• Title/Summary/Keyword: Si absorption

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Fabrication and Characterization of a-Si:H Films by a Remote Plasma Enhanced CVD (Remote Plasma Enhanced CVD에 의한 수소화된 비정질 실리콘 박막의 제작 및 특성연구)

  • Yang, Young-Sik;Yoon, Yeer-Jean;Jang, Jin
    • Proceedings of the KIEE Conference
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    • 1987.07a
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    • pp.513-516
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    • 1987
  • Hydrogenated amorphous silicon (a-Si:H) films have been deposited, for thye first time, by a remote plasma chemical vapor deposition. The hydrogen radical play a important role to control the deposition rate, The bonded hydrogen content to silicon is independent of hydrogen partial pressure in the plasma. Optical gap of deposited a-Si:H lies between 1.7eV and 1.8eV and all samples have sharp absorption edge. B-doped a-Si:H films by a RPECVD has a high doping efficiency compared with plasma CVD. The Fermi level of 100ppm B-doped film lies at 0.5eV above valence band edge.

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A Study on Synthesis Process of Zeolite 4A for Improvement of Properties as a Detergent Builder (세제 빌더용 제올라이트 4A의 물성 향상을 위한 합성공정 연구)

  • Cho, Yong-Sik;Lee, Won-Young;Hong, Ji-Sook;Suh, Jeong-Kwon;Ryu, Seung-Kon
    • Korean Chemical Engineering Research
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    • v.47 no.4
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    • pp.488-494
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    • 2009
  • Zeolite 4A was prepared by new synthesis method, 2-step crystallization, for enhancement of oil absorption capacity. Vietnamese sand and $NaAlO_2$ solution from natural bauxite were used as raw materials in stead of conventional cullet and $Al(OH)_3$ to reduced the processing cost. Some dissolved organics in $NaAlO_2$ solution were removed by activated carbon. Synthetic method was progressed by 1) reacting the raw materials at $55^{\circ}C$, 4 hr with the ratio of Si/Al to 1.15, and 2) reacting at $65^{\circ}C$, 5 hr with reducing the ratio of Si/Al to 0.98. New method can easily control the particle size, aggregation, surface polarity, and enhanced the whiteness of the products. The prepared zeolite 4A shows excellent oil absorption capacity(O.A.C>50 ml/100 g) as well as equal value with calcium ion exchange capacity, and proves the 2-step crystallization is the economic and effective process for the preparation of zeolite 4A.

The High Density Sintering of Green-emitting β-SiAlON:Eu Ceramic Plate Phosphor (녹색발광 β-SiAlON:Eu 세라믹 플레이트 형광체의 치밀화 소결)

  • Park, Young-Jo;Lee, Sung-Hoon;Jang, Wook-Kyung;Yoon, Chang-Bun;Yoon, Chul-Soo
    • Journal of the Korean Ceramic Society
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    • v.47 no.6
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    • pp.503-508
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    • 2010
  • $Eu^{2+}$-doped $\beta$-SiAlONs ($Si_{6-z}Al_zO_zN_{8-z}:Eu_y$) are recognized as promising phosphor materials to build an white LED for lighting application due to its excellent absorption/emission efficiency in the long wave length region. In this research, the fabrication of $\beta$-SiAlON:Eu plate phosphor by sintering was investigated with fixed Eu content(y) and varied composition of the host lattice(z). The addition of the activator $Eu_2O_3$ lead to enhanced densification by forming the transient liquid phase. The refinement of a composition by the calculated lattice parameter indicated that the measured composition of the fabricated specimens is nearly same to that of designed one. The single phase $\beta$-SiAlON:Eu plate with relative density of 96.4% was achieved by addition of 2 wt% CaO, which implies the possibility of full densification by adjusting the processing variables.

Effect of Si Contents on Structure and Mechanical Properties of Al-Si Alloy Metallic Foams (Al-Si 합금 발포금속의 조직 및 기계적 특성에 미치는 Si함량의 영향)

  • Kim, Byeong-Gu;Tak, Byeong-Su;Jeong, Seung-Reung;Jeong, Min-Jae;Hur, Bo-Young
    • Journal of Korea Foundry Society
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    • v.30 no.1
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    • pp.22-28
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    • 2010
  • Metal foam is a porous or cellular structure material and representative property is a very high porosity. Foamed materials have very special properties such as sound, vibration, energy and impact absorption capacity. Especially this properties are widely used for safety demands of architecture, auto and aircraft industry. But metal foam need to increased its compression strength and hardness. This study were researched about Al-Si alloy foams with variation amount of Si contents for their fabrication and properties such as porosity, cell structure, microstructure and mechanical properties. The result are that the range of pore size is 2~4 $mm{\phi}$, the high porosity are 88%, high yield strength is 1.8MPa, the strain ratio is 60~70% and vickers hardness is 33.1~50.6.

Accurate electronic structures for Ce doped SiAlON using a semilocal exchange-correlation potential

  • Yu, Dong-Su;Jeong, Yong-Jae
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.438-438
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    • 2011
  • White light-emitting diodes (LEDs), the so-called next-generation solid-state lighting, offer benefits in terms of reliability, energy-saving, maintenance, safety, lead-free, and eco-friendly. Recently, rare-earth-doped oxynitride or nitride compounds have attracted a great deal of interest as a photoluminescent material because of their unique luminescent property, especially for white LEDs applications. Ce doped ${\beta}$-SiAlON has been studied as a wavelength conversion phosphor in white LEDs thanks to its high absorption rates, high quantum efficiency, and excellent thermal stability. Previously researches were not enough to understand the detail mechanism and characteristics of ${\beta}$-SiALON. The bandgap structures and electronic structures were not exact due to limitation of calculation methods. In this study, to elucidate the Ce doping effect on the SiAlON system, accurate band structures and electronic structure of the Ce doped ${\beta}$-SiAlON was intensively investigated using density functional theory calculations. In order to get a better description of the band gaps, MBJLDA method were used. We have found a single Ce atom site in ${\beta}$-SiAlON super cell. Furthermore, the density of state, band structure and lattice constant were intensively investigated.

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Microwave Absorbance of Polymer Composites Containing SiC Fibers Coated with Ni-Fe Thin Films

  • Liu, Tian;Kim, Sung-Soo;Choi, Woo-cheal;Yoon, Byungil
    • Journal of Powder Materials
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    • v.25 no.5
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    • pp.375-378
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    • 2018
  • Conductive and dielectric SiC are fabricated using electroless plating of Ni-Fe films on SiC chopped fibers to obtain lightweight and high-strength microwave absorbers. The electroless plating of Ni-Fe films is achieved using a two-step process of surface sensitizing and metal plating. The complex permeability and permittivity are measured for the composite specimens with the metalized SiC chopped fibers dispersed in a silicone rubber matrix. The original non-coated SiC fibers exhibit considerable dielectric losses. The complex permeability spectrum does not change significantly with the Ni-Fe coating. Moreover, dielectric constant is sensitively increased with Ni-Fe coating, owing to the increase of the space charge polarization. The improvements in absorption capability (lower reflection loss and small matching thickness) are evident with Ni-Fe coating on SiC fibers. For the composite SiC fibers coated with Ni-Fe thin films, a -35 dB reflection loss is predicted at 7.6 GHz with a matching thickness of 4 mm.

A Synthesis of Spherical Shape $TiO_2-SiO_2$ Complex via Solvothermal Process and Thermal Properties at Non-Isothermal (용매열합성을 이용한 구형 $TiO_2-SiO_2$ 복합체 제조 및 열적특성)

  • Cho Tae-Hwan;Park Seong-Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.141-147
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    • 2005
  • Nanomaterial $TiO_2-SiO_2$ was synthesized by hydrolysis and condensation process using 2-propanol(2-PrOH) and was characterized by FT-IR, DSC, XRD and FE-SEM. FT-IR spectra were measured to investigate Ti-0-Si absorption peak. DSC thermal analysis results appllied to Ozawa equation were used to calculate to activation energy of crystallization. It was found that the changes of X-ray diffraction patterns and FWHM obtained XRD measurement depended on calcination temperature. In FE-SEM analysis, particle size changed by quantity changes of Ti-alkokide.

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Qantum Transition properties of Si in Electron Deformation Potential Phonon Interacting Qusi Two Dimensional System (준 2차원 시스템에서 전자 변위 포텐셜 상호 작용에 의한 Si의 양자 전이 특성)

  • Joo, Seok-Min;Cho, Hyun-Chul;Lee, Su-Ho
    • Journal of IKEEE
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    • v.23 no.2
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    • pp.502-507
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    • 2019
  • We investigated theoretically the quantum optical transition properties of qusi 2-Dinensinal Landau splitting system, in Si. We apply the Quantum Transport theory (QTR) to the system in the confinement of electrons by square well confinement potential. We use the projected Liouville equation method with Equilibrium Average Projection Scheme (EAPS). In order to analyze the quantum transition, we compare the temperature and the magnetic field dependencies of the QTLW and the QTLS on two transition processes, namely, the phonon emission transition process and the phonon absorption transition process. Through the analysis of this work, we found the increasing properties of QTLW and QTLS of Si with the temperature and the magnetic fields. We also found the dominant scattering processes are the phonon emission transition process.

Synthesis of NiO and TiO2 Combined SiC Matrix Nanocomposite and Its Photocatalytic MB Degradation

  • Zambaga, Otgonbayar;Jun Hyeok, Choi;Jo Eun, Kim;Byung Jin, Park;Won-Chun, Oh
    • Korean Journal of Materials Research
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    • v.32 no.11
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    • pp.458-465
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    • 2022
  • Interest in the use of semiconductor-based photocatalyst materials for the degradation of organic pollutants in a liquid phase has grown, due to their excellent performance and response to the light source. Herein, we fabricated a NiO-SiC-TiO2 ternary structured photocatalyst which had reduced bandgap energy, with strong activation under UV-light irradiation. The synthesized samples were examined using XRD, SEM, EDX, TEM, DRS, EIS techniques and photocurrent measurement. The results confirmed that the two types of metal oxides were well bonded to the SiC fiber surface. The junction of the new photocatalyst exhibited a large number of photoexcited electrons and holes. The holes tended to oxidize the water and form a hydroxyl radical, which promoted the decomposition of methylene blue. The close contact between the 2D SiC fiber and metal oxide semiconductors expanded the scope of absorption wavelength, and enhanced the usability of the ternary photocatalyst for the degradation of methylene blue. Among three synthesized samples, the NiO-SiC-TiO2 showed the best photocatalytic effect, and was considered to have excellent photoelectron transfer due to the synergy effect between the metal oxide and SiC.

Enhanced Photo Current in n-ZnO/p-Si Diode Via Embedded Ag Nanoparticles for the Solar Cell Application

  • Ko, Young-Uk;Yun, Ho-Jin;Jeong, Kwang-Seok;Kim, Yu-Mi;Yang, Seung-Dong;Kim, Seong-Hyeon;Kim, Jin-Sup;An, Jin-Un;Eom, Ki-Yun;Lee, Hi-Deok;Lee, Ga-Won
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.15 no.1
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    • pp.35-40
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    • 2015
  • In this study, an n-ZnO/p-Si heterojunction diode with embedded Ag nanoparticles was fabricated to investigate the possible improvement of light trapping via the surface plasmon resonance effect for solar cell applications. The Ag nanoparticles were fabricated by the physical sputtering method. The acquired current-voltage curves and optical absorption spectra demonstrated that the application of Ag nanoparticles in the n-ZnO/p-Si interface increased the photo current, particularly in specific wavelength regions. The results indicate that the enhancement of the photo current was caused by the surface plasmon resonance effect generated by the Ag nanoparticles. In addition, minority carrier lifetime measurements showed that the recombination losses caused by the Ag nanoparticles were negligible. These results suggest that the embedding of Ag nanoparticles is a powerful method to improve the performance of n-ZnO/p-Si heterojunction solar cells.