• Elastomers and Composites
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• v.37 no.1
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• pp.49-56
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• 2002

Polypropylene is oxidized with UV/ozone as a function of UV treatment time and ozone flow rate and its surface characteristics are investigated using contart angle measurements and XPS. The aging behavior of oxidized surface is investigated under air, water and ethylene glycol as the aging media. Adhesion strength is also investigated using a lap shear test. Polar surface energy increases with increasing UV/ozone treatment time as well as ozone flow rate. No polar surface energy change is observed under water aging, while under air aging it decreases significantly within 2-3 days and reaches the close value as that of the untreated PP. Adhesion strength increases with increasing UV/ozone treatment time as well as ozone flow rate.

• Tribology and Lubricants
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• v.35 no.3
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• pp.169-175
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• 2019

In lithium-ion batteries (LIBs), the stress induced by the volume change of an electrode during charge-discharge processes may often cause the mechanical integrity of the electrode to degrade. Polymer binders with enhanced mechanical properties are preferred for improved mechanical integrity and cycling stability of the electrode. In addition, given that sliding and shearing between the polymer binder and components in the electrode may readily occur, frictional and adhesion characteristics of the polymer binder may play a critical role in the mechanical integrity of the electrode. In this study, frictional and adhesion characteristics of polyacrylonitrile (PAN) and polyvinylidene fluoride (PVDF) were investigated using a colloidal probe atomic force microscope. Friction loops were obtained under various normal forces ranging from 0 to 159 nN in air and electrolyte and then the interfacial shear strengths of PAN and PVDF in air were calculated to be $1.4{\pm}0.5$ and $1.3{\pm}0.3MPa$, respectively. The results show that in electrolyte, interfacial shear strength of PAN decreased slightly ($1.2{\pm}0.2MPa$), whereas that of PVDF decreased drastically ($0.06{\pm}0.01MPa$). Decreases in mechanical properties and adhesion in electrolyte may be responsible for the decrease in interfacial shear strength in electrolyte. The findings from this study may be helpful in developing polymer binders to improve the mechanical integrity of electrodes in LIBs.

• Journal of the Korea Institute of Building Construction
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• v.16 no.3
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• pp.237-245
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• 2016

Structural performance and durability of ultra high performance concrete could demonstrate optimal performance when unity was kept. Accordingly, it is necessary to involve the characteristics and quantitative surface treatment at the same time in order to retain oneness of Ultra-High-Performance Concrete(UHPC) according to construction joint occurrence. Therefore, this study derives a reasonable surface treatment method in a material's point of view through the shear adhesion performance evaluation according to the construction joints surface processing method as a part for securing the adhesion performance of the construction joints when casting UHPC. 180 MPa of required average strength was used for mix of UHPC and surface treatment method was set to totally 7 level that MN, GR-10-0, GR-20-0, GR-30-0, SH-30-5, SH-30-10. After the specimen were manufactured to a size of $150{\times}150{\times}150mm$, Direct shear test was performed to evaluate the shear adhesion strength. As a result, it was confirmed that the adhesion performance was improved when executing a surface treatment for the construction joint interface and standard of failure mode of specimen was over Type C. Also, It was considered that interface of cross section and depth of concavo-convex should be concerned.

• Journal of the Korean institute of surface engineering
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• v.39 no.1
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• pp.1-8
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• 2006

In this study, effect of sputtering after plasma nitriding and before PVD coating on the microstucture, microhardness, surface roughness and the adhesion strength of CrN thin films were investigated. Experimental results showed that this sputtering process not only removed surface compound layer which formed during a plasma nitriding process but also induced an alteration of the surface of plasma nitrided substrate in terms of microhardness distribution and surface roughness, which in turn affected the adhesion strength of PVD coatings. After sputtering, microhardness distribution showed general decrease and the surface roughness became increased slightly. The critical shear stress measured from the scratch test on the CrN coatings showed an approximately twice increase in the binding strength through the sputtering prior to the coating and this could be attributed to a complete removal of compound layer from the plasma nitrided surface and to an increase in the surface roughness after sputtering.

• Polymer(Korea)
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• v.37 no.2
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• pp.184-195
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• 2013

Acrylic pressure sensitive adhesive (PSA) tapes were used for the automotive, the electrical and the electronic industries and the display module junction. In this study, the manufacture of high-strength structural tape used 2-ethylhexyl acrylate (2-EHA) and acrylic acid (AAC), and UV irradiation for photo-polymerization, and the semi-structural properties of acrylic PSA tape with the AAC content and inorganic filler $SiO_2$ content were investigated. The initial adhesion strength was lowered by the rigidity of molecule chains due to the use of AAC, and the adhesion strength increased with increasing wetting time. The wetability, contact angle, and SEM images of PSA tapes with various contents of AAC were determined. Without filler, the peel strength and dynamic shear strength of PSA tape showed inverse correlation but the peel strength and dynamic shear strength increased with increasing filler content. From these correlations the PSA tapes could be optimized for the applications requiring high performance.

• Journal of Welding and Joining
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• v.20 no.4
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• pp.498-504
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• 2002

Fluxless flip chip bonding process using plasma treatment instead of flux was investigated. The effect of plasma process parameters on tin-oxide etching characteristics were estimated with Auger depth profile analysis. The die shear test was performed to evaluate the adhesion strength of the flip chip bonded after plasma treatment. The thickness of oxide layer on tin surface was reduced after Ar+H2 plasma treatment. The addition of H2 improved the oxide etching characteristics by plasma. The die shear strength of the plasma-treated Sn-Pb solder flip chip was higher than that of non-treated one but lower than that of fluxed one. The difference of the strength between plasma-treated specimen and non-treated one increased with increase in bonding temperature. The plasma-treated flip chip fractured at solder/TSM interface at low bonding temperature while the fracture occurred at solder/UBM interface at higher bonding temperature.

• Journal of Adhesion and Interface
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• v.5 no.1
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• pp.21-28
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• 2004

In this work, glass fiber/nylon 6 and woven glass fiber/nylon 6 composites have been fabricated using glass fiber reinforcements sized with 3-chloropropyltrimethoxysilane(CTMS) having a chloropropyl organo-functional group in the molecular chain end. The interfacial shear strength of glass fiber/nylon 6 composite was measured using a single fiber microbonding test and the interlaminar shear strength and the storage modulus of woven glass fabric/nylon 6 composites were measured using a short-warn shear test and a dynamic mechanical analysis, respectively, informing the effect of the concentration of CTMS on the properties. With increasing CTMS concentration, the interfacial properties of the composites were improved. The results on the interfacial shear strength, interlaminar shear strength, interlaminar failure pattern, and storage modulus with varying the CTMS concentration agree with each other.

• Journal of the Korean Wood Science and Technology
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• v.35 no.4
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• pp.38-44
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• 2007

As environmental issues is important thing, our study aims to develop natural adhesives made by rosin instead of synthesis adhesive with the formaldehyde emission. Natural adhesives were formulated to enhance curing speed and adhesion performances with various drying agent contents. Adhesion performances were evaluated with tack values measured by texture analyzer and shear strengths determined by single lap shear test. The adhesion performances of nature adhesives developed in this study and compared with those of overseas natural adhesives made by AURO, BioFa, Livos. Optimum drying agent formulation was Co 0.7 part, Zr 1.0 part, Ca 0.5 part, and Activ8 0.1 part. Shear strength of the adhesives manufactured by the optimum drying agent formulation was $93.2{\pm}19.1N/cm^2$.

• Journal of the Korean Society of Propulsion Engineers
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• v.5 no.3
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• pp.60-70
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• 2001

The study of compatible liner with ADP-505 propellant based PCP was performed. HTPB/DDl was chosen as a binder of liner in order to prohibit migration of nitroester plasticizer from propellant. The possible formulations for liner were screened by peel test of EPDM insulation/liner, propellant/liner and insulation/liner/propellant. Also, the adhesion tests including tension and shear were conducted. The adhesion of liner and propellant fumed out to be very good. The peel value was shown 1.5∼1.8 daN/cm, tensile force was 5.5∼6.0bar and shear force was 4.2∼5.0bar. In the samples of insulation/liner/propellant, they also have shown good adhesion properties. The peel, tensile and shear strength were 1.8 daN/cm, 5.0∼6.0bar and 4.5∼5.0bar, respectively.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.3
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• pp.335-341
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• 2020

This study examined the shear bond strength between the zirconia core and pressed lithium disilicate veneering ceramics. The Schmitz-Schulmeyer test method was used to investigate the core-veneer shear bond strength of industrially manufactured zirconia core ceramic (Zirtooth, HASS, Gangneung, Korea) and pressed veneer ceramic (IPS e.max Zirpress, Vita PM9, GC Initial IQ, HASS Rosetta SM) (N=40). Data were statistically analyzed using one-way ANOVA and Tukey's test (a=0.05). The fractured surfaces of the specimens were examined to determine the failure pattern using a digital microscope. The mean ± SD shear bond strength in MPa were 16.69±3.11, 14.21±3.63, 11.17±2.92, and 27.90±5.71 for IPS e.max Zirpress, VITA PM9, GC Initial IQ, and HASS Rosetta SM, respectively. The average shear bond strength was largest for HASS Rosetta SM, followed by IPS e.max Zirpress, Vita PM9, and GC Initial IQ(p<0.05). The digital microscopy examination of the fracture surface showed adhesive and cohesive failure in pressed lithium disilicate veneering ceramics. The use of lithium disilicate veneer ceramic produced a significantly higher shear bond strength.