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Synthesis of Core-Shell Silica Nanoparticles with Hierarchically Bimodal Pore Structures

  • Yun, Seok-Bon;Park, Dae-Geun;Yun, Wan-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.467-467
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    • 2011
  • Reflecting the growing importance of nanomaterials in science and technology, controlling the porosity combined with well-defined structural properties has been an ever-demanding pursuit in the related fields of frontier researches. A number of reports have focused on the synthesis of various nanoporous materials so far and, recently, the nanomaterials with multimodal porosity are getting an emerging importance due to their improved material properties compared with the mono porous materials. However, most of those materials are obtained in bulk phases while the spherical nanoparticles are one of the most practical platforms in a great number of applications. Here, we report on the synthesis of the core-shell silica nanoparticles with double mesoporous shells (DMSs). The DMS nsnoparticles are spherical and monodispersive and have two different mesoporous shells, i.e., the bimodal porosity. It is the first example of the core-shell silica nanoparticles with the different mesopores coexisting in the individual nanoparticles. Furthermore, the carbon and silica hollow capsules were also fabricated via a serial replication process.

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A Design and Implementation of Tetris Came System according to Score Calculation Method per Level (단계별 점수산출방식에 따른 테트리스 게임 시스템 설계 및 구현)

  • Lim Jong-Hyuk;Jeong Hwa-Young
    • Journal of Internet Computing and Services
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    • v.6 no.2
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    • pp.85-97
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    • 2005
  • At th first time in 1985, Tetris appeared, it became game that are loved to many users until now. Existent Tetris employed way to give score according to number of that is destroyed whenever line are destroyed, and give advantage about serial attack and so on, But, these score calculation method gave so fixed and simple pattern. In this paper, We design and implement the new tetris game System by score calculation method per level that Is different with existent method. That Is, this method is to compare present and before with number of destroyed line and give advantage in basis score, Also, It is going to permit strategic utilization of still more developed tetris than existent tetris using score calculation method per level.

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Development of Auto-tuning Temperature Controller with Multi-channel (다중채널을 갖는 오토튜닝 온도 제어기 개발)

  • Lee, Kap Rai
    • The Journal of the Convergence on Culture Technology
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    • v.4 no.4
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    • pp.419-427
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    • 2018
  • This paper designs and develops auto-tuning temperature controller with multi-channel, which controller with multi-channel could control a number of control system simultaneously. This controller has multi-channel input and output. And a number of control algorithms run in this controller simultaneously and independently. Firstly we present design method of controller with multi-channel. Secondly we design electrical circuit of sensor input, controller output and power control for temperature control board. And finally we design data protocol for serial communication to monitor control state and present verification of temperature controller with muiti-channel through field experiment.

Modified partial least squares method implementing mixed-effect model

  • Kyunga Kim;Shin-Jae Lee;Soo-Heang Eo;HyungJun Cho;Jae Won Lee
    • Communications for Statistical Applications and Methods
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    • v.30 no.1
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    • pp.65-73
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    • 2023
  • Contemporary biomedical data often involve an ill-posed problem owing to small sample size and large number of multi-collinear variables. Partial least squares (PLS) method could be a plausible alternative to an ill-conditioned ordinary least squares. However, in the case of a PLS model that includes a random-effect, how to deal with a random-effect or mixed effects remains a widely open question worth further investigation. In the present study, we propose a modified multivariate PLS method implementing mixed-effect model (PLSM). The advantage of PLSM is its versatility in handling serial longitudinal data or its ability for taking a randomeffect into account. We conduct simulations to investigate statistical properties of PLSM, and showcase its real clinical application to predict treatment outcome of esthetic surgical procedures of human faces. The proposed PLSM seemed to be particularly beneficial 1) when random-effect is conspicuous; 2) the number of predictors is relatively large compared to the sample size; 3) the multicollinearity is weak or moderate; and/or 4) the random error is considerable.

A GaAs MMIC Multi-Function Chip with a Digital Serial-to-Parallel Converter for an X-band Active Phased Array Radar System (X-대역 능동 위상 배열 레이더 시스템용 디지털 직병렬 변환기를 포함한 GaAs MMIC 다기능 칩)

  • Jeong, Jin-Cheol;Shin, Dong-Hwan;Ju, In-Kwon;Yom, In-Bok
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.6
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    • pp.613-624
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    • 2011
  • An MMIC multi-function chip for an X-band active phased array radar system has been designed and fabricated using a 0.5 ${\mu}m$ GaAs p-HEMT commercial process. A digital serial-to-parallel converter is included in this chip in order to reduce the number of the control interface. The multi-function chip provides several functions: 6-bit phase shifting, 6-bit attenuation, transmit/receive switching, and signal amplification. The fabricated multi-function chip with a relative compact size of 24 $mm^2$(6 mm${\times}$4 mm) exhibits a transmit/receive gain of 24/15 dB and a P1dB of 21 dBm from 8.5 GHz to 10.5 GHz. The RMS errors for the 64 states of the 6-bit phase shift and attenuation were measured to $7^{\circ}$ and 0.3 dB, respectively over the frequency.

VIP IMMUNOREACTIVITY IN THE RAT TRIGEMINAL GANGLION AFTER INFERIOR ALVEOLAR NERVE AXOTOMY (하치조신경 절단 후 흰쥐 삼차신경절에서 VIP-IR의 변화)

  • Kim, Heung-Joong;Park, Joo-Cheol;Kim, Hyun-Sub;Moon, Joo-Hoon
    • Restorative Dentistry and Endodontics
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    • v.25 no.2
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    • pp.225-234
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    • 2000
  • The purpose of this study was to investigate the distribution and fluorescene intensity of vasoactive intestinal polypeptide(VIP) immunoreactive cells in rat trigeminal ganglion after inferior alveolar nerve axotomy. The animals were divided into normal and two experimental groups. The experimental animals were sacrificed at 14th and 28th day after inferior alveolar nerve axotomy. The trigeminal ganglion was removed and immersed in the 4% paraformaldehyde-0.2% picric acid in 0.1M phosphate buffer. Serial frozon sections about $16{\mu}m$ in thickness were cut with a cryostat. The immunofluorescence staining was performed. The rabbit anti-VIP(1 : 8,000) was used as primary antibody and fluorescene isothiocynate(FITC)-conjugated anti-rabbit IgG(1 : 80) as secondary antibody. The slides were observed under confocal laser scanning microscope. Three-dimensional images were constructed from 9 serial images(each $1{\mu}m$ in thickness) made by automatic optical sectioning. Unprocessed optical sections were obtained and stored on a optical disk. Color picture were printed by a video copy processor. The results were as follows; 1. The appearance of VIP immunoreactive cells in the mandibular part of trigeminal ganglion was 8.79${\pm}$1.99% in normal group and 39.16${\pm}$5.62% in 14 days, 16.25${\pm}$2.39% in 28 days after inferior alveolar nerve axotomy groups. 2. The relative fluorescence intensity of VIP immunoreactive cell bodies in the mandibular part of trigeminal ganglion was 134.40${\pm}$10.39 in normal group and 192.88${\pm}$14.06 in 14 days, 143.10${\pm}$5.02 in 28 days after nerve axotomy groups. Therefore, the relative fluorescence intensity of 14 days after nerve axotomy group was 43.3% higher than intensity of normal group. 3. In optical single section analysis of VIP immunoreactive cell bodies, white cell bodies(moderate fluorescence intensity) were the most abundant in normal and 28 days after nerve axotomy groups. Whereas, in 14 days after nerve axotomy group, red cell bodies(high fluorescence intensity) were the most abundant. 4. In optical serial section analysis of VIP immunoreactive cell bodies, red cell bodies(high fluorescence intensity) were observed in a part of the 9 sections of normal and 24 days after nerve axotomy groups. Whereas, red cell bodies were observed in all of the 9 sections of 14 days after nerve axotomy group. 5. The results indicates that number and fluorescence intensity of VIP immunoreactive cells were increased in the mandibular part of trigeminal ganglion following inferior alveolar nerve axotomy.

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Lung Function Trajectory Types in Never-Smoking Adults With Asthma: Clinical Features and Inflammatory Patterns

  • Kim, Joo-Hee;Chang, Hun Soo;Shin, Seung Woo;Baek, Dong Gyu;Son, Ji-Hye;Park, Choon-Sik;Park, Jong-Sook
    • Allergy, Asthma & Immunology Research
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    • v.10 no.6
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    • pp.614-627
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    • 2018
  • Purpose: Asthma is a heterogeneous disease that responds to medications to varying degrees. Cluster analyses have identified several phenotypes and variables related to fixed airway obstruction; however, few longitudinal studies of lung function have been performed on adult asthmatics. We investigated clinical, demographic, and inflammatory factors related to persistent airflow limitation based on lung function trajectories over 1 year. Methods: Serial post-bronchodilator forced expiratory volume (FEV) 1% values were obtained from 1,679 asthmatics who were followed up every 3 months for 1 year. First, a hierarchical cluster analysis was performed using Ward's method to generate a dendrogram for the optimum number of clusters using the complete post-FEV1 sets from 448 subjects. Then, a trajectory cluster analysis of serial post-FEV1 sets was performed using the k-means clustering for the longitudinal data trajectory method. Next, trajectory clustering for the serial post-FEV1 sets of a total of 1,679 asthmatics was performed after imputation of missing post-FEV1 values using regression methods. Results: Trajectories 1 and 2 were associated with normal lung function during the study period, and trajectory 3 was associated with a reversal to normal of the moderately decreased baseline FEV1 within 3 months. Trajectories 4 and 5 were associated with severe asthma with a marked reduction in baseline FEV1. However, the FEV1 associated with trajectory 4 was increased at 3 months, whereas the FEV1 associated with trajectory 5 was persistently disturbed over 1 year. Compared with trajectory 4, trajectory 5 was associated with older asthmatics with less atopy, a lower immunoglobulin E (IgE) level, sputum neutrophilia and higher dosages of oral steroids. In contrast, trajectory 4 was associated with higher sputum and blood eosinophil counts and more frequent exacerbations. Conclusions: Trajectory clustering analysis of FEV1 identified 5 distinct types, representing well-preserved to severely decreased FEV1. Persistent airflow obstruction may be related to non-atopy, a low IgE level, and older age accompanied by neutrophilic inflammation and low baseline FEV1 levels.

Parallel O.C. Algorithm for Optimal design of Plane Frame Structures (평면골조의 최적설계를 위한 병렬 O.C. 알고리즘)

  • 김철용;박효선;박성무
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2000.04b
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    • pp.466-473
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    • 2000
  • Optimality Criteria algorithm based on the derivation of reciprocal approximations has been applied to structural optimization of large-scale structures. However, required computational cost for the serial analysis algorithm of large-scale structures consisting of a large number of degrees of freedom and members is too high to be adopted in the solution process of O.C. algorithm Thus, parallel version of O.C. algorithm on the network of personal computers is presented in this Paper. Parallelism in O.C. algorithm may be classified into two regions such as analysis and optimizer part As the first step of development of parallel algorithm, parallel structural analysis algorithm is developed and used in O.C. algorithm The algorithm is applied to optimal design of a 54-story plane frame structure

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Change of Recognition Range According to Resonance Frequency of the 13.56MHz RFID Transponder (13.56MHz RFID 트랜스폰더의 공진 주파수에 따른 인식거리의 변화)

  • Yoon, Ki-Suk;Yang, Woon-Geun;Yoo, Hong-Jun
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.127-130
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    • 2005
  • In this paper, we investigated the change of recognition distance according to the resonance frequency of the transponder for the ISO 14443 Type A 13.56MHz RFID(Radio Frequency IDentification) system. We made thirteen transponders of the same size. The dimension of the transponder is $84.65mm{\times}53.00mm{\times}0.45mm$. We measured the resonance frequency by means of an inductive coupling. The measured resonance frequencies were between 12.9MHz and 17.3MHz. We measured the maximum distances where the transponder's USN(Unique Serial Number) was recognized and the subcarrier was observed. The measurement results show that we can obtain good performance when the Type A transponder has the resonance frequency around 14.2MHz for the given case.

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A Study on Word Recognition using sub-model based Hidden Markov Model (HMM 부모델을 이용한 단어 인식에 관한 연구)

  • 신원호
    • Proceedings of the Acoustical Society of Korea Conference
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    • 1994.06c
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    • pp.395-398
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    • 1994
  • In this paper the word recognition using sub-model based Hidden Markov Model was studied. Phoneme models were composed of 61 phonemes in therms of Korean language pronunciation characteristic. Using this, word model was maded by serial concatenation. But, in case of this phoneme concatenation, the second and the third phoneme of syllable are overlapped in distribution at the same time. So considering this, the method that combines the second and the third phoneme to one model was proposed. And to prevent the increase in number of model, similar phonemes were combined to one, and finially, 57 models were created. In experiment proper model structure of sub-model was searched for, and recognition results were compared. So similar recognition results were maded, and overall recognition rates were increased in case of using parameter tying method.

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