• 대한치과교정학회지
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• 제42권1호
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• pp.17-22
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• 2012

Objective: To study and compare the effects of different demineralization-inhibition methods on the shear bond strength (SBS) and fracture mode of an adhesive used to bond orthodontic brackets to demineralized enamel surfaces. Methods: Eighty freshly extracted, human maxillary premolars were divided into 4 equal groups and demineralized over the course of 21 days. Brackets were bonded to the demineralized enamel of teeth in Group 1. In Group 2, bonding was performed following resin infiltration ($ICON^{(R)}$, DMG, Hamburg, Germany). Before bonding, pre-treatment with acidulated phosphate fluoride (APF) or solutions containing casein phosphopeptide-amorphous calcium phosphate with 2% neutral sodium fluoride (CPP-ACP/wF) was performed in Groups 3 and 4, respectively. The SBS values of the brackets were measured and recorded following mechanical shearing of the bracket from the tooth surface. The adhesive remnant index (ARI) scores were determined aft er the brackets failed. Statistical comparisons were performed using one-way ANOVA, Tukey's post-tests, and G-tests. Results: Significant differences were found in some of the intergroup comparisons of the SBS values (F = 39.287, p < 0.001). No significant differences were found between the values for the APF-gel and control groups, whereas significantly higher SBS values were recorded for the resin-infiltrated and CPP-ACP/wF-treated groups. The ARI scores were also significantly different among the 4 groups (p < 0.001). Conclusions: Tooth surfaces exposed to resin infiltration and CPP-ACP/wF application showed higher debonding forces than the untreated, demineralized surfaces.

• 마이크로전자및패키징학회지
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• 제20권4호
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• pp.7-11
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• 2013

As thermosonic ball bonding is developed for more and more advanced applications in the electronic packaging industry, the control of process stresses induced on the integrated circuits becomes more important. If Cu bonding wire is used instead of Au wire, larger ultrasonic levels are common during bonding. For advanced microchips the use of Cu based wire is risky because the ultrasonic stresses can cause chip damage. This risk needs to be managed by e.g. the use of ultrasound during the impact stage of the ball on the pad ("pre-bleed") as it can reduce the strain hardening effect, which leads to a softer deformed ball that can be bonded with less ultrasound. To find the best profiles of ultrasound during impact, a numerical model is reported for ultrasonic bonding with capillary dynamics combined with a geometrical model describing ball deformation based on volume conservation and stress balance. This leads to an efficient procedure of ball bond modelling bypassing plasticity and contact pairs. The ultrasonic force and average stress at the bond zone are extracted from the numerical experiments for a $50{\mu}m$ diameter free air ball deformed by a capillary with a hole diameter of $35{\mu}m$ at the tip, a chamfer diameter of $51{\mu}m$, a chamfer angle of $90^{\circ}$, and a face angle of $1^{\circ}$. An upper limit of the ultrasonic amplitude during impact is derived below which the ultrasonic shear stress at the interface is not higher than 120 MPa, which can be recommended for low stress bonding.

• 대한치과보철학회지
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• 제43권4호
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• pp.415-425
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• 2005

Statement of problem : Fracture of composite resin core will be occulted by progress of crack. Bonding interface of different materials has large possibility of starting point of crack line. Therefore, the bond strength of glass fiber post to composite resin core is important for prevention of fracture. Purpose: This in vitro study tried to find out how to get the higher strength of glass fiber post to composite resin core through surveying the maximum load that fractures the post and cote complex. Materials and methods: 40 specimens made with glass fiber Posts(Style $post^{(R)}$, Metalor, Swiss) and composite resin core ($Z-100^{(R)}$, 3M, USA) were prepared and loaded to failure with push-out type shear-bond strength test in a universal test machine. The maximum fracture load and fracture mode were investigated in the specimens that were restored with four different surface treatments. With the data. ANOVA test was used to validate the significance between the test groups, and Bonferroni method was used to check if there is any significant statistical difference between each test group. Evely analysis was approved with 95% reliance. Results: On measuring the maximum fracture load of specimens, both the treatments of sandblasted and acid-etched one statistically showed the strength increase rather than the control group (p<0.005). The scanning electric microscope revealed that sand blasting made more micro-retention form not only on the resin matrix but on the glass fiber, and acid-etching contributed to increase in surface retention form, eliminated the inorganic particles in resin matrix. Specimen fracture modes investigation represented that sand blasted groups showed lower bonding failure than no-sand blasted groups. Conclusion: Referring to the values of maximum fracture load of specimens, the bonding strength was increased by sand blasting and acid-etching.

• Restorative Dentistry and Endodontics
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• 제28권4호
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• pp.314-325
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• 2003

이 연구의 목적은 수종 상아질 접착 시스템과 복합 레진 및 resin-modified glass ionomer를 상아질 표면에 접착하여 재료 및 상아질내 위치에 따른 미세전단결합강도를 측정, 비교하는 것이다. 상아질 접착 시스템으로는, 3-step인 Scotchbond Multi-Purpose Plus, 2-step인 Single Bond와 자가 부식형 시스템인 Clearfil SE Bond를, 1-step인 Prompt L-Pop을 사용하였다. 이와 함께 hybrid type의 복합 레진인 Clearfil AP-X와 2250을 사용하였으며 resin-modified glass ionomer로는 Fuji II LC를 사용하였다. 상악 소구치를 치아의 근원심 중앙부를 절단하여 상아질면을 노출시켰다. 5개 실험군으로 분류하고 상아질면을 위치에 따라 치관부의 occlusal $\frac{1}{3}$, middle $\frac{1}{3}$, cervical $\frac{1}{3}$과 치근부로 구분지어 시편을 부착하였다. 미세전단결합강도측정는 Universal testing machine(EZ-test; Shimadzu, Japan)에서 측정하였다. Occlusal 1/3부위에서는 SE가 가장 높은 값을, SM과 SB간에는 유의차가 없었으며, PL, GI순으로, Middle 1/3부위에서는 $SM{\;}{\geq}{\;}SE{\;}{\geq}{\;}SB{\;}{\geq}{\;}PL{\;}{\geq}{\;}GI$순으로, cervical 1/3부위에서는 SM, SE, SB간에 유의차가 없었다. Root dentin에서는 SM이 가장 높은 값을 보였으며 SE, PL, GI간에 유의차가 없었다. SE만이 치관부 상아질에 비해 치근부에서 유의할만한 결합강도의 감소를 나타냈다(p<0.05). GI는 치관부 상아질에서는 다른 군에 비해 유의성 있게 낮은 결합강도를 보였으나 치근부에서는 SE, PL과 유의차가 없었다.

• The Journal of Advanced Prosthodontics
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• 제7권2호
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• pp.85-92
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• 2015

PURPOSE. This study aimed to investigate the efficacy of cleaning solutions on saliva-contaminated zirconia in comparison to air-abrasion in terms of resin bonding. MATERIALS AND METHODS. For saliva-contaminated air-abraded zirconia, seven cleaning methods)-no contamination (NC), water-spray rinsing (WS), additional air-abrasion (AA), and cleaning with four solutions (Ivoclean [IC]; 1.0 wt% sodium dodecyl sulfate [SDS], 1.0 wt% hydrogen peroxide [HP], and 1.0 wt% sodium hypochlorite [SHC])-were tested. The zirconia surfaces for each group were characterized using various analytical techniques. Three bonded resin (Panavia F 2.0) cylinders (bonding area: $4.5mm^2$) were made on one zirconia disk specimen using the Ultradent jig method [four disks (12 cylinders)/group; a total of 28 disks]. After 5,000 thermocycling, all specimens were subjected to a shear bond strength test with a crosshead speed of 1.0 mm/minute. The fractured surfaces were observed using an optical and scanning electron microscope (SEM). RESULTS. Contact angle measurements showed that groups NC, AA, IC, and SHC had hydrophilic surfaces. The X-ray photoelectron spectroscopy (XPS) analysis showed similar elemental distributions between group AA and groups IC and SHC. Groups IC and SHC showed statistically similar bond strengths to groups NC and AA (P>.05), but not groups SDS and HP (P<.05). For groups WS, SDS, and HP, blister-like bubble formations were observed on the surfaces under SEM. CONCLUSION. Within the limitations of this in vitro study, some of the cleaning solutions (IC or SHC) were effective in removing saliva contamination and enhancing the resin bond strength.

• Restorative Dentistry and Endodontics
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• 제43권2호
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• pp.19.1-19.10
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• 2018

Objectives: This study investigated the effect of continuous application of 10-methacryloyloxydecyldihydrogen phosphate (MDP)-containing primer and luting resin cement on bond strength to tribochemical silica-coated yttria-stabilized tetragonal zirconia polycrystal (Y-TZP). Materials and Methods: Forty bovine teeth and Y-TZP specimens were prepared. The dentin specimens were embedded in molds, with one side of the dentin exposed for cementation with the zirconia specimen. The Y-TZP specimen was prepared in the form of a cylinder with a diameter of 3 mm and a height of 10 mm. The bonding surface of the Y-TZP specimen was sandblasted with silica-coated aluminium oxide particles. The forty tribochemical silica-coated Y-TZP specimens were cemented to the bovine dentin (4 groups; n = 10) with either an MDP-free primer or an MDP-containing primer and either an MDP-free resin cement or an MDP-containing resin cement. After a shear bond strength (SBS) test, the data were analyzed using 1-way analysis of variance and the Tukey test (${\alpha}=0.05$). Results: The group with MDP-free primer and resin cement showed significantly lower SBS values than the MDP-containing groups (p < 0.05). Among the MDP-containing groups, the group with MDP-containing primer and resin cement showed significantly higher SBS values than the other groups (p < 0.05). Conclusions: The combination of MDP-containing primer and luting cement following tribochemical silica coating to Y-TZP was the best choice among the alternatives tested in this study.

• 대한치과보철학회지
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• 제34권4호
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• pp.791-799
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• 1996

교정치료을 위해 발거된 소구치를 사용하며 레진에 고정한 후 직경 4mm이상의 법랑질 평면을 얻었다. 직경 4mm의 아크릴릭 봉을 길이 5mm로 해서 Ni-Cr 비귀금속 합금으로 주조한 후, 사용될 표면을 전기화학적 식각처리 하였다. 각 실험군당 시편 42개를 I군은 Panavia 21, II군은 Superbond, III군은 All-Bond로 세멘트 한 후 1일, 15일, 그리고 30일에 각 군당 14개의 시편을 임의로 취득하여 인스트론 만능시험기에 특별히 만든 Jig를 사용하여 거상하고 cross-head speed 1mm/min으로 전달결합강도를 측정하였다. 세멘팅한 후 1일에 측정한 전달결합강도는 Panavia-21의 I군에서 $32.7{\pm}9.9kg$중, Super-bond의 II군에서 $25.9{\pm}5.9kg$중, 그리고 All-Bond의 III군에서 $23.5{\pm}7.2kg$중의 순으로 나타났으며, I군이 II군과 III군에 대하여 통계학적인 유의성이 있었다(P<0.01). 세멘팅후 15일에 측정한 전단결합강도는 II군이 $34.6{\pm}10.4kg$중, I군에서 $23.1{\pm}8.7kg$중, 그리고 III군에서 $10.9{\pm}7.2kg$중으로 II군이 I과 III군에 대해, I군은 III군에 대해 통계학적 유의성이 있었다(P<0.01) 세민팅후 30일에 측정한 전달결합강도는 II군에서 $33.0{\pm}12.9kg$중, I군에서 $31.0{\pm}8.6kg$중, 그리고 III군에서 $13.6{\pm}6.6kg$중으로 II군과 I군이 III군에 대해 통계학적인 유의성이 있었다(p<0.01). 저장기간에 따른 전달결합강도 비교에서 III군에서 1일에서의 전단결합강도가 15일과 30일에서의 전단결합강도보다 통계학적으로 유의성 있게 높았다(P<0.01).

• 콘크리트학회논문집
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• 제14권5호
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• pp.766-773
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• 2002

본 연구에서는 습도 변화와 같은 물리적인 원인으로 보수체의 손상(표면 균열, 경계면 파괴)을 유발하는 표면 인장 응력과 기층과 보수층 단부 경계변의 연직 인장 응력 및 전단 응력이 해석적으로 조사되었다. 응력 계산 시에는 사용 재료의 비선형응력-변형률 곡선이 사용되었고, 특히 변형률 경화, 변형률 연화 특성이 고려되었다. 응력 계산은 보수층의 두께와 보수 재료를 변수로 하였다. 습도 변화에 의한 영향은 보수체가 장기간 공용된 후 수위 하강으로 인해 나타나는 현상(콘크리트 댐)과 보수 후 일정한 양생 기간 후에 거푸집을 제거했을 때 나타나는 현상의 두 가지 경우에 대해서 조사되었다 건조되기 전 보수체 표변의 초기 습도는 100%, 대기 습도는 55%로 가정하였고, 계산기간(양생＋건조기간)은 30일간으로 하였다. 상기 두 가지 경우에 대해서 응력을 계산한 결과, 보수체 표면에서는 일부 보수체(CM20, ECM25)에서 단지 변형률 연화 단계의 가상 균열이 발생되었다. 한편 단부 경계면에서는 양생 중에 부착 강도를 약간 상회하는 일부 보수체(CM20)를 제외하고는 부착 전단 파괴는 발생치 않았다. 습도 변화에서도 단부 경계면의 들뜸현상(Peel-Off)이 보수체 손상의 주요원인으로 나타났고, 이를 유발하는 연직 인장 응력은 공용 중에 건조되는 경우에는 보수층 두께 dO=1cm에서만 부착 강도보다 낮은 값을 유지하고, 보수 작업시 양생 후 대기에 노출되는 경우에는 1.5일 이내에 발현된 부착 강도를 초과하였다.

• The Journal of Advanced Prosthodontics
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• 제8권1호
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• pp.1-8
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• 2016

PURPOSE. The purpose of this study was to evaluate the efficacy of two different metal conditioners for non-precious metal alloys for the bonding of porcelain to a cobalt-chromium (Co-Cr) alloy. MATERIALS AND METHODS. Disk-shaped specimens ($2.5{\times}10.0mm$) were cast with Co-Cr alloy and used as adherend materials. The bonding surfaces were polished with a 600-grid silicon carbide paper and airborne-particle abraded using $110{\mu}m$ alumina particles. Bonding specimens were fabricated by applying and firing either of the metal conditioners on the airborne-particle abraded surface, followed by firing porcelain into 5 mm in diameter and 3 mm in height. Specimens without metal conditioner were also fabricated. Shear bond strength for each group (n=8) were measured and compared (${\alpha}=.05$). Sectional view of bonding interface was observed by SEM. EDS analysis was performed to determine the chemical elements of metal conditioners and to determine the failure modes after shear test. RESULTS. There were significant differences among three groups, and two metal conditioner-applied groups showed significantly higher values compared to the non-metal conditioner group. The SEM observation of the sectional view at bonding interface revealed loose contact at porcelain-alloy surface for non-metal conditioner group, however, close contact at both alloy-metal conditioner and metal conditioner-porcelain interfaces for both metal conditioner-applied groups. All the specimens showed mixed failures. EDS analysis showed that one metal conditioner was Si-based material, and another was Ti-based material. Si-based metal conditioner showed higher bond strengths compared to the Ti-based metal conditioner, but exhibited more porous failure surface failure. CONCLUSION. Based on the results of this study, it can be stated that the application of metal conditioner is recommended for the bonding of porcelain to cobalt-chromium alloys.

• Steel and Composite Structures
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• 제21권1호
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• pp.157-175
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• 2016

It was found that the lateral stiffness changes obvious at the transfer position of the section configuration from SRC to RC. This particular behavior leads to that the transfer columns become as the important elements in SRC-RC hybrid structures. A comprehensive study was conducted to investigate the seismic behavior of SRC-RC transfer columns based on a low cyclic loading test of 16 transfer columns compared with 1 RC column. Test results shows three failure modes for transfer columns, which are shear failure, bond failure and bend failure. Its seismic behavior was completely analyzed about the failure mode, hysteretic and skeleton curves, bearing capacity deformation ability, stiffness degradation and energy dissipation. It is further determined that displacement ductility coefficient of transfer columns changes from 1.97 to 5.99. The stiffness of transfer columns are at the interval of SRC and RC, and hence transfer columns can play the role of transition from SRC to RC. All specimens show similar discipline of stiffness degradation and the process can be divided into three parts. Some specimens of transfer column lose bearing capacity swiftly after shear cracking and showed weak energy dissipation ability, but the others show better ability of energy dissipation than RC column.