• Journal of Korean Society of Environmental Engineers
• /
• v.35 no.11
• /
• pp.835-860
• /
• 2013

Recently, the consumption of nanomaterials has been significantly increased in both industrial and commercial sectors, as a result of steady advancement in the nano-technologies. This ubiquitous use of nanomaterials has brought up the concern that their exposure to environments may cause detrimental effects on human health as well as natural ecosystems, and it is required to characterize their behavior in various environmental media and to evaluate their ecotoxicity. For the sake of accomplishing those assessments, the development of methods to effectively separate them from diverse media and to quantify their properties should be requisitely accompanied. Among a number of separation techniques developed so far, this study focuses on Field-Flow Fractionation (FFF) because of its strengths, such as relatively less disturbance of samples and simple pretreatment, and we review overseas and domestic literatures on the separation of nanomaterials using the FFF technique. In particular, researches with Flow Field-Flow Fractionation (FlFFF) are highlighted due to its most frequent application among FFF techniques. The basic principle of the FlFFF is briefly introduced and the studies conducted so far are classified and scrutinized based on the sort of target nanomaterials for the purpose of furnishing practical data and information for the researchers struggling in this field. The literature review suggests that the operational conditions, such as pretreatment, selection of membrane and carrier solution, and rate (velocity) of each flow, should be optimized in order to effectively separate them from various matrices using the FFF technique. Moreover, it seems to be a prerequisite to couple or hyphenate with several detectors and analyzers for quantification of their properties after their separation using the FFF. However, its application has been restricted regarding the types of target nanomaterials and environmental media. Furthermore, domestic literature data on both separation and characterization of nanomaterials are extremely limited. Taking into account the overwhelmingly increasing consumption of nanomaterials, the efforts for the area seem to be greatly urgent.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.5
• /
• pp.1143-1148
• /
• 2010

We investigated the separation of nitrogen heterocyclic compound (NHC) contained in a model coal tar fraction comprising four kinds of NHC [indole (In), quinoline (Q), iso-quinoline (iQ), quinaldine (Qu)], three kinds of bicyclic aromatic compound (BAC) [1-methylnaphthalene (1MN), 2-methylnaphthalene (2MN), dimethylnaphthalene (DMN) mixture with ten structural isomers (DMNs; regarded as one component)], biphenyl (Bp) and phenyl ether (Pe) by liquid membrane permeation (LMP). A batch-stirred tank was used as the permeation unit. An aqueous solution of saponin and n-hexane were used as the liquid membrane and the outer oil phase, respectively. Yield and selectivity of individual NHC was much larger than that of BAC, Bp and Pe. Increasing the initial mass fraction of the saponin to the membrane solution ($C_{sap,0}$) and the initial volume fraction of O/W emulsion to total liquid in a stirred tank (${\phi}_{OW,0}$) resulted in deteriorating the yield of individual NHC, but increasing the stirring speed (N) resulted in improving the yield of each NHC. With increasing $C_{sap,0}$, the selectivity of each NHC based on DMNs increased. Increasing ${\phi}_{OW,0}$ and N resulted in decreasing the selectivity of individual NHC based on DMNs. At an experimental condition fixed, the sequence of the yield and selectivity in reference to DMNs for each NHC was Q > Qu = iQ > In. Furthermore, we compared LPM method with methanol extraction method in view of the separation efficiency (yield, selectivity) of NHC.

• Korean Chemical Engineering Research
• /
• v.54 no.5
• /
• pp.598-605
• /
• 2016

V-Cr-Y alloy is a material for hydrogen separation membrane possessing high transmittance and selectivity. In order to increase the rate of hydrogen permeation flux through the membrane, V-Cr-Y thin film was prepared using a sputtering technique and was investigated focusing on its basic properties. Thin film was deposited on a silicon wafer using a target including V (89.8%), Cr (10.0%) and Y(0.2%), and results of EDS analysis confirm that the ratio of metal in thin film agrees with that in the target. Higher sputtering temperature and power resulted in more rapid growth rate of the thin film and larger size of the crystals, and denser and finer crystal structure was observed when lower pressure was applied. An optimal sputtering condition was found with RF, 2mTorr, 300W and ambient temperature, and a suitable V-Cr-Y thin film for hydrogen separation was obtained upon heat treatment of the thin film prepared in this way.

• Physical Therapy Korea
• /
• v.18 no.3
• /
• pp.94-102
• /
• 2011

The purpose of this study was to review existing assessment tools for patients with low back pain and improve them through combination. A total of 314 patients with low back pain participated. Their condition was assessed using the Oswestry Disability Questionnaire (ODQ), the Quebec Back Pain Disability Scale (QBPD), and the Back Pain Functional Scale (BPFS). Rasch analysis was applied to identify inappropriate items, item difficulties, and the separation index. In this study, the 'sex life' item of the ODQ (10 items) and the 'sleeping' item of the BPFS (12 items) showed misfit statistics, whereas all items of the QBPD (20 items) were appropriate. After combining the ODQ, QBPD and BPFS, Rasch analysis was applied. The 'pain intensity', and the 'sex life' item of the ODQ and the 'throw a ball' item of QBPD showed misfit statistics. These 3 items were retained for further analysis. The remaining 42 combined ODQ-QBPD-BPFS items were arranged according to difficulty. For all subjects, the most difficult item was 'pain intensity', whereas the easiest was 'take food out of the refrigerator'. As the separation index of 42 combined ODQ-QBPD-BPFS was higher than that of the three questionnaires separately, difficulty of items varied with some need for rearrangement. The results of this study confirmed the possibility and need for a new back pain disability assessment tool, and produced one. Further study is needed to refine the questionnaire in consideration of psychosocial and occupational factors.

• Membrane Journal
• /
• v.24 no.5
• /
• pp.393-399
• /
• 2014

The permeation experiments were carried out to examine the separation characteristics of the modules which were piled up the disc-ring shape patterned membranes in this study. First of all, permeability of the pure water was measured for the self-made 5 shape disc filters, and varied from 0.25 to $2.24L/m^2{\cdot}hr{\cdot}bar$. The module showed the maximum pure water permeability was the maximum permeation flux, and the module showed the minimum pure water permeability was the minimum permeation flux for 0.1 wt% kaolin solution. However, all of the modules were not proportioned to the pure water permeability. Also, the backwashing was performed periodically for the module 1 in order to operate with 0.1 wt% kaolin solution for a long time. The most efficient operating condition was the 8 minute permeation and 2 minute backwashing cycle.

• Journal of Biosystems Engineering
• /
• v.7 no.2
• /
• pp.45-56
• /
• 1983

The purpose of this experiment was to evaluate the effect of the drum structures and crop moisture contents on the performance of newly developed throw-in type axial thersher. Sachun No.2 malting barley with four different crop moisture levels was used as the testing material. Four different types of threshing drum; the cylindrical drum-equipped with teeth or rubber bars and the conical drum-equipped with teeth or rubber bars were tested. The results are summarized as follows; 1. The threshing efficiency of cylindrical drum was higher than that of the conical one, and the drum with teeth was more effective in threshing than the one with bars. However, the higher the threshing efficiency over the whole range of moisture levels and drum speeds given, the more the rapid and unexpectable variations in threshing efficiencies 2. The separation efficiency of the conical drum was decreased as drum speed was increased and was not so much influenced as crop moisture content. But in case of the cylindrical drum, the result was shown in opposite way to that of the conical one. The separation efficiency of the drum with teeth was higher than that of the drum with bars and no significant decrease in separating efficiency was found at wet crop condition. 3. Foreign matters other than grain passing through the concave sieve was decreased as crop moisture content was increased, and the purity was increased at middle range of drum speed regardless of drum types. 4. Minimum grain loss was found at 700 rpm to 800 rpm of drum speed for all types of drums. The effect of crop moisture content on total grain loss was varied with drum types. As far as the grain loss is concerned, the conical drum having teeth was not so greatly influenced by various crop moisture contents and drum speeds as compared with the other types of drum. 5. Generally, the crop moisture content has more relevant effect on the germination than the drum speed regardless of drum types. The germination percentage of grain threshed by the conical drum and the bar attached drum were higher than those of cylindrical one and teeth attached one, respectively.

• Journal of Advanced Navigation Technology
• /
• v.19 no.5
• /
• pp.379-388
• /
• 2015

In the end of 1990's, future free flight technology had been developed and tested in America and government established the plan for free flight until 2017. Aircraft separation assurance must be secured essentially to avoid collision between aircrafts before Free Flight comes true. Now, Civil aircraft has rules about avoidance activity with traffic collision avoidance system (TCAS) but it can't apply to light aircraft. So there is a need about alternative method to apply light-aircraft because it has space and price problem to use TCAS. In this paper, TCAS algorithm has been modified and verified by simulating with LABVIEW program under ADS-B condition to get miniaturization and weight lighting cheaply. By simulating, collision alert algorithm is analyzed and verified with collision situation proposed by ICAO, and 100% checked for performing the alert announciation on all cases by TCAS standards.

• Journal of Communications and Networks
• /
• v.8 no.2
• /
• pp.187-193
• /
• 2006

In this paper, we study the coexistence of orthogonal frequency division multiplexing (OFDM)-based systems beyond 3G (B3G) and point-to-point (P-P) fixed service (FS) microwave systems. The advanced general analytical model derived via a power spectral density (PSD) analysis proposed in this paper has two advantages in comparison with the conventional minimum coupling loss (MCL) method. First, the interfering signal power that appears in the band of a victim system can be easily assessed without a spectrum emission mask. Second, when transmit power is not allocated to some subcarriers overlapping the band of the victim system in order to mitigate B3G OFDM-based systems interference with other systems, the general analytical model can successfully assess the interference from the B3G systems into FS systems, whereas the MCL method incorporating the spectrum emission mask cannot be applied in the presence of the same interference condition. The proposed model can be derived in a closed form and is simply implemented with the help of simulation, and thus the solution can be obtained in significantly reduced time. Through application of the proposed model, coexistence results are analyzed in a co-channel and adjacent channel with respect to guard band and minimum separation distance.

• Journal of the Society of Naval Architects of Korea
• /
• v.54 no.1
• /
• pp.18-25
• /
• 2017

This study deals with numerically comparing performance according to rudder shape called 'Twisted rudder and Wavy twisted rudder'. In comparison with conventional rudder, rudder with wavy shape has showed a better performance at high angles of attack($30^{\circ}{\sim}40^{\circ}$) due to delaying stall. But most of study concerned with wavy shape had been performed in uniform flow condition. In order to identify the characteristics behind a rotating propeller, the present study numerically carries out an analysis of resistance and self-propulsion for KCS with twisted rudder and wavy twisted rudder. The turbulence closure model, Realizable $k-{\epsilon}$, is employed to simulate three-dimensional unsteady incompressible viscous turbulent and separation flow around the rudder. The simulation of self-propulsion analysis is performed in two step, because of finding optimization case of wavy shape. The first step presents there are little difference between twisted rudder and case of H_0.65 wavy twisted rudder in delivered power. So two kind of rudders are employed from first step to compare lift-to-drag ratio and torque at high angles of attack. Consequently, the wavy twisted rudder is presented as a possible way of delaying stall, allowing a rudder to have a better performance containing superior lift-to-drag ratio and torque than twisted rudder at high angles of attack. Also, as we indicate the flow visualization, check the quantity of separation flow around the rudder.

• Korean Chemical Engineering Research
• /
• v.48 no.4
• /
• pp.515-518
• /
• 2010

D,L-tryptophans were separated by using $Chirobiotic^{(R)}$ T HPLC column. Mobile phases were the mixture of methanol and water(70:30, 80:20, 90:10, v/v). Experimental temperatures were adjusted as 25, 40 and $55^{\circ}C$ in order to compare retention times. Difference in D,L-tryptophan retention times was studied in terms of the interaction between stationary phase and tryptophans. Selectivity, resolution and efficiency of column were utilized to find an optimum separation condition. Retention times were shortened by increasing the amount of methanol in mobile phase and the temperature of column. The best selectivity and resolution was obtained with the temperature($25^{\circ}C$) and the ratio of mobilephase(70/30 v/v%).