• Korean Chemical Engineering Research
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• v.45 no.6
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• pp.582-590
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• 2007

In view of the analysis of the phenomena and the prediction of the performance, mathematical modelling and simulation of a high temperature pilot reactor for water gas shift reaction (WGSR) has been carried out. Multiscale simulation incorporated computational fluid dynamics (CFD) technique, which has the capability to deal with the reactor shape, fluid and energy transport with extensive degree of accuracy, and process modeling technique, which, in turn is responsible for reaction kinetics and mass transport. This research employed multiscale simulation and the results were compared with those from process simulation. From multiscale simulation, the maximum conversion of was predicted approximately 0.85 and the maximum temperature at the reactor was calculated 720 K, resulting from the heat of reaction. Dynamic simulation was also performed for the time transient profile of temperature, conversion, etc. Considering the results, it is concluded that multiscale simulation is a safe and accurate technique to predict reactor behaviors, and consequently will be available for the design of commercial size chemical reactors as well as other commercial unit operations.

• Applied Chemistry for Engineering
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• v.25 no.2
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• pp.204-208
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• 2014

This study investigated the effect of hydrogen permeance and selectivity, catalyst amount, $H_2O/CO$ ratio in a feed stream, and Ar sweep gas on the performance of a water gas shift reaction in a membrane reactor. It was observed that a minimum hydrogen selectivity of 100 was needed in a membrane reactor to obtain a hydrogen yield higher than the one at equilibrium and the hydrogen yield enhancement gradually decreased as the hydrogen permeance increased. The CO conversion in a membrane reactor initially increased with the catalyst amount and reached a plateau later for a membrane reactor with a low hydrogen permeance while the high CO conversion independent of a catalyst amount was observed for a membrane reactor with a high hydrogen permeance. For the $H_2O/CO$ ratio in a feed stream higher than 1.5, a hydrogen permeance had little effect on the CO conversion in a membrane reactor and it was found that a minimum Ar molar flow rate of $6.7{\times}10^{-6}mol\;s^{-1}$ was needed to achieve the CO conversion higher than the one at equilibrium in a membrane reactor.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.5
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• pp.494-502
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• 2016

A 1-dimensional heterogeneous reactor model with the gas-solid interfacial phase gradients was developed for the simulation of the packed bed reactor where the exothermic reversible water gas shift reaction for the natural gas steam reformed gas was proceeding in adiabatic mode. Experimental results obtained over the WGS catalyst, C18-HA, were best simulated when the frequency factor of the reaction rate constant was adjusted to a half the value reported over another WGS catalyst, EX-2248, having the same kinds of active components as the C18-HA. For the reactor of the inside diameter 158.4 mm and the bed length 650 mm, the optimum feeding temperature of the reformed gas was simulated to be $194^{\circ}C$, giving the lowest CO content in the product gas by 1.68 mol% on the basis of dried gas. For reactors more extended in the bed length, the possible lowest CO content in the product gas with the optimum feeding temperature of the reformed gas were suggested.

• Nuclear Engineering and Technology
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• v.34 no.2
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• pp.176-185
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• 2002

A 4-bundle shift refuelling method of CANDU6 F/H (Fuel Handling) System is analyzed to assess the operational flexibility and capacity of F/H system. The current 8-bundle shift refuelling scheme requires to refuel eight fuel bundles from a single fuel channel, and to refuel 14 fuel channels in a week on average assuming that the reactor is in a steady state. The analysis showed that the 4-bundle shift refuelling method increases F/M (Fuelling Machine) duty cycle and operator load. However, the fuellin’g method change from the 8- to 4-bundle shift refuelling ill not require additional team of operators. A marginal increase in the maintenance cost may be resulted in by the change of fuelling method and the increase of fatigue usage factors requires some components to be replaced during the FM lifetime.

• Nuclear Engineering and Technology
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• v.44 no.5
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• pp.543-550
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• 2012

The decrease in the fracture toughness of ferritic steels in a reactor pressure vessel is an important factor in determining the lifetime of a nuclear power plant. A surveillance program has been in place in Korea since 1979 to assess the structural integrity of RPV steels. In this work, the surveillance data were collected and analyzed statistically in order to derive the empirical relationship between the embrittlement and strengthening of irradiated reactor pressure vessel steels. There was a linear relationship between the yield strength change and the transition temperature shift change at 41 J due to irradiation. The proportional coefficient was about $0.5^{\circ}C$/MPa in the base metals (plate/forgings). The upper shelf energy decrease ratio was non-linearly proportional to the yield strength change, and most of the data lay along the trend curve of the US results. The transition regime temperature interval, ${\Delta}T_T$, was less than the US data. The overall change from irradiation was very similar to the US results. It is expected that the results of this study will be applied to basic research on the multiscale modeling of the irradiation embrittlement of RPV materials in Korea.

• Nuclear Engineering and Technology
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• v.49 no.5
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• pp.1109-1112
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• 2017

The precise prediction of radiation embrittlement of aged reactor pressure vessels (RPVs) is a prerequisite for the long-term operation of nuclear power plants beyond their original design life. The expiration of the operation licenses for Korean reactors the RPVs of which are made from SA533B-1 plates and welds is imminent. Korean regulatory rules have adopted the US Nuclear Regulatory Commission's transition temperature shift (TTS) models to the prediction of the embrittlement of Korean reactor pressure vessels. The applicability of the TTS model to predict the embrittlement of Korean RPVs made of SA533B-1 plates and welds was investigated in this study. It was concluded that the TTS model of 10 CFR 50.61a matched the trends of the radiation embrittlement in the SA533B-1 plates and welds better than did that of Regulatory Guide (RG) 1.99 Rev. 2. This is attributed to the fact that the prediction performance of 10 CFR 50.61a was enhanced by considering the difference in radiation embrittlement sensitivity among the different types of RPV materials.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.4
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• pp.324-330
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• 2018

In this study a numerical study was conducted to show flow, temperature and gas distributions in a high temperature CO shift reactor which was designed specially for energy saving and then evaluated with the related experiment. Mole fractions of syngas at the end of the catalyst bed were predicted with various assumed pre-exponential factors, were compared with the corresponding experimental results and $10^8$ was finally selected as the value. With the selection, a base case was examined. It was calculated that the inlet duct attached asymmetrically to the CO shift reactor affects on the distribution of the upward momentum (+z directional). In addition, CO conversion ratio is achieved up to 90% in the catalyst bed and especially it reached up to 70% at the initial part of catalyst bed.

• Membrane Journal
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• v.20 no.3
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• pp.228-234
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• 2010

In this study, dynamic simulation of membrane reactor was performed for water gas shift reaction and temperature, hydrogen concentration, etc. were investigated as a function of time and position. Simulation results indicated that differences of hydrogen concentration, hydrogen partial pressure, and temperature in the radial direction, were larger in the entrance than in the exit. In addition, the hydrogen flux was the largest in the entrance, where the hydrogen partial pressure difference was the largest, and the conversion of carbon monoxide in the exit was about 0.65.

• Journal of Welding and Joining
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• v.9 no.4
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• pp.60-68
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• 1991

The weld quality of end cap welds in Pressurized Heavy Water Reactor (PHWR) Fuel is extremely important for the fuel performance in the nuclear reactor. The quality of resistance upset welds is currently evaluated mainly by the metallographic examination although it reveals only two weld cross-sections in a circumference welds. This investigation was, firstly, carried out to determine whether the ultrasonic examination would be applied to detect weld defects in the end cap welds and, secondly, to measure the mechanical strength of upset butt welds as a function of phase shift percentage. The major results obtained in this study are as follows: 1. The weld current and amount of upset shrinkage linearly increased with increasing the phase shift percentage. 2. Above the phase shift 55%, the defects in the welds were completely eliminated with increasing the phase of sound weld was over the thickness of cladding tube. 3. The ultrasonic testing well detected such defects in the end cap welds as upset external crack, upset split, corner crack and irregular weld flash comparing with the results of metallography. 4. The micro-fissure in the corner of the end cap welds was reliably detected by ultrasonic testing. 5. The mechanical strength in the welds increased with increasing phase shift percentage but the fracture did't occur in the welds above 55%.

• Journal of the Korean Institute of Gas
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• v.8 no.3 s.24
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• pp.16-23
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• 2004

A membrane reactor concept, which combines the typical characteristics of chemical reaction with separation process, has been analyzed and simulated in this study. The advantages of the use of a membrane reactor include chemical equilibrium shift towards higher reactant conversion and purer product than the traditional reactors. A membrane reactor model which incorporates a catalytic reaction zone and a separation membrane is proposed. The water-gas shift reaction to produce hydrogen was chosen as a model reaction to be investigated. The membrane reactor is divided into smaller parts by number of n and each part (named cell), which contains both reaction and product separation function is modeled. One of the membrane outlet streams is connected to the next cell, which is repeated up to the last cell. The simulation results can be used for various purposes including decision of optimum operating condition and membrane reactor design.