• Title/Summary/Keyword: Si 분포

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Porous silica ceramics prepared by sol-gel process-Effect of $H_2O/TEOS$ molar ratio- (솔-젤법에 의한 다공성 실리카 세라믹스의 제조-$H_2O/TEOS$ 몰비의 영향-)

  • Lee, Jin-Hui;Kim, Wha-Jung;Lee, Joon
    • Journal of the Korean Ceramic Society
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    • v.34 no.2
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    • pp.216-224
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    • 1997
  • Porous silica ceramics were prepared(with HCI catalyst) using H2O/TEOS molar ratios of 2.6~59.0, with the EtOH/TEOS ratio fixed. After preparing 9 kinds of sol, the followings were investigated; measurement of the gelation time, thermal analyses by TG/DTA, property analyses of the intermediates by FT-IR and X-ray diffractometry with dried samples, analyses of SiO2 polymer by FT-IR, the investigation of specific sur-face area and pore size distribution by N2-adsorption isotherm, and structural change of SiO2 polymer and pore morphology by TEM observation, with samples heat-treated to 50$0^{\circ}C$. In the concentrations of in-vestigated compositions and catalyst, gelation time showed a minimum at ca. 11 moles of water per one mole of TEOS, the highest degree of polymerization at ca. 8-18 moles, and the largest specific surface area at ca. 11 moles, which means that the polymerization proceeded fastest at ca. 11 moles of water. In con-clusion, the more water used, the faster the polymerization reaction up to ca. 11 moles, but more than ca. 11 moles of water caused retardation of gelation and resultant reduction of specific surface area.

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The Significant Caries Index of 12 Years Old in Korean (한국 12세 아동의 Significant Caries Index)

  • An, Eun-Suk;Han, Ji-Hyoung
    • Journal of dental hygiene science
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    • v.13 no.1
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    • pp.91-96
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    • 2013
  • The purpose of this study was to examine the possibility of the existence of high-risk groups of dental caries and influential factors for the high-risk groups, as there was a possibility that certain people might especially be at risk of suffering from dental caries when decayed, missing, and filled teeth index were analyzed, which were the typical indicators of dental caries. The data of the 4th National Health & Nutrition Survey for 2007, 2008 and 2009 were analyzed. Significant caries index (SiC index) were calculated, which were one of the representative devices to indicate high-risk groups of dental caries, and the SiC index and related factors were analyzed by using $x^2$ (chi-square) test. Besides, logistic regression analysis was utilized to find out influential factors, and a statistical package STATA 11.0 was employed. As a result of analyzing what factors would be linked to high-risk groups of dental caries, it's found that women were more likely to belong to high-risk groups than men (p<0.01). How the related factors affected the high-risk groups was analyzed, and it's found that those who didn't find themselves to be in good oral health were more likely to be classified into a high-risk group, and that those who brushed their teeth three times a more a day on a regular basis were more likely to belong to a high-risk group than the others who didn't (p<0.01). Thus, SiC index were calculated in this study to confirm the existence of dental caries high-risk groups, and what factors impacted on the high-risk groups was ascertained. It's required to implement efficient national policies to step up the promotion of national oral health based on the findings of the study.

Ecological Studies on Pal'tang River-Reservoir System in Korea. 4. Dynamics on Inorganic nutrients, POM and Phytoplankton Succession in the Lower Stream Kyungan (팔당호의 생태학적 연구 4. 경안천 하류의 영양염 및 입자태 유기물 거동과 식물플랑크톤의 천이)

  • Hong, Sung-Su;Auh, Yun-Yeol;Han, : Myung-Soo
    • Korean Journal of Ecology and Environment
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    • v.35 no.1 s.97
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    • pp.1-9
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    • 2002
  • In order to understand the relationship between succession of phytoplankton community structure and inorganic nutrients and particulate organic matters, a one station in Kyungan stream in Korea during the dry season was chosen. Water samplings were carried out once a week from 18 August to 13 November 1993. The DIN concentration distributed always abundantly, however, phosphate and silicate gradually reduced during the period. Phytoplankton community had a peak chlorophyll a concentration of $90.6\;{\mu}g/l$ in late summer (21 August 1993) and a second peak of $29.7\;{\mu}g/l$ in autumn (2 October 1993). After then late autumn was characterined by relatively low chlorophyll a concentration of $15{\sim}16\;{\mu}g/l$. Seasonal fluctuation of chlorophyll a concentrations were correlated with measured POC and PON concentrations: phytoplankton blooming may be a major factor controlling POC and PON concentrations in this ecosystem. Phosphate plays an most important role as a limiting factor of phytoplankton growth. However, when Si/P ratio low, silicate may be a more critical limiting factor than phosphate. Shifts of P-limitation to Si- limitation the succession of dominant phytoplankton can in duce: diatom to cyanobacteria such as Anabaena, Microcystis and Oscillatoria.

Properties of $(Pb,La)TiO_3$ Ferroelectric Thin Films by Sol-Gel Method for the Infrared Sensors (졸-겔법에 의해 제작된 적외선 센서용 $(Pb,La)TiO_3$ 강유전체 박막의 특성)

  • Seo, Gwang-Jong;Jang, Ho-Jeong;Jang, Ji-Geun
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.484-490
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    • 1999
  • $(Pb,La)TiO_3$(PLT) thin films were prepared on Pt/SiO$_2$/Si substrates by the sol-gel method and investigated the crystalline and electrical properties according to La concentration and post-annealing temperatures. The PLT films annealed at above $600^{\circ}C$ were exhibited the typical perovskite structures regardless of La contents. When the $(Pb,La)TiO_3$(PT) films were doped with La concentration up to 10mol%(PLT-10), the degree of z-axis orientation was greatly decreased from 63% to 26%. From AES depth profiles for the PLT-10 samples, no remarkable inter-reaction between PLT film and lower Pt electrode was found. The remanent polarization$(2Pr,Pr_+-Pr_-)$ were increased from $4\muC\textrm{cm}^2 to 16\muC\textrm{cm}^2$ as the annealing temperature increased from $600^{\circ}C to 700^{\circ}C$. This result may be ascribed to the improvement of crystallinity by the high temperature post-annealing. The dielectric constant$({\varepsilon}r)$ and tangent loss(tan$\delta$) of the PLT-10 films annealed at $650^{\circ}C$ were about 193 and 0.02, respectively with the pyroelectric coefficient($\gamma$) of around $4.0nC/\textrm{cm}^2{\cdot}^{\circ}C at 30^{\circ}C$.

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Vulnerability Assessment of the Air Pollution Using Entropy Weights : Focused on Ozone (엔트로피 가중치를 활용한 대기오염 취약성 평가 - 오존을 중심으로 -)

  • Lee, Sang-hyeok;Kang, Jung Eun;Bae, Hyun Joo;Yoon, Dong Keun
    • Journal of the Korean association of regional geographers
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    • v.21 no.4
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    • pp.751-763
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    • 2015
  • Both the selection of indicators and weights for them are critical issues in the vulnerability assessment. This study is to assess the air pollution vulnerability focused on ozone for 249 local jurisdictions using weights calculated by the entropy methodology and then examine the applicability of the methodology. We selected indicators for air pollution vulnerability assessment and standardized them. Subsequently, we calculated weights of each indicator using the entropy method and then integrated them into the vulnerability index. The exposure indicators consider meteorological and air pollution factors and the sensitivity of the local jurisdiction include variables on vulnerable areas and environments. The adaptive capacity contains socio-economic characteristics, health care capacities and air pollution managemental factors. The results show that Hwaseong-si, Gwangjin-gu, Gimpo-si, Gwangju-si, Gunpo-si are among the highest vulnerabilities based on the simple aggregation of indicators. And vulnerability-resilience (VRI) aggregation results indicates the similar spatial pattern with the simple aggregation outcomes. This article extends current climate change vulnerability assessment studies by adopting the entropy method to evaluate relative usefulness of data. In addition, the results can be used for developing customized adaptation policies for each jurisdiction reflecting vulnerable aspects.

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Effect of Si contents on Tensile-Shear Peak Load and Nugget Diameter in the Resistance Spot Welded of Dual Phase Steel for Automotive Body Applications (자동차 차체용 냉연 DP강 저항점용접부의 너깃경과 인장전단강도에 미치는 Si 함유량의 영향)

  • Kong, Jong-Pan;Park, Tae-Jun;Han, Tae-Kyo;Chin, Kwang-Geun;Kang, Chung-Yun
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.45-45
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    • 2009
  • 원가 측면에서 유리한 저항점용접(Resistance Spot Welding)이 차체 용접에 80%이상으로 가장 많이 적용되고 있다. 첨단고강도강(Advanced High Strength Steel)의 저항점용접성 및 용접부 특성에 미치는 공정 변수의 영향에 대한 연구결과는 많으나, 합금원소의 영향에 대해서는 전무하다. 특히, Si는 DP(Dual Phase)강에 첨가 시 균일한 마르텐사이트의 분포를 촉진하는 원소로 저항 점용접성 및 용접부 특성에 영향을 미칠 것으로 예상되며, 이에 대한 연구는 보고된바 없다. 본 연구에서는 냉연 DP강의 저항 점용접시 중요한 인자 중 하나인 너깃경과 전단인장강도에 미치는 Si함유량의 영향을 검토하였다. 사용된 강재 및 용접기는 1.2mm 두께의 Si함유량(0, 0.5, 1.0, 1.5wt%)이 다른 인장강도 780~1000MPa급 냉연 DP강과 단상 AC용접기를 사용하였다. 용접조건은 ISO 18278-2규격에 따라 가압력 4kA, 초기가압시간 40cycle, 유지시간 17cycle로 고정하고, 용접전류만 변화하여 용접을 실시하였다. 너깃경은 용접부 단면을 컷팅 후 폴리싱 하여, 광학현미경과 Image Pro plus를 이용하여 측정했으며, 인장시편규격은 JIS Z 3137를 이용하였다. Si함유량이 증가에 따라 스패터 발생 전류는 감소했고, 너깃경은 직선적으로 증가했다. Si함유량 증가에 따른 너깃경 증가 이유는 저항(R) 측정결과, Si함유량 증가에 따라 모재의 저항이 높아져, 따라서 입열량($Q=I^2Rt$)이 많아지기 때문으로 판단되었다. 인정전단강도는 Si함유량 증가에 따라 직선적으로 증가했다. 이러한 이유는 Si함유량 증가에 따라 너깃경이 증가되기 때문으로 판단되었고, 너깃경과 인장전단강도 사이에 직선적 관계(PL(kN)=$3.2N_{dia.}$-0.81, $R^2$=0.93)를 가지고 있었다. 파단양상은 Si함유량에 상관없이 5.4kA이하에서는 계면파단이 일어났고, 6.0kA이상에서는 풀 아웃 파단이 일어났다. 계면파단주원인은 용접부 가장자리에 지름이 약 $5{\mu}m$이하의 예리한 노치가 존재하여 노치응력집중과 HAZ계면 근처에 미접합부가 존재하기 때문으로 판단되었다. 6.0kA이상에서는 예리한 노치가 없었고, HAZ부가 완전히 접합되어 있기 때문에 풀 아웃 파단이 일어난 것으로 판단되었다. 따라서, Si함유량 증가에 따라 적정용접전류 구간은 감소했고, 너깃경은 직선적으로 증가했다. 또한, Si함유량 증가에 따라 인장전간강도는 증가 했으며, 너깃경과 인장전단강도 사이에 직선적 관계를 가지고 있었다. 파단 양상은 Si함유량에 상관없이 5.2kA이하에서는 계면파단이, 6.0kA이상에서는 풀 아웃 파단이 일어났다.

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The Characterization of Spherical Particles in S/G Sludge (S/G 슬러지 중 구형입자의 특성측정)

  • Pyo Hyung-Yeal;Park Yang-Soon;Park Sun-Dal;Park Yong-Joon;Park Kyoung-Kyun
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.129-136
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    • 2005
  • There should not be ion exchange resin particles in S/G sludge. The suspicious spherical resin particles observed in S/G sludge sample were characterized for particle size distribution under optical microscope using the micro-technique, for element analysis by the electron probe micro analysis (EPMA), and for molecular identification by the IR spectroscopy The particle sizes are distributed from 1 to 200 ${\mu}m$ for the sludge, while 40 to 500 ${\mu}m$ for the spherical resin particles. The results of the elemental analysis showed different major impurities: Si, Al, Mn, Cr, Ni, Zn and Ti for the sludge particles, while Si, Cu, Zn for the spherical resin particles. However, both particles contain Fe as a matrix of hematite ($Fe_{3}O_4$). IR spectrum of the spherical particles was quite different from that of ion exchange resins used in S/G system. These results indicate that the spherical particles are not related to ion exchange resin particles and formed by the process of the sludge formation.

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Flora of the Southeastern Areas of Gangwon-do (Donghae-si, Samcheok-si) (강원도 남동부 지역(동해시, 삼척시)의 식물상)

  • Han, Jun-Soo;Cheon, Kyeong-Sik;Kim, Kyung-Ah;Jung, Hee-Jin;Yoo, Ki-Oug
    • Korean Journal of Plant Taxonomy
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    • v.41 no.4
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    • pp.383-397
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    • 2011
  • This study was carried out to investigate the flora of the southeastern areas, including Donghae-si and Samcheok-si, of Gangwon-do. Vascular plants based on voucher specimens were summarized as 750 taxa, including 109 families, 394 genera, 642 species, 5 subspecies, 90 varieties, and 13 forms. Among the investigated 750 taxa, 17 Korean endemic, 38 rare plants and 147 specially designated plants by the Ministry of the Environment were also included. The naturalized plants were 28 taxa, and the percent of naturalized plant species was estimated as 3.7%. The life form of the investigated taxa was the H-R5-D4-e type. The usefulness of the plants of the 750 taxa listed consists of 284 taxa (37.9%) of edible plants, 232 taxa (30.9%) of medicinal plants, 124 taxa (16.5%) of pasture plants, 88 taxa (11.7%) of ornamental plants, 21 taxa (2.8%) of timber plants, 20 taxa (2.7%) of fiber plants, 7 taxa (0.9%) of miscellaneous plants and 3 taxa (0.4%) of industrial plants.

Analysis of the GIS-Based Water Cycle System for Effective Rainwater Management of Gyeongsangnam-do (경상남도의 효율적 빗물관리를 위한 GIS 기반 물순환 체계 분석)

  • Lee, Taek-Soon;Song, Bong-Geun;Han, Chi-Bok;Park, Kyung-Hun
    • Journal of the Korean Association of Geographic Information Studies
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    • v.14 no.2
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    • pp.82-95
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    • 2011
  • The objective of this paper is to analyze the GIS-based water cycle system: rainfall, evapotranspiration, surface run-off of Gyeongsanam-do for the effective rainwater management. The rainfall(1999~2008) analyzed by a spatial interpolation method, showed relatively higher amount in Hadong-gun, Sanchung-gun, and Sacheon-gun on the southwest coast than in Changnyeong-gun, Miryang-si, and Changwon-si in the mideast inland. The evapotranspiration was calculated by the three independent variables: air temperature, landuse, and NDVI(normalized difference vegetation index). The analysis showed that Namhae-gun had the highest evapotranspiration of 93.71mm, and Jinhae-si and Changwon-si had the lowest values of 81.78mm and 84.37mm. The surface run-off was analysed by a run-off equation based on the SCS hydrologic soil classification and landuse. The amount of surface run-off showed that Hadong-gun had the highest value, of 90.40mm, and Geochang-gun had the lowest, of 46.69mm. The analysis results of the GIS-based water cycle system will be used to support the establishment of the effective rainwater management plan in Gyeongasngnam-do.

New Analysis Approach to the Characteristics of Excimer Laser Annealed Polycrystalline Si Thin Film by use of the Angle wrapping (엑시며 레이저에 의해 형성된 다결정 실리콘 박막의 Angle wrapping에 의한 깊이에 따른 특성변화)

  • Lee, Chang-U;Go, Seok-Jung
    • Korean Journal of Materials Research
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    • v.8 no.10
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    • pp.884-889
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    • 1998
  • Amorphous silicon films of large area have been crystallized by a line shape excimer laser beam of one dimensional scanning with a gaussian profile in the scanning direction. In order to characterize the crystalline phase transition of thickness variables in excimer laser annealing(ELA), angle wrapping method was used. And also to characterize the residual stresses of crystalline phase transition in the case of angle wrapped-crystalline silicon on corning 7059 glass, polarized raman spectroscopies were measured at various laser energy density and substrate temperature. The residual stress varies from $9.0{\times}10^9$ to $9.9{\times}10^9$, and from $9.9{\times}10^9$ to $1.2{\times}10^10$dyne/${cm}^2$ of the substrate temperature at room temperature and varies from $8.1{\times}10^9$ to $9.0{\times}10^9$, and from $9.0{\times}10^9$ to $9.9{\times}10^9$dyne/${cm}^2$ of the substrate temperature at $400^{\circ}C$ as a function of direction from surface to substrate. According to the direction from the surface in liquid phase to the interface and from the interface to near the substrate in solid phase of recrystallized Si thin film, respectively. Thus, the stress is increased from(Liquid phase to solid phase) with phase transition.

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