropped in the reduced MO space, and a substantial amount of computation time can be reduced without deteriorating the results. In order to study the magnitudes and trends of the effects of the dropped MOs, the geometries and vibrational properties of the ground and excited states of BF, CO, CN, N2, AlCl, SiS, P2, BCl, AIF, CS, SiO, PN and GeSe are calculated with different sizes of molecular orbital space. The 6-31 G* and the aug-cc-pVTZ basis sets are employed for all molecules except GeSc for which the 6-311 G* and the TZV+f basis sets are used. It is shown that the magnitudes of the drop-MO effects are about $0.005\AA$ in bond lengths and about 1% on harmonic frequencies and IR intensities provided that the dropped MOs correspond to (1s), (1s,2s,2p), an (1s,2s,2p,3s,3p) atomic orbitals of the first, the second, and the third row atoms, respectively. The geometries and vibrational properties of the first and the second excited states of HCN and HNC are calculated by using a drastically reduced virtual MO space as well as with the well defined frozen core MO space. The results suggest the possibility of using a very smalI MO space for qualitative study of valence excited states.

Isolatin and Quantitative Determination of 20-Hydroxyecdysone from Achyranthis Radix (우슬로부터 20-Hydroxyecdysone의 분리 및 함량분석)

  • Hwang, Ji-Hyun;Lee, Seung-Ho;Park, Jeong-Hill;Kang, Shin-Jung;Chang, Seung-Yeup;Lee, Kyong-Soon;Son, Kun-Ho
    • Korean Journal of Pharmacognosy
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    • v.30 no.3
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    • pp.335-339
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    • 1999
  • Separation and quantitative determination of 20-hydroxyecdysone from Achyranthis Radix has been conducted by using HPLC method. 20-hydroxyecdysone in a methanol extract from the raw drug was separated on a reverse phase column using a $CH_3CN-H_2O\;(18:82)$ solvent system and the average content is $0.0931{\pm}0.0048%$. For the preparation of authentic standard, we isolated 20-hydroxyecdysone from the roots of Achyranthes fauriei by $SiO_2$ and RP-18 column chromatography.

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Improvement of precision of three-dimensional ceramic microstructures employing silica nanoparticle-mixed precursor (나노 실리카분말의 충진효과를 이용한 극미세 3차원 세라믹 구조물 정밀화)

  • Lim T.W.;Park S.H.;Yang D.Y.;Pham Tuan Anh;Kim D.P.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.157-158
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    • 2006
  • A novel nanofabrication process has been developed using two-photon crosslinking (TPC) for the fabrication of three-dimensional (3D) SiCN ceramic microstructures applicable to high functional 3D devices, which can be used in harsh working environments requiring a high temperature, a resistance to chemical corrosion, as well as tribological properties. After sequential processes: TPC and pyrolysis, 3D ceramic microstructures are obtained. However, large shrinkage due to low-ceramic yield during the pyrolysis is a serious problem to be solved in the precise fabrication of 3D ceramic microstructures. In this work, silica nanoparticles were employed as a filler to reduce the amount of shrinkage. In particular, the ceramic microstructures containing 40 wt% silica nanoparticles exhibited relatively isotropic shrinkage owing to its sliding free from the substrate during pyrolysis.

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The Synthesis and Pore Property of Hydrogen Membranes Derived from Polysilazane as Inorganic Polymer (무기 고분자인 폴리실라잔을 이용한 수소 분리막의 합성 및 기공특성)

  • Kwon, Il-Min;Song, In-Hyuck;Park, Young-Jo;Lee, Jae-Wook;Yun, Hui-Suk;Kim, Hai-Doo
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.462-466
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    • 2009
  • We investigated the pore properties of inorganic membranes applied for hydrogen separation industry. Inorganic membranes were derived from polysilazanes. The thermal reactions involved were studied using thermogravimetry(TG) and IR spectroscopy(FTIR) of the solids. To determine the thermal effect of pore properties, polysilazanes were pyrolysed in inert atmosphere. Pore volume and BET surface area showed the maximum value at a pyrolysis temperature of $500^{\circ}C$. For amorphous SiCN membrane derived from polysilazanes, selectivity of $H_2/N_2$ was 4.81 at $600^{\circ}C$.