• Title/Summary/Keyword: Sequential extraction method

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Electrokinetic Removal and Removal Characteristics of Heavy Metals from Metal-Mining Deposit (동전기법에 의한 광산퇴적토의 중금속 제거 특성)

  • Lee, Chang-Eun;Shin, Hyun-Moo
    • Journal of Environmental Science International
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    • v.12 no.2
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    • pp.227-236
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    • 2003
  • Electrokinetic remediation technique offers the opportunity to extract heavy metals from soils with high plasticity. The experiment demonstrated the applicability of electrokinetic remediation on metal-mining deposit and the decision of the enhancement method for four kinds of bench-scale studies. According to the sequential extraction of heavy metals in the "I" mining deposit, Pb and Cu were mostly associated with residual fraction and Zn and Cd were associated with water soluble and residual fraction. Therefore, removable fractions by electrokinetic technology was determined by the sum of the fraction of water soluble and exchangeable, which is Cu : 19.53%, Pb : 1.42%, Cd : 52.82%, Zn : 57.28%, respectively. When considering electrical potential, volume of effluent, soil pH, and eliminated rate of contaminant, results determined by sum of each weight were Citric aic+SDS (13) > 0.1N $HNO_3$ (10) > HAc (8) > DDW (4). Therefore, citric acid and SDS mixed solution was determined the best enhancing agent for the remediation of metal mining deposit.g deposit.

Chemical Speciation of Heavy Metals in Soils of Jeju Island, Korea (제주도 토양 중 중금속의 화학적 형태)

  • Hyun, Sung-Su;Kim, Se-Ra;Lee, Min-Gyu;Kam, Sang-Kyu
    • Journal of Environmental Science International
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    • v.26 no.7
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    • pp.847-858
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    • 2017
  • For 26 soil series distributed more than 1% among 63 soil series in Jeju Island, natural uncultivated soil samples were collected. For these soils, the chemical speciation of eight heavy metals (Cd, Cr, Cu, Mn, Ni, Pb, V, and Zn) was examined. Further, the Plant Bioavailability (PB) and Mobility Factor (MF) of these heavy metals were evaluated using Tessier's 5-step sequential extraction method (exchangeable, carbonate, reducible (bound to Fe/Mn oxides), oxidizable (bound to organic matter), and residual fraction). The main form present was residual fraction for Cd and Zn; residual and oxidizable fractions for Cr, Cu, Ni, and Pb; reducible fraction for Mn; and carbonate fraction for V. The average plant availability and average mobility factor were found to be V (57.37%) > Zn (12.49%) > Cd (11.76%) > Cu (11.19%) > Pb (9.37%) > Cr (9.09%) > Mn (3.13%) > Ni (2.63%), and Mn (61.04%) > V (59.94%) > Zn (31.54%) > Cd (17.65%) > Cr (15.66%) > Ni (13.89%) > Pb (13.80%) > Cu (13.53%), respectively.

Isolation of Polypeptide Fractions from Different Park offered Ginseng

  • Larina, Ludmila;Muranova, T.;Cho, B.G.;Park, H.
    • Proceedings of the Ginseng society Conference
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    • 1998.06a
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    • pp.160-167
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    • 1998
  • Chemical studies of nitrogen compounds of Panax ginseng seem relatively rare, Probably due to the isolation difficulties, subsequently the investigations of biological activities are little. The experimental conditions were established for highly complete extraction of peptides (basic, acidic and neutral) from Panax ginseng. This task was achieved by applying the follow isolation procedure: 1 , the sequential extraction with water, 0.1% TFA in 20% acetonitril and buffer pH 6.5 (water-pyridine-acetic acid 100:3:900) : 2, fractionation by ultrafiltration : 3, n-butanol extraction 4, cation- and anion-exchange chromatography : 5, chromato-electrophoresis. The comparison of red ginseng (xylem Sl pith part) and red ginseng inside white (xylem Sc pith part) was also provided. To analyze the peptide mixture the chromato-electrophoresis method of separation was applied. Optimal conditions for peptides mapping of sample were explored. Our experiments revealed the quantitative difference of peptide between xylem & pith and phloem & cortex part. We have also found the qualitative difference in the composition of polypeptides between normal red ginseng (xylem Sc pith part) and red ginseng inside-white (xylem St pith part)

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Bioaccumulation of Ag and Zn in earthworms (Eisenia fetida) from soil contaminated with Ag and Zn nanoparticles using a radiotracer method (방사성동위원소 추적자 기법을 이용한 제조나노입자로 오염된 토양으로부터 지렁이(Eisenia fetida)의 은과 아연 축적 연구)

  • Seung Ha Lee;Byeong-Gweon Lee
    • Korean Journal of Environmental Biology
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    • v.39 no.4
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    • pp.550-558
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    • 2021
  • In a radiotracer study, the bioaccumulation and efflux of metals in earthworms (Eisenia fetida) exposed to soil spiked with ZnO and Ag nanoparticles (AgNP) were compared to those exposed to soil spiked with ionic Zn and Ag. Additionally, the bioavailability and chemical mobility of nano- and ionic metals in the soil were estimated using the sequential extraction method and compared to the bioaccumulation factor(BAF). The BAF for ZnO (0.06) was 31 times lower than that for Zn ions (1.86), suggesting that ZnO was less bioavailable than the ionic form in contaminated soil. In contrast, the BAFs for two types of AgNPs coated with polyvinylpyrrolidone (0.12) or citrate (0.11) were comparable to those of ionic Ag (0.17). The sequential extraction of metals from the soil suggests that the chemically mobile fractions in the Zn ion treatment were higher(35%) than those (<20%) in the Ag ion treatment, which was consistent with the greater BAFs in the former than the latter. However, the chemical mobility in the ZnO treatments did not predict bioavailability. The efflux rates of Ag (3.2-3.8% d-1) in the worms were 2-3×those(1.2-1.7% d-1) for Zn.

Feature curve extraction from point clouds via developable strip intersection

  • Lee, Kai Wah;Bo, Pengbo
    • Journal of Computational Design and Engineering
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    • v.3 no.2
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    • pp.102-111
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    • 2016
  • In this paper, we study the problem of computing smooth feature curves from CAD type point clouds models. The proposed method reconstructs feature curves from the intersections of developable strip pairs which approximate the regions along both sides of the features. The generation of developable surfaces is based on a linear approximation of the given point cloud through a variational shape approximation approach. A line segment sequencing algorithm is proposed for collecting feature line segments into different feature sequences as well as sequential groups of data points. A developable surface approximation procedure is employed to refine incident approximation planes of data points into developable strips. Some experimental results are included to demonstrate the performance of the proposed method.

Removal of Cr, Pb and Cd from Reservoir Sediment by Electrokinetic Technique (동전기를 이용한 유수지 오염 퇴적토내 Cd, Pb 및 Cr제거)

  • Shin, Hyun-Moo
    • Journal of Soil and Groundwater Environment
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    • v.14 no.1
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    • pp.68-77
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    • 2009
  • For the reservoir sediment highly contaminated with total Cr, Pb, and Cd, the applicability of electrokinetic remediation method was evaluated. Also, BCR sequential extraction method was adopted to compare the heavy metal speciation in between before and after electrokinetic reaction that is operated under constant current condition for the sediment. After reaction, total Cr and Pb moved toward the direction of anode, while Cd tended to cathode and stayed highest in the midst of sediment specimen. From the BCR sequential extraction analysis, it was known that for total Cr and Pb the residual fraction that showed high fraction before reaction decreased and changed to the oxidation fraction. On the other hand, for Cd the fraction of exchangeable/carbonate that dominated most fractions before reaction changed to the residual and oxidation fractions.

A study on automatic extraction of a moving object using optical flow (Optical flow 이론을 이용한 움직이는 객체의 자동 추출에 관한 연구)

  • 정철곤;김경수;김중규
    • Proceedings of the IEEK Conference
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    • 2000.06d
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    • pp.50-53
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    • 2000
  • In this work, the new algorithm that automatically extracts moving object of the video image is presented. In order to extract moving object, it is that velocity vectors correspond to each frame of the video image. Using the estimated velocity vector, the position of the object are determined. the value of the coordination of the object is initialized to the seed, and in the image plane, the moving object is automatically segmented by the region growing method. As the result of an application in sequential images, it is available to extract a moving object.

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A Sequential Estimation Algorithm for TDOA/FDOA Extraction for VHF Communication Signals (VHF 대역 통신 신호에서 TDOA/FDOA 정보 추출을 위한 순차 추정 알고리즘)

  • Kim, Dong-Gyu;Kim, Yong-Hee;Park, Jin-Oh;Lee, Moon Seok;Park, Young-Mi;Kim, Hyoung-Nam
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.7
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    • pp.60-68
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    • 2014
  • In modern electronic warfare systems, a demand on the more accurate estimation method based on TDOA and FDOA has been increased. TDOA/FDOA localization consists of two-stage procedures; the extraction of information from signals, and the estimation of emitter location. CAF(complex ambiguity function) is known as a basic method in the extraction stage. However, when we extract TDOA and FDOA information from VHF(very high frequency) communication signals, conventional CAF algorithms may not work within a permitted time because of much computation. Therefore, in this paper, an improved sequential estimation algorithm based on CAF is proposed for effective calculation of extracting TDOA and FDOA estimates in terms of computational complexity. The proposed method is compared with the conventional CAF-based algorithms through simulation. In addition, we derive the optimal performance based on the CRLB(Cramer-Lao lower bound) to check the extraction performance of the proposed method.

The Partitioning Characteristics of Heavy Metals in Soils of Ulsan by Sequential Extraction Procedures (단계별추출법에 의한 울산지역 토양 중의 중금속 Partitioning 특성연구)

  • Lee, Byeong-Kyu;Koh, Il-Ha;Kim, Haeng-Ah
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.25-35
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    • 2005
  • This study analyzed total concentrations and existing forms of heavy metals in soils of Ulsan using a sequential extraction method. Soil samples were collected from 6 categorized areas including green, residential, heavy traffic, petrochemical industrial complex(IC), mechanical and shipbuilding IC, and non-ferrous metal IC areas. which represent different emission characteristics. The highest total concentrations of heavy metals by a sequential extraction analysis were observed in the soils collected from the non-ferrous metal IC area, followed by the mechanical and shipbuilding IC and heavy traffic areas. Dominant(> 50%) existing forms of Cd, Cr and Ni were residual forms followed by Fe and Mn oxides in almost areas. Residual fractions in the non-ferrous metal IC areas were relatively lower than those in other areas. However, the fractions of organic and sulphides in the IC areas were higher. The dominant farms of Cu were much different with the investigated areas. In most areas, the dominant forms of Pb and Zn were Fe and Mn oxides, followed by residual fraction for Pb. The exchangeable and carbonate fractions represent mobility of metallic elements in soils. They are also significantly affected by the environmental renditions, such as pHs of soil and rainfall. In this study the exchangeable and carbonate fractions were lower than other fractions. Because the total concentrations of heavy metals in the soils of the non-ferrous metal IC area were extremely high, however, the mobile fractions of heavy metals in the IC area would be significant. Thus a large amount of heavy metals can be released into plants, water bodies, and soils. Therefore, urgent measures, such as source control for soil remediation of heavy metals, in the non-ferrous metal IC areas are essentially required. Analysis results obtained from the sequential extraction and the aqua regia extraction showed a high correlation, whose determination coefficients(R2) of heavy metals except Cd approximately ranged from 0.7 to 0.9.

Genetic Algorithm Based Feature Selection Method Development for Pattern Recognition (패턴 인식문제를 위한 유전자 알고리즘 기반 특징 선택 방법 개발)

  • Park Chang-Hyun;Kim Ho-Duck;Yang Hyun-Chang;Sim Kwee-Bo
    • Journal of the Korean Institute of Intelligent Systems
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    • v.16 no.4
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    • pp.466-471
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    • 2006
  • IAn important problem of pattern recognition is to extract or select feature set, which is included in the pre-processing stage. In order to extract feature set, Principal component analysis has been usually used and SFS(Sequential Forward Selection) and SBS(Sequential Backward Selection) have been used as a feature selection method. This paper applies genetic algorithm which is a popular method for nonlinear optimization problem to the feature selection problem. So, we call it Genetic Algorithm Feature Selection(GAFS) and this algorithm is compared to other methods in the performance aspect.