• Title/Summary/Keyword: Shape Engineering

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Electrochemical Characteristics of the Silicon Thin Films on Copper Foil Prepared by PECVD for the Negative Electrodes for Lithium ion Rechargeable Battery (PECVD법으로 구리 막 위에 증착된 실리콘 박막의 이차전지 음전극으로서의 전기화학적 특성)

  • Shim Heung-Taek;Jeon Bup-Ju;Byun Dongjin;Lee Joong Kee
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.173-178
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    • 2004
  • Silicon thin film were synthesized from silane and argon gas mixture directly on copper foil by rf PECVD and then lithium ion batteries were prepared from them employed as the negative electrodes without any further treatment. In the present study, two different kinds of silicon thin films, amorphous silicon and copper silicide were prepared by changing deposition temperature. Amorphous silicon film was prepared below $200^{\circ}C$, but copper silicide film with granular shape was formed by the reaction between silicon radical and diffused copper ions under elevating temperature above $400^{\circ}C$. The amorphous silicon film gives higher capacity than copper silicide, but the capacity decreases sharply with charge-discharge cycling. This is possibly due to severe volume changes. The cyclability is improved, however, by employing the copper silicide as a negative electrode. The copper silicide plays an important role as an active material of the electrode, which mitigates volume change cause by the existence of silicon and copper chemical bonding and provides low electrical resistance as well.

Effects of Electrolyte Concentration on Growth of Dendritic Zinc in Aqueous Solutions (수용액중 아연 덴드라이트의 성장 반응에 미치는 전해질 농도의 영향)

  • Shin, Kyung-Hee;Jung, Kyu-Nam;Yoon, Su-Keun;Yeon, Sun-Hwa;Shim, Joon-Mok;Joen, Jae-Deok;Jin, Chang-Soo;Kim, Yang-Soo;Park, Kyoung-Soo;Jeong, Soon-Ki
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.4
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    • pp.390-396
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    • 2012
  • In order to understand the nature of dendritic zinc growth, electrochemical zinc redox reaction on nickel plate was investigated in aqueous solutions containing different concentrations, 0.2, 0.1 and 0.02 $mol{\cdot}dm^{-3}$ (M), of zinc sulfate ($ZnSO_4$) or zinc chloride ($ZnCl_2$). Zinc ion was efficiently reduced and oxidized on nickel in the high-concentration (0.2 M) solution, whereas relatively poor efficiency was obtained from the other low-concentration solutions (0,1 and 0.02 M). Cyclic voltammetry (CV) analysis revealed that the 0.2 M electrolyte solution decomposes at more positive potentials than the 0.1 and the 0.02 M solutions. These results suggested that the concentration of electrolyte solution and anion would be an important factor that suppresses the reaction of the zinc dendrite formation. Scanning Electron Microscopy (SEM) data revealed that the shape of dendritic zinc and its growing behavior were also influenced by electrolyte concentration.

Comparison of Pipeline and Clamshell Capping Technologies for the Remediation of Contaminated Marine Sediments (해양 오염퇴적물 정화를 위한 원통관과 클램쉘을 이용한 피복 기술의 비교)

  • Kang, Ku;Hong, Seong-Gu;Kim, Young-Kee;Park, Seong-Jik
    • Journal of Navigation and Port Research
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    • v.41 no.4
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    • pp.195-206
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    • 2017
  • In situ capping technology for marine sediment pollution control has never been applied in South Korea. In this study a pilot project for the capping was carried out in Busan N Harbor. Pipeline and clamshell capping technologies were implemented for the pollution control. Changes of capping shapes, sediment contamination, and the time and costs required for the two constructions were compared. Both the pipeline and clamshell technologies were found to satisfy the target thickness of 50 cm on average. However, the pipeline method did not operate sensitively in terms of change of the sea floor topography, resulting in an uneven shape and a thickness. Organic carbon and ignition loss quite decreased after the pipeline or the clamshell capping while pH showed no significant change. Organic and residual fraction of Cd, Ni, and Zn in the sediments appeared to decrease after all cappings. The pipeline method took a construction time four times as much as the clamshell method. The clamshell method was demonstrated to reduce the construction cost by about 40% compared with the pipeline method. However, a monitoring for all the parameters needs to be conducted at least two years in order to better evaluate an efficiency of the pollution control by these capping constructions.

Development Status and Research Direction in the Mineral Carbonation Technology Using Steel Slag (제철 슬래그를 이용한 광물 탄산화 기술의 개발 현황과 연구 방향)

  • Son, Minah;Kim, Gookhee;Han, Kunwoo;Lee, Min Woo;Lim, Jun Taek
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.141-155
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    • 2017
  • In the present paper, we investigated the development status of precipitated calcium carbonate (PCC) production using steel slag, which is one of mineral carbonation (MC) technologies, from the standpoint of $CO_2$ utilization. Principle, feature, and global and domestic development status of the mineral carbonation technology were discussed together with the overview of the production method and market of PCC. Mineral carbonation is known as stable and environmentally-friendly technology enabling economical treatment of industrials wastes. Typically, PCC is produced by the reaction of $CO_2$ with supernatant solution after Ca extraction from steel slag followed by the separation of solid and liquid. The development status of MC using steel slag is at the pilot stage (Slag2PCC at Aalto University), and there remains the process economics improvement for commercialization. Key technologies for the further development are efficient extraction of Ca ions from steel slag including impurities removal, valorization of PCC via shape and size control, usage development and value-addition of residual slag, and optimization of reaction conditions for continuous process setup, etc.

Shell Finite Element for Nonlinear Analysis of Reinforced Concrete Containment Building (철근콘크리트 격납건물의 비선형 해석을 위한 쉘 유한요소)

  • Choun Young-Sun;Lee Hong-Pyo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.19 no.1 s.71
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    • pp.93-103
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    • 2006
  • It is absolutely essential that safety assessment of the containment buildings during service life because containment buildings are last barrier to protect radioactive substance due to the accidents. Therefore, this study describes an enhanced degenerated shell finite element(FE) which has been developed for nonlinear FE analysis of reinforced concrete(RC) containment buildings with elasto-plastic material model. For the purpose of the material nonlinear analysis, Drucker-Prager failure criteria is adapted in compression region and material parameters which determine the shape of the failure envelop are derived from biaxial stress tests. Reissner-Mindlin(RM) assumptions are adopted to develop the degenerated shell FE so that transverse shear deformation effects is considered. However, it is found that there are serious defects such as locking phenomena in RM degenerated shell FE since the stiffness matrix has been overestimated in some situations. Therefore, shell formulation is provided in this paper with emphasis on the terms related to the stiffness matrix based on assumed strain method. Finally, the performance of the present shell element to analysis RC containment buildings is tested and demonstrated with several numerical examples. From the numerical tests, the present results show a good agreement with experimental data or other numerical results.

Experimental study on the behavior of the adjacent ground due to the sidewall failure in a shallow tunnel (얕은터널에서 측벽파괴시 주변지반 거동에 대한 실험적 연구)

  • Park, Chan Hyuk;Lee, Sang Duk
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.6
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    • pp.871-885
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    • 2017
  • Nowadays, the construction of tunnels with a shallow depth drastically in urban areas increases. But the effect of sidewall displacement in shallow tunnel on its behavior is not well known yet. Most studies on the shallow tunnel have been limited to the stability and the failure of the tunnel and the adjacent ground in plane strain state. Therefore, the model tests were conducted in a model ground which was built with carbon rods, in order to investigate the impact of the tunnel sidewall displacement on the lateral load transfer to the adjacent ground. The lateral displacement of the tunnel sidewall and the load transfered to the adjacent ground were measured in model tests for various overburdens (0.50D, 0.75D, 1.00D, 1.25D). As results, if the cover depth of tunnel was over a constant depth (0.75D) in a shallow tunnel, the tunnel sidewall was failed with a constant shape not depending on the tunnel cover depth and also not affected by the opposite side of the wall. But, if the cover depth of tunnel was under a constant depth (0.75D), the failure of the tunnel sidewall could affect the opposite sidewall. In addition, if the displacement of tunnel sidewall with 50% of the critical displacement occurred, the tunnel failure was found to be at least 75%. However, additional studies are deemed necessary, since they may differ depending on the ground conditions.

A Parallel Processing Technique for Large Spatial Data (대용량 공간 데이터를 위한 병렬 처리 기법)

  • Park, Seunghyun;Oh, Byoung-Woo
    • Spatial Information Research
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    • v.23 no.2
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    • pp.1-9
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    • 2015
  • Graphical processing unit (GPU) contains many arithmetic logic units (ALUs). Because many ALUs can be exploited to process parallel processing, GPU provides efficient data processing. The spatial data require many geographic coordinates to represent the shape of them in a map. The coordinates are usually stored as geodetic longitude and latitude. To display a map in 2-dimensional Cartesian coordinate system, the geodetic longitude and latitude should be converted to the Universal Transverse Mercator (UTM) coordinate system. The conversion to the other coordinate system and the rendering process to represent the converted coordinates to screen use complex floating-point computations. In this paper, we propose a parallel processing technique that processes the conversion and the rendering using the GPU to improve the performance. Large spatial data is stored in the disk on files. To process the large amount of spatial data efficiently, we propose a technique that merges the spatial data files to a large file and access the file with the method of memory mapped file. We implement the proposed technique and perform the experiment with the 747,302,971 points of the TIGER/Line spatial data. The result of the experiment is that the conversion time for the coordinate systems with the GPU is 30.16 times faster than the CPU only method and the rendering time is 80.40 times faster than the CPU.

Accelerated Convolution Image Processing by Using Look-Up Table and Overlap Region Buffering Method (Loop-Up Table과 필터 중첩영역 버퍼링 기법을 이용한 컨벌루션 영상처리 고속화)

  • Kim, Hyun-Woo;Kim, Min-Young
    • Journal of the Institute of Electronics Engineers of Korea SC
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    • v.49 no.4
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    • pp.17-22
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    • 2012
  • Convolution filtering methods have been widely applied to various digital signal processing fields for image blurring, sharpening, edge detection, and noise reduction, etc. According to their application purpose, the filter mask size or shape and the mask value are selected in advance, and the designed filter is applied to input image for the convolution processing. In this paper, we proposed an image processing acceleration method for the convolution processing by using two-dimensional Look-up table (LUT) and overlap-region buffering technique. First, based on the fixed convolution mask value, the multiplication operation between 8 or 10 bit pixel values of the input image and the filter mask values is performed a priori, and the results memorized in LUT are referred during the convolution process. Second, based on symmetric structural characteristics of the convolution filters, inherent duplicated operation region is analysed, and the saved operation results in one step before in the predefined memory buffer is recalled and reused in current operation step. Through this buffering, unnecessary repeated filter operation on the same regions is minimized in sequential manner. As the proposed algorithms minimize the computational amount needed for the convolution operation, they work well under the operation environments utilizing embedded systems with limited computational resources or the environments of utilizing general personnel computers. A series of experiments under various situations verifies the effectiveness and usefulness of the proposed methods.

In vitro Antibacterial Effect of Orthodontic Adhesives Mixed with Silver Nanoparticles

  • Choi, Kwon-Yong;Lee, Jong-Chan;Hwang, Yun-Chan;Chang, Seok-Woo;Kum, Kee-Yeon;Bae, Kwang-Shik;Lim, Bum-Soon;Paeng, Jun-Young;Kim, Eun-Cheol;Kwon, Ho-Beom;Kim, Young-Ho
    • Journal of Korean Dental Science
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    • v.5 no.1
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    • pp.7-12
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    • 2012
  • Purpose: To examine the antibacterial effectiveness of silver nanoparticles (SNP) mixed with commercial orthodontic adhesives. Materials and Methods: SNP was prepared by dissolving silver perchlorate in an organic solvent and reducing it with ultraviolet radiation. SNP was then mixed with four commercial orthodontic adhesives (Light Bond, Blugloo, Transbond XT, and Fuji Ortho LC) (0.05 wt %), which were then formed into disc-shape specimens ($8.0mm{\times}3.0mm$). Commercial orthodontic adhesives containing no SNP were used as the control groups. Specimens of the four experimental and four control groups were incubated with streptococcus mutans and the medium turbidity was assessed at 3, 6, 9, 12, and 24 hours after incubation. The agar diffusion test was also performed to examine the growth inhibition zone of these groups. The data were statistically analyzed using a Wilcoxon rank sum test and t-test with a Bonferroni's correction (P<0.05). Result: The SNP containing groups had a superior antibacterial effect compared to the control groups. In the agar diffusion test, the control groups without SNP did not produce an inhibition zone, whereas the SNP containing groups showed inhibition zone of 10~13 mm. Conclusion: The incorporation of SNP into orthodontic adhesives can inhibit cariogenic bacterial growth.

Development of a New Lumped-Mass Stick Model using the Eigen-Properties of Structures (구조물의 동적 고유특성을 이용한 새로운 집중질량모델 개발)

  • Roh, Hwa-Sung;Youn, Ji-Man;Lee, Hu-Seok;Lee, Jong-Seh
    • Journal of the Earthquake Engineering Society of Korea
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    • v.16 no.4
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    • pp.19-26
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    • 2012
  • For a seismic design or performance evaluation of a structure, an experimental investigation on a scale model of the structure or numerical analysis based on the finite element model is considered. Regarding the numerical analysis, a three-dimensional finite element analysis is performed if a high accuracy of the results is required, while a sensitivity or fragility analysis which uses huge seismic ground motions leads to the use of a lumped-mass stick model. The conventional modeling technique to build the lumped-mass stick model calculates the amount of the lumped mass by considering the geometric shape of the structure, like a tributary area. However, the eigenvalues of the conventional model obtained through such a calculation are normally not the same as those of the actual structure. In order to overcome such a deficiency, in this study, a new lumped mass stick model is proposed. The model is named the "frequency adaptive-lumped-mass stick model." It provides the same eigenvalues and similar dynamic responses as the actual structure. A non-prismatic column is considered as an example, and its natural frequencies as well as the dynamic performance of the new lumped model are compared to those of the full-finite element model. To investigate the damping effect on the new model, 1% to 5% of the critical damping ratio is applied to the model and the corresponding results are also compared to those of the finite element model.